Carbon-14 Carbon-14 Carbon-14, (C), or radiocarbon, is a radioactive isotope of carbon with an atomic nucleus containing 6 protons and 8 neutrons. Its presence in organic materials is the basis of the radiocarbon dating method pioneered by Willard Libby and colleagues (1949) to date archaeological, geological and hydrogeological samples. Carbon-14 was discovered on February 27, 1940, by Martin Kamen and Sam Ruben at the University of California Radiation Laboratory in Berkeley, California. Its existence had been suggested by Franz Kurie in 1934. There are three naturally occurring isotopes of carbon on Earth: carbon-12, which makes up 99% of all carbon on
Hydrogen isotope biogeochemistry measurement nowadays. The commercial products of GC-IRMS include both combustion and pyrolysis interfaces so that δC and δD can be measured simultaneously. The significant advantage of GC/pyrolysis method for hydrogen isotope measurement is that it can separate different compounds in the samples. It requires the smallest sample size (a typical size of ~ 200 ng) relative to other methods and also has a high precision of 1~5 ‰. But this method is relatively slow and limited to the samples which can be applied in GC system. Laser Spectroscopy (or Cavity ring-down spectroscopy, CRDS) is able to directly measure D/H, O/O