Chalcopyrite Chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral that crystallizes in the tetragonal system. It has the chemical formula CuFeS. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green tinged black. On exposure to air, chalcopyrite oxidises to a variety of oxides, hydroxides and sulfates. Associated copper minerals include the sulfides bornite (CuFeS), chalcocite (CuS), covellite (CuS), digenite (CuS); carbonates such as malachite and azurite, and rarely oxides such as cuprite (CuO). Chalcopyrite is rarely found in association with native copper. Natural
Chalcopyrite chalcopyrite has no solid solution series with any other sulfide minerals. There is limited substitution of Zn with Cu despite chalcopyrite having the same crystal structure as sphalerite. Minor amounts of elements such as Ag, Au, Cd, Co, Ni, Pb, Sn, and Zn can be measured (at part per million levels), likely substituting for Cu and Fe. Selenium, Bi, Te, and As may substitute for sulfur in minor amounts. Chalcopyrite is present with many ore-bearing environments via a variety of ore forming processes. Chalcopyrite is present in volcanogenic massive sulfide ore deposits and sedimentary exhalative deposits, formed by deposition of