Absolute dating radiocarbon dating. The development of accelerator mass spectrometry (AMS) dating, which allows a date to be obtained from a very small sample, has been very useful in this regard. Other radiometric dating techniques are available for earlier periods. One of the most widely used is potassium–argon dating (K–Ar dating). Potassium-40 is a radioactive isotope of potassium that decays into argon-40. The half-life of potassium-40 is 1.3 billion years, far longer than that of carbon-14, allowing much older samples to be dated. Potassium is common in rocks and minerals, allowing many samples of geochronological or archeological interest to be dated. Argon,
Kinetic isotope effect "k"/"k", of 1.0133±0.0002 along with a hydrogen kinetic isotope effect of 3.2 at the leaving hydrogen. Similarly, combining nitrogen and hydrogen isotope effects was used to show that syn eliminations of simple ammonium salts also follow a concerted mechanism, which was a question of debate before. In the following two reactions of 2-phenylcyclopentyltrimethylammonium ion with ethoxide, both of which yield 1-phenylcyclopentene, both isomers exhibited a nitrogen isotope effect "k"/"k" at 60C. Although the reaction of the trans isomer, which follows syn elimination, has a smaller nitrogen kinetic isotope effect (1.0064) compared to the cis isomer which undergoes anti elimination (1.0108),