Chalcopyrite is closely related to that of zinc blende ZnS (sphalerite). The unit cell is twice as large, reflecting an alternation of Cu and Fe ions replacing Zn ions in adjacent cells. In contrast to the pyrite structure chalcopyrite has single S sulfide anions rather than disulfide pairs. Another difference is that the iron cation is not diamagnetic low spin Fe(II) as in pyrite. Copper metal can be extracted from the roasting of chalcopyrite, as shown in the following reaction: Although if roasted partially it produces and . Chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral that crystallizes in
Ore Mountains this is a contract between Boresch of Riesenburg and the Ossegg abbot, Gerwig, in which the division of revenue derived from ore was agreed. Grains of tin ("Zinnkörner" or "Graupen") were obtained at that time in the Seiffen mining area and gave the Bohemian mining town of Graupen (Czech "Krupka") its name. With the further settlement of the Ore Mountains in the 15th century, new, rich, ore deposits were eventually discovered around Schneeberg Annaberg and St. Joachimsthal. The "Second Berggeschrey" started and triggered a massive wave of colonization. In quick succession, new, planned, mining towns were built across the Ore