Surface tension gases. The pressure inside an ideal (one surface) soap bubble can be derived from thermodynamic free energy considerations. At constant temperature and particle number, , the differential Helmholtz energy is given by where is the difference in pressure inside and outside of the bubble, and is the surface tension. In equilibrium, , and so, For a spherical bubble, the volume and surface area are given simply by and Substituting these relations into the previous expression, we find which is equivalent to the Young–Laplace equation when . For real soap bubbles, the pressure is doubled due to the presence of two
Surface states expected. A simplified model of the crystal potential in one dimension can be sketched as shown in Figure 1 . In the crystal, the potential has the periodicity, "a", of the lattice while close to the surface it has to somehow attain the value of the vacuum level. The step potential (solid line) shown in Figure 1 is an oversimplification which is mostly convenient for simple model calculations. At a real surface the potential is influenced by image charges and the formation of surface dipoles and it rather looks as indicated by the dashed line. Given the potential in Figure