Ozone layer bromine (Br). While there are natural sources for all of these species, the concentrations of chlorine and bromine increased markedly in recent decades because of the release of large quantities of man-made organohalogen compounds, especially chlorofluorocarbons (CFCs) and bromofluorocarbons. These highly stable compounds are capable of surviving the rise to the stratosphere, where Cl and Br radicals are liberated by the action of ultraviolet light. Each radical is then free to initiate and catalyze a chain reaction capable of breaking down over 100,000 ozone molecules. By 2009, nitrous oxide was the largest ozone-depleting substance (ODS) emitted through human activities. The
Planetary boundary layer PBL top or "entrainment layer" or "capping inversion layer" (between 0.7 and 1 of the PBL depth). Four main external factors determine the PBL depth and its mean vertical structure: Physical laws and equations of motions, which govern the planetary boundary layer dynamics and microphysics, are strongly non-linear and considerably influenced by properties of the Earth's surface and evolution of the processes in the free atmosphere. To deal with this complicity, the whole array of turbulence modelling has been proposed. However, they are often not accurate enough to meet practical requests. Significant improvements are expected from application of a large