Chalcopyrite Chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral that crystallizes in the tetragonal system. It has the chemical formula CuFeS. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green tinged black. On exposure to air, chalcopyrite oxidises to a variety of oxides, hydroxides and sulfates. Associated copper minerals include the sulfides bornite (CuFeS), chalcocite (CuS), covellite (CuS), digenite (CuS); carbonates such as malachite and azurite, and rarely oxides such as cuprite (CuO). Chalcopyrite is rarely found in association with native copper. Natural
Carbonate-hosted lead-zinc ore deposits brines (10-30 wt.% NaCl equivalent) with pH's of 4.5-5 (buffered by host carbonates). This hydrothermal fluid may or may not carry the required sulfur to form sulfide minerals. Mobile hydrocarbons may have played a role in delivering reduced sulfur to certain MVT systems, while methane and other organic matter can potentially reduce sulfate carried by an acidic fluid. The ore fluid is suspected to be derived from clastic red bed sequences (potential metal source) that contain evaporites (potential sulfur source). Two potential transportation mechanisms for the metal-bearing ore fluid have been proposed. The first involves compaction of sediments in basins