Surface tension gases. The pressure inside an ideal (one surface) soap bubble can be derived from thermodynamic free energy considerations. At constant temperature and particle number, , the differential Helmholtz energy is given by where is the difference in pressure inside and outside of the bubble, and is the surface tension. In equilibrium, , and so, For a spherical bubble, the volume and surface area are given simply by and Substituting these relations into the previous expression, we find which is equivalent to the Young–Laplace equation when . For real soap bubbles, the pressure is doubled due to the presence of two
BET theory physical adsorption of gas molecules. The total surface area formula_19 and the specific surface area formula_20 are given by where formula_5 is in units of volume which are also the units of the monolayer volume of the adsorbate gas, formula_24 is Avogadro's number, formula_25 the adsorption cross section of the adsorbing species, formula_26 the molar volume of the adsorbate gas, and formula_27 the mass of the solid sample or adsorbent. The BET theory can be derived similarly to the Langmuir theory, but by considering multilayered gas molecule adsorption, where it is not required for a layer to be completed before