Chalcopyrite is closely related to that of zinc blende ZnS (sphalerite). The unit cell is twice as large, reflecting an alternation of Cu and Fe ions replacing Zn ions in adjacent cells. In contrast to the pyrite structure chalcopyrite has single S sulfide anions rather than disulfide pairs. Another difference is that the iron cation is not diamagnetic low spin Fe(II) as in pyrite. Copper metal can be extracted from the roasting of chalcopyrite, as shown in the following reaction: Although if roasted partially it produces and . Chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral that crystallizes in
Broken Hill ore deposit hornblende schists. The ore consists of massive, recrystallised sphalerite-rich, galena-sphalerite and galena-rich sulfide lenses in folded horizons, known as No. 2 Lens Formation and No.3 Lens Formation. Both have distinctive metal ratios and gangue minerals. The ore boundaries are parallel to the bedding planes. According to Gustafson, "There is evidence that the ore has been introduced into an old, already folded, rock and has replaced certain favourable layers of that rock, particle by particle, with large tonnages of garnet, rhodonite, fluorite, marmatite (and wurtzite), galena, and other minerals that constitute the orebodies." The Potosi-Footwall Gneiss is found on both sides