Surface tension gases. The pressure inside an ideal (one surface) soap bubble can be derived from thermodynamic free energy considerations. At constant temperature and particle number, , the differential Helmholtz energy is given by where is the difference in pressure inside and outside of the bubble, and is the surface tension. In equilibrium, , and so, For a spherical bubble, the volume and surface area are given simply by and Substituting these relations into the previous expression, we find which is equivalent to the Young–Laplace equation when . For real soap bubbles, the pressure is doubled due to the presence of two
Surface energy radius formula_1 and length formula_2 at high temperature and a constant uniaxial tension formula_3, then at equilibrium, the variation of the total Helmholtz free energy vanishes and we have where formula_5 is the Helmholtz free energy and formula_6 is the surface area of the rod: Also, since the volume (formula_8) of the rod remains constant, the variation (formula_9) of the volume is zero, i.e., Therefore, the surface energy density can be expressed as The surface energy density of the solid can be computed by measuring formula_3, formula_1, and formula_2 at equilibrium. This method is valid only if the solid is