Van der Waals surface research use of a model showing the van der Waals surfaces of molecules. Related to the title concept are the ideas of a "van der Waals volume", V, and a "van der Waals surface area," abbreviated variously as A, vdWSA, VSA, and WSA. A van der Waals surface area is an abstract conception of the surface area of atoms or molecules from a mathematical estimation, either computing it from first principles or by integrating over a corresponding van der Waals volume. In simplest case, for a spherical monatomic gas, it is simply the computed surface area of a sphere of
Surface area lead to different limiting values of the area; this example is known as the Schwarz lantern. Various approaches to a general definition of surface area were developed in the late nineteenth and the early twentieth century by Henri Lebesgue and Hermann Minkowski. While for piecewise smooth surfaces there is a unique natural notion of surface area, if a surface is very irregular, or rough, then it may not be possible to assign an area to it at all. A typical example is given by a surface with spikes spread throughout in a dense fashion. Many surfaces of this type occur