Chalcopyrite is closely related to that of zinc blende ZnS (sphalerite). The unit cell is twice as large, reflecting an alternation of Cu and Fe ions replacing Zn ions in adjacent cells. In contrast to the pyrite structure chalcopyrite has single S sulfide anions rather than disulfide pairs. Another difference is that the iron cation is not diamagnetic low spin Fe(II) as in pyrite. Copper metal can be extracted from the roasting of chalcopyrite, as shown in the following reaction: Although if roasted partially it produces and . Chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral that crystallizes in
Southeast Missouri Lead District sphalerite, and chalcopyrite. Gangue minerals associated with the economic minerals include pyrite, calcite, dolomite, and quartz. Specimens from the Lead Belt are highly prized by gem and mineral collectors and are found in museums worldwide. The ore minerals of the Lead Belt are primarily hosted by bacterial stromatolite reefs and associated oolitic rocks of the dolomitic Bonneterre Formation. This Cambrian age formation was deposited in a shallow sea around the Precambrian age St. Francois Mountains, which formed an island archipelago. Ore mineralization most likely occurred during the late Pennsylvanian and/or Permian periods when warm metal and petroleum bearing fluids from