Metal carbonyl 18-electron complexes is sometimes catalysed by catalytic amounts of oxidants, via electron-transfer. Metal carbonyls react with reducing agents such as metallic sodium or sodium amalgam to give carbonylmetalate (or carbonylate) anions: For iron pentacarbonyl, one obtains the tetracarbonylferrate with loss of CO: Mercury can insert into the metal-metal bonds of some polynuclear metal carbonyls: The CO ligand is often susceptible to attack by nucleophiles. For example, trimethylamine oxide and bistrimethylsilylamide convert CO ligands to CO and CN, respectively. In the "Hieber base reaction", hydroxide ion attacks the CO ligand to give a metallacarboxylic acid, followed by the release of carbon
What Is the Matter with Willi? What Is the Matter with Willi? What Is the Matter with Willi? (German:Was ist denn bloß mit Willi los) is a 1970 German comedy film directed by Werner Jacobs and starring Heinz Erhardt, Ralf Wolter and Ruth Stephan. A tax inspector tries to reform the Ministry of Finance. It was based on a character Heinz Erhardt played on television. It was followed by a loose sequel "That Can't Shake Our Willi!" and in 1971 a third film "Our Willi Is the Best" was made with Erhard returning as Willi. The final film "Willi Manages The Whole Thing" was released in