Mount Isa Mines tetrahedrite as ore minerals along with common accessories pyrite, pyrrhotite, quartz, carbonates and graphite. Minor arsenopyrite, marcasite, chalcopyrite, valleriite, proustite, polybasite and argentite also occur. Original surface oxidized ore contained cerussite, anglesite and pyromorphite. Silver and zinc were removed from the surface oxidized zone and were deposited as supergene ore at a depth above the primary ore. Copper occurs in brecciated "silica-dolomite" rock. Primary minerals are chalcopyrite, pyrrhotite and arsenopyrite. minor amounts of cobaltite, marcasite, valleriite, chalcostibite, galena and others are reported. Smelter operations release sulfur dioxide emissions very close to the city of Mount Isa. The Mount Isa Mines
Chalcopyrite chalcopyrite has no solid solution series with any other sulfide minerals. There is limited substitution of Zn with Cu despite chalcopyrite having the same crystal structure as sphalerite. Minor amounts of elements such as Ag, Au, Cd, Co, Ni, Pb, Sn, and Zn can be measured (at part per million levels), likely substituting for Cu and Fe. Selenium, Bi, Te, and As may substitute for sulfur in minor amounts. Chalcopyrite is present with many ore-bearing environments via a variety of ore forming processes. Chalcopyrite is present in volcanogenic massive sulfide ore deposits and sedimentary exhalative deposits, formed by deposition of