Native metal brass, bronze, pewter, German silver, osmiridium, electrum, white gold, and silver-mercury and gold-mercury amalgam. Only gold, silver, copper and the platinum metals occur in nature in large amounts. Over geological time scales, very few metals can resist natural weathering processes like oxidation, which is why generally only the less reactive metals such as gold and platinum are found as native metals. The others usually occur as isolated pockets where a natural chemical process reduces a common compound or ore of the metal, leaving the pure metal behind as small flakes or inclusions. Non-metallic elements occurring in the native state include
Volcanogenic massive sulfide ore deposit sulfidic sediments, similar to SEDEX ores, and is generally manganese, barium and hematite enriched, with cherts, jaspers and chemical sediments common. Most VMS deposits show metal zonation, caused by the changing physical and chemical environments of the circulating hydrothermal fluid. Ideally, this forms a core of massive pyrite and chalcopyrite around the throat of the vent system, with a halo of chalcopyrite-sphalerite-pyrite grading into a distal sphalerite-galena and galena-manganese and finally a chert-manganese-hematite facies. Most VMS deposits show a vertical zonation of gold, with the cooler upper portions generally more enriched in gold and silver. The mineralogy of VMS massive