Roca dels Bous (archaeological site) interesting archaeological site indeed. Furthermore, it is to be noted that the samples used for the 14C AMS dating were obtained from deep strata at the site. The oldest Neanderthal sites known in the nearby areas date back to around 40,000 BP. The first settlements attributed to “anatomically modern” Homo sapiens sapiens in Northern Spain are dated around 39,000-38,000 BP. All this would suggest that Neanderthals could have persisted in this particular area longer than previously believed, preceding the arrival of the first Homo sapiens to the area. Research work began in 1988. This wide period of time has contributed
Hydrogen isotope biogeochemistry non-equilibrium isotope effect in methane clumped isotopes from lab-cultured methanogens and field samples. These methane samples have relatively low abundance of clumped isotopologues, sometimes even lower than the stochastic distribution. This indicates that there are irreversible steps in enzymatic reactions during methanogenesis that fractionation against clumped isotopologues to create the depleted signal. Isotope clumping in methane has proven a robust proxy, and scientists are now moving towards higher-order alkane molecules like ethane for further work. Oil is generally a product of thermal breakdown of type I and type II kerogen during catagenesis. The deuterium content should reflect the source kerogen