Metal carbonyl 18-electron complexes is sometimes catalysed by catalytic amounts of oxidants, via electron-transfer. Metal carbonyls react with reducing agents such as metallic sodium or sodium amalgam to give carbonylmetalate (or carbonylate) anions: For iron pentacarbonyl, one obtains the tetracarbonylferrate with loss of CO: Mercury can insert into the metal-metal bonds of some polynuclear metal carbonyls: The CO ligand is often susceptible to attack by nucleophiles. For example, trimethylamine oxide and bistrimethylsilylamide convert CO ligands to CO and CN, respectively. In the "Hieber base reaction", hydroxide ion attacks the CO ligand to give a metallacarboxylic acid, followed by the release of carbon
Mercury selenide mean that it is less toxic than elemental mercury or many organometallic mercury compounds. Selenium's ability to complex with mercury has been proposed as a reason for the lack of mercury toxicity in deep sea fish despite high mercury levels. Mercury selenide Mercury selenide (HgSe) is a chemical compound of mercury and selenium. It is a grey-black crystalline solid semi-metal with a sphalerite structure. The lattice constant is 0.608 nm. Mercury selenide can also refer to the following chemical compounds: HgSe and HgSe. HgSe is strictly mercury(II) selenide. HgSe occurs naturally as the mineral Tiemannite. Along with other II-VI compounds,