Solid angle orientation formula_9, and distance from the viewer as: where the surface area of a sphere is . The solid angle of a cone with its apex at the apex of the solid angle, and with apex angle 2, is the area of a spherical cap on a unit sphere For small such that , this reduces to the area of a circle . The above is found by computing the following double integral using the unit surface element in spherical coordinates: This formula can also be derived without the use of calculus. Over 2200 years ago Archimedes proved that the
BET theory physical adsorption of gas molecules. The total surface area formula_19 and the specific surface area formula_20 are given by where formula_5 is in units of volume which are also the units of the monolayer volume of the adsorbate gas, formula_24 is Avogadro's number, formula_25 the adsorption cross section of the adsorbing species, formula_26 the molar volume of the adsorbate gas, and formula_27 the mass of the solid sample or adsorbent. The BET theory can be derived similarly to the Langmuir theory, but by considering multilayered gas molecule adsorption, where it is not required for a layer to be completed before