Van der Waals surface research use of a model showing the van der Waals surfaces of molecules. Related to the title concept are the ideas of a "van der Waals volume", V, and a "van der Waals surface area," abbreviated variously as A, vdWSA, VSA, and WSA. A van der Waals surface area is an abstract conception of the surface area of atoms or molecules from a mathematical estimation, either computing it from first principles or by integrating over a corresponding van der Waals volume. In simplest case, for a spherical monatomic gas, it is simply the computed surface area of a sphere of
Surface integral of the graph of some scalar function, say formula_3, we have where formula_5. So that formula_6, and formula_7. So, which is the standard formula for the area of a surface described this way. One can recognize the vector in the second line above as the normal vector to the surface. Note that because of the presence of the cross product, the above formulas only work for surfaces embedded in three-dimensional space. This can be seen as integrating a Riemannian volume form on the parameterized surface, where the metric tensor is given by the first fundamental form of the surface. Consider