Metal carbonyl 18-electron complexes is sometimes catalysed by catalytic amounts of oxidants, via electron-transfer. Metal carbonyls react with reducing agents such as metallic sodium or sodium amalgam to give carbonylmetalate (or carbonylate) anions: For iron pentacarbonyl, one obtains the tetracarbonylferrate with loss of CO: Mercury can insert into the metal-metal bonds of some polynuclear metal carbonyls: The CO ligand is often susceptible to attack by nucleophiles. For example, trimethylamine oxide and bistrimethylsilylamide convert CO ligands to CO and CN, respectively. In the "Hieber base reaction", hydroxide ion attacks the CO ligand to give a metallacarboxylic acid, followed by the release of carbon
Mercury glass Mercury glass Mercury glass (or silvered glass) is glass that was blown double walled, then silvered between the layers with a liquid silvering solution, and sealed. Although mercury was originally used to provide the reflective coating for mirrors, elemental mercury was never used to create tableware. Silvered glass was free-blown, then silvered with a solution containing silver nitrate and grape sugar in solution, heated, then closed. Sealing methods include metal discs covered with a glass round or a cork inserted into the unpolished pontil scar. "Mercury" silvered glass was produced originally around 1840 until at least 1930 in Bohemia (now