Chalcopyrite is closely related to that of zinc blende ZnS (sphalerite). The unit cell is twice as large, reflecting an alternation of Cu and Fe ions replacing Zn ions in adjacent cells. In contrast to the pyrite structure chalcopyrite has single S sulfide anions rather than disulfide pairs. Another difference is that the iron cation is not diamagnetic low spin Fe(II) as in pyrite. Copper metal can be extracted from the roasting of chalcopyrite, as shown in the following reaction: Although if roasted partially it produces and . Chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral that crystallizes in
Broken Hill ore deposit mining is concentrated in the Blackwood Open Cut, which commenced in 1973, and the Kintore Open Cut. Stope fill, plus remnant supergene silver and sulphide ore characterize the ore reserve. Pasminco Limited took over the leases of The Zinc Corporation, Limited, and New Broken Hill Consolidated Limited. Their main shafts included ZC, NBHC and Southern Cross. These ZC Mines Leases lie south of the MMM Mining Leases along the Broken Hill "line of lode". By the early 1950s the Broken Hill area had suffered a major drought of over 8 years which was close to shutting down the mining operation.