Ore genesis with igneous rocks. The world's major copper deposits are formed within the granitic porphyry copper style. Copper is enriched by processes during crystallisation of the granite and forms as chalcopyrite — a sulfide mineral, which is carried up with the granite. Sometimes granites erupt to surface as volcanoes, and copper mineralisation forms during this phase when the granite and volcanic rocks cool via hydrothermal circulation. Sedimentary copper forms within ocean basins in sedimentary rocks. Generally this forms by brine from deeply buried sediments discharging into the deep sea, and precipitating copper and often lead and zinc sulfides directly onto the
Carbonate-hosted lead-zinc ore deposits brines (10-30 wt.% NaCl equivalent) with pH's of 4.5-5 (buffered by host carbonates). This hydrothermal fluid may or may not carry the required sulfur to form sulfide minerals. Mobile hydrocarbons may have played a role in delivering reduced sulfur to certain MVT systems, while methane and other organic matter can potentially reduce sulfate carried by an acidic fluid. The ore fluid is suspected to be derived from clastic red bed sequences (potential metal source) that contain evaporites (potential sulfur source). Two potential transportation mechanisms for the metal-bearing ore fluid have been proposed. The first involves compaction of sediments in basins