Ore genesis with igneous rocks. The world's major copper deposits are formed within the granitic porphyry copper style. Copper is enriched by processes during crystallisation of the granite and forms as chalcopyrite — a sulfide mineral, which is carried up with the granite. Sometimes granites erupt to surface as volcanoes, and copper mineralisation forms during this phase when the granite and volcanic rocks cool via hydrothermal circulation. Sedimentary copper forms within ocean basins in sedimentary rocks. Generally this forms by brine from deeply buried sediments discharging into the deep sea, and precipitating copper and often lead and zinc sulfides directly onto the
Southeast Missouri Lead District sphalerite, and chalcopyrite. Gangue minerals associated with the economic minerals include pyrite, calcite, dolomite, and quartz. Specimens from the Lead Belt are highly prized by gem and mineral collectors and are found in museums worldwide. The ore minerals of the Lead Belt are primarily hosted by bacterial stromatolite reefs and associated oolitic rocks of the dolomitic Bonneterre Formation. This Cambrian age formation was deposited in a shallow sea around the Precambrian age St. Francois Mountains, which formed an island archipelago. Ore mineralization most likely occurred during the late Pennsylvanian and/or Permian periods when warm metal and petroleum bearing fluids from