Acid mine drainage where the ore is a sulfide mineral or is associated with pyrite. In these cases the predominant metal ion may not be iron but rather zinc, copper, or nickel. The most commonly mined ore of copper, chalcopyrite, is itself a copper-iron-sulfide and occurs with a range of other sulfides. Thus, copper mines are often major culprits of acid mine drainage. At some mines, acidic drainage is detected within 2–5 years after mining begins, whereas at other mines, it is not detected for several decades. In addition, acidic drainage may be generated for decades or centuries after it is first detected.
Iron ore is mined in Minnesota and Michigan in the U.S., Eastern Canada and Northern Sweden. Magnetite bearing banded iron formation is currently mined extensively in Brazil, which exports significant quantities to Asia, and there is a nascent and large magnetite iron-ore industry in Australia. Direct-shipping iron-ore (DSO) deposits (typically composed of hematite) are currently exploited on all continents except Antarctica, with the largest intensity in South America, Australia and Asia. Most large hematite iron-ore deposits are sourced from altered banded iron formations and rarely igneous accumulations. DSO deposits are typically rarer than the magnetite-bearing BIF or other rocks which form its