Chalcopyrite Chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral that crystallizes in the tetragonal system. It has the chemical formula CuFeS. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green tinged black. On exposure to air, chalcopyrite oxidises to a variety of oxides, hydroxides and sulfates. Associated copper minerals include the sulfides bornite (CuFeS), chalcocite (CuS), covellite (CuS), digenite (CuS); carbonates such as malachite and azurite, and rarely oxides such as cuprite (CuO). Chalcopyrite is rarely found in association with native copper. Natural
Volcanogenic massive sulfide ore deposit sulfide consists of over 90% iron sulfide, mainly in the form of pyrite, with chalcopyrite, sphalerite and galena also being major constituents. Magnetite is present in minor amounts; as magnetite content increases, the ores grade into massive oxide deposits. The gangue (the uneconomic waste material) is mainly quartz and pyrite or pyrrhotite. Due to the high density of the deposits some have marked gravity anomalies (Neves-Corvo, Portugal) which is of use in exploration. Alteration haloes developed by VMS deposits are typically conical in shape, occur mostly stratigraphically below the original fluid flow location (not necessarily the ore itself), and are