Chalcopyrite is closely related to that of zinc blende ZnS (sphalerite). The unit cell is twice as large, reflecting an alternation of Cu and Fe ions replacing Zn ions in adjacent cells. In contrast to the pyrite structure chalcopyrite has single S sulfide anions rather than disulfide pairs. Another difference is that the iron cation is not diamagnetic low spin Fe(II) as in pyrite. Copper metal can be extracted from the roasting of chalcopyrite, as shown in the following reaction: Although if roasted partially it produces and . Chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral that crystallizes in
Ore genesis a solution of gold (III) tetrachloride, a compound highly toxic to most other microorganisms. Similarly, Delftia acidovorans can form gold nuggets. Platinum and palladium are precious metals generally found in ultramafic rocks. The source of platinum and palladium deposits is ultramafic rocks which have enough sulfur to form a sulfide mineral while the magma is still liquid. This sulfide mineral (usually pentlandite, pyrite, chalcopyrite, or pyrrhotite) gains platinum by mixing with the bulk of the magma because platinum is chalcophile and is concentrated in sulfides. Alternatively, platinum occurs in association with chromite either within the chromite mineral itself or within