Van der Waals surface research use of a model showing the van der Waals surfaces of molecules. Related to the title concept are the ideas of a "van der Waals volume", V, and a "van der Waals surface area," abbreviated variously as A, vdWSA, VSA, and WSA. A van der Waals surface area is an abstract conception of the surface area of atoms or molecules from a mathematical estimation, either computing it from first principles or by integrating over a corresponding van der Waals volume. In simplest case, for a spherical monatomic gas, it is simply the computed surface area of a sphere of
Surface area area of the whole surface is then obtained by adding together the areas of the pieces, using additivity of surface area. The main formula can be specialized to different classes of surfaces, giving, in particular, formulas for areas of graphs "z" = "f"("x","y") and surfaces of revolution. One of the subtleties of surface area, as compared to arc length of curves, is that surface area cannot be defined simply as the limit of areas of polyhedral shapes approximating a given smooth surface. It was demonstrated by Hermann Schwarz that already for the cylinder, different choices of approximating flat surfaces can