Surface-area-to-volume ratio Surface-area-to-volume ratio The surface-area-to-volume ratio, also called the surface-to-volume ratio and variously denoted sa/vol or SA:V, is the amount of surface area per unit volume of an object or collection of objects. In chemical reactions involving a solid material, the surface area to volume ratio is an important factor for the reactivity, that is, the rate at which the chemical reaction will proceed. For a given volume, the object with the smallest surface area (and therefore with the smallest SA:V) is the sphere, a consequence of the isoperimetric inequality in 3 dimensions. By contrast, objects with tiny spikes will have
Ideal surface Ideal surface An ideal solid surface is flat, rigid, perfectly smooth, and chemically homogeneous, and has zero contact angle hysteresis. Zero hysteresis implies the advancing and receding contact angles are equal. In other words, only one thermodynamically stable contact angle exists. When a drop of liquid is placed on such a surface, the characteristic contact angle is formed as depicted in Fig. 1. Furthermore, on an ideal surface, the drop will return to its original shape if it is disturbed. The following derivations apply only to ideal solid surfaces; they are only valid for the state in which the interfaces