Van der Waals surface research use of a model showing the van der Waals surfaces of molecules. Related to the title concept are the ideas of a "van der Waals volume", V, and a "van der Waals surface area," abbreviated variously as A, vdWSA, VSA, and WSA. A van der Waals surface area is an abstract conception of the surface area of atoms or molecules from a mathematical estimation, either computing it from first principles or by integrating over a corresponding van der Waals volume. In simplest case, for a spherical monatomic gas, it is simply the computed surface area of a sphere of
Surface energy radius formula_1 and length formula_2 at high temperature and a constant uniaxial tension formula_3, then at equilibrium, the variation of the total Helmholtz free energy vanishes and we have where formula_5 is the Helmholtz free energy and formula_6 is the surface area of the rod: Also, since the volume (formula_8) of the rod remains constant, the variation (formula_9) of the volume is zero, i.e., Therefore, the surface energy density can be expressed as The surface energy density of the solid can be computed by measuring formula_3, formula_1, and formula_2 at equilibrium. This method is valid only if the solid is