Van der Waals surface research use of a model showing the van der Waals surfaces of molecules. Related to the title concept are the ideas of a "van der Waals volume", V, and a "van der Waals surface area," abbreviated variously as A, vdWSA, VSA, and WSA. A van der Waals surface area is an abstract conception of the surface area of atoms or molecules from a mathematical estimation, either computing it from first principles or by integrating over a corresponding van der Waals volume. In simplest case, for a spherical monatomic gas, it is simply the computed surface area of a sphere of
Surface stress same, they are very different in solid–gas or solid–solid interface, which will be discussed in details later. Since both terms represent a force per unit length, they have been referred to as “surface tension”, which contributes further to the confusion in the literature. Definition of surface free energy is seemly the amount of reversible work formula_1 performed to create new area formula_2 of surface, expressed as: Gibbs was the first to define another surface quantity, different from formula_4, that is associated with the reversible work per unit area needed to elastically stretch a pre-existing surface. Surface stress can be derived