Iron oxide copper gold ore deposits to be within Neoproterozoic to Mesoproterozoic basement. Worldwide, ages of recognised IOCG deposits range from 1.8 Ga to 15 Ma, however, the majority are within the 1.6 Ga to 850 Ma range. Ore minerals in IOCG deposits are typically copper-iron sulfide chalcopyrite and gangue pyrite, forming 10–15% of the rock mass. Supergene profiles can be developed above weathered examples of IOCG deposits, as exemplified by the Sossego deposit, Para State, Brazil, where typical oxidised copper minerals are present, e.g.; malachite, cuprite, native copper and minor amounts of digenite and chalcocite. Alteration is a mixture of sodic-calcic (albite-epidote) to potassic (K-feldspar)
Volcanogenic massive sulfide ore deposit sulfidic sediments, similar to SEDEX ores, and is generally manganese, barium and hematite enriched, with cherts, jaspers and chemical sediments common. Most VMS deposits show metal zonation, caused by the changing physical and chemical environments of the circulating hydrothermal fluid. Ideally, this forms a core of massive pyrite and chalcopyrite around the throat of the vent system, with a halo of chalcopyrite-sphalerite-pyrite grading into a distal sphalerite-galena and galena-manganese and finally a chert-manganese-hematite facies. Most VMS deposits show a vertical zonation of gold, with the cooler upper portions generally more enriched in gold and silver. The mineralogy of VMS massive