Surface-area-to-volume ratio Surface-area-to-volume ratio The surface-area-to-volume ratio, also called the surface-to-volume ratio and variously denoted sa/vol or SA:V, is the amount of surface area per unit volume of an object or collection of objects. In chemical reactions involving a solid material, the surface area to volume ratio is an important factor for the reactivity, that is, the rate at which the chemical reaction will proceed. For a given volume, the object with the smallest surface area (and therefore with the smallest SA:V) is the sphere, a consequence of the isoperimetric inequality in 3 dimensions. By contrast, objects with tiny spikes will have
Capillary surface and other energy potentials absent, the energy of the system is where the subscripts formula_40, formula_41, and formula_42 respectively indicate the liquid–gas, solid–gas, and solid–liquid interfaces. Note that inclusion of gravity would require consideration of the volume enclosed by the capillary surface and the solid walls. Typically the surface tension values between the solid–gas and solid–liquid interfaces are not known. This does not pose a problem; since only changes in energy are of primary interest. If the net solid area formula_43 is a constant, and the contact angle is known, it may be shown that (again, for two different fluids