Acid mine drainage where the ore is a sulfide mineral or is associated with pyrite. In these cases the predominant metal ion may not be iron but rather zinc, copper, or nickel. The most commonly mined ore of copper, chalcopyrite, is itself a copper-iron-sulfide and occurs with a range of other sulfides. Thus, copper mines are often major culprits of acid mine drainage. At some mines, acidic drainage is detected within 2–5 years after mining begins, whereas at other mines, it is not detected for several decades. In addition, acidic drainage may be generated for decades or centuries after it is first detected.
Broken Hill ore deposit hornblende schists. The ore consists of massive, recrystallised sphalerite-rich, galena-sphalerite and galena-rich sulfide lenses in folded horizons, known as No. 2 Lens Formation and No.3 Lens Formation. Both have distinctive metal ratios and gangue minerals. The ore boundaries are parallel to the bedding planes. According to Gustafson, "There is evidence that the ore has been introduced into an old, already folded, rock and has replaced certain favourable layers of that rock, particle by particle, with large tonnages of garnet, rhodonite, fluorite, marmatite (and wurtzite), galena, and other minerals that constitute the orebodies." The Potosi-Footwall Gneiss is found on both sides