Solid angle orientation formula_9, and distance from the viewer as: where the surface area of a sphere is . The solid angle of a cone with its apex at the apex of the solid angle, and with apex angle 2, is the area of a spherical cap on a unit sphere For small such that , this reduces to the area of a circle . The above is found by computing the following double integral using the unit surface element in spherical coordinates: This formula can also be derived without the use of calculus. Over 2200 years ago Archimedes proved that the
Surface energy individual molecule, and formula_25 is the pairwise intermolecular energy. Surface area can be determined by squaring the cube root of the volume of the molecule: Here, formula_27 corresponds to the molar mass of the molecule, formula_28 corresponds to the density, and formula_29 is Avogadro’s number. In order to determine the pairwise intermolecular energy, all intermolecular forces in the material must be broken. This allows thorough investigation of the interactions that occur for single molecules. During sublimation of a substance, intermolecular forces between molecules are broken, resulting in a change in the material from solid to gas. For this reason, considering