Ore genesis with igneous rocks. The world's major copper deposits are formed within the granitic porphyry copper style. Copper is enriched by processes during crystallisation of the granite and forms as chalcopyrite — a sulfide mineral, which is carried up with the granite. Sometimes granites erupt to surface as volcanoes, and copper mineralisation forms during this phase when the granite and volcanic rocks cool via hydrothermal circulation. Sedimentary copper forms within ocean basins in sedimentary rocks. Generally this forms by brine from deeply buried sediments discharging into the deep sea, and precipitating copper and often lead and zinc sulfides directly onto the
Volcanogenic massive sulfide ore deposit sulfide consists of over 90% iron sulfide, mainly in the form of pyrite, with chalcopyrite, sphalerite and galena also being major constituents. Magnetite is present in minor amounts; as magnetite content increases, the ores grade into massive oxide deposits. The gangue (the uneconomic waste material) is mainly quartz and pyrite or pyrrhotite. Due to the high density of the deposits some have marked gravity anomalies (Neves-Corvo, Portugal) which is of use in exploration. Alteration haloes developed by VMS deposits are typically conical in shape, occur mostly stratigraphically below the original fluid flow location (not necessarily the ore itself), and are