Van der Waals surface research use of a model showing the van der Waals surfaces of molecules. Related to the title concept are the ideas of a "van der Waals volume", V, and a "van der Waals surface area," abbreviated variously as A, vdWSA, VSA, and WSA. A van der Waals surface area is an abstract conception of the surface area of atoms or molecules from a mathematical estimation, either computing it from first principles or by integrating over a corresponding van der Waals volume. In simplest case, for a spherical monatomic gas, it is simply the computed surface area of a sphere of
Finite volume method tensor. Again we can sub-divide the spatial domain into finite volumes or cells. For a particular cell, formula_42, we take the volume integral over the total volume of the cell, formula_43, which gives, On integrating the first term to get the "volume average" and applying the "divergence theorem" to the second, this yields where formula_46 represents the total surface area of the cell and formula_47 is a unit vector normal to the surface and pointing outward. So, finally, we are able to present the general result equivalent to (8), i.e. Again, values for the edge fluxes can be reconstructed by