Surface tension gases. The pressure inside an ideal (one surface) soap bubble can be derived from thermodynamic free energy considerations. At constant temperature and particle number, , the differential Helmholtz energy is given by where is the difference in pressure inside and outside of the bubble, and is the surface tension. In equilibrium, , and so, For a spherical bubble, the volume and surface area are given simply by and Substituting these relations into the previous expression, we find which is equivalent to the Young–Laplace equation when . For real soap bubbles, the pressure is doubled due to the presence of two
Volume as volume divided by mass. Specific volume is a concept important in thermodynamics where the volume of a working fluid is often an important parameter of a system being studied. The volumetric flow rate in fluid dynamics is the volume of fluid which passes through a given surface per unit time (for example cubic meters per second [m s]). In calculus, a branch of mathematics, the volume of a region "D" in R is given by a triple integral of the constant function formula_1 and is usually written as: The volume integral in cylindrical coordinates is and the volume integral