Chalcopyrite is closely related to that of zinc blende ZnS (sphalerite). The unit cell is twice as large, reflecting an alternation of Cu and Fe ions replacing Zn ions in adjacent cells. In contrast to the pyrite structure chalcopyrite has single S sulfide anions rather than disulfide pairs. Another difference is that the iron cation is not diamagnetic low spin Fe(II) as in pyrite. Copper metal can be extracted from the roasting of chalcopyrite, as shown in the following reaction: Although if roasted partially it produces and . Chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral that crystallizes in
Broken Hill ore deposit of the main lode. The ore often consists up to 100% lead-zinc sulfides, with little or no pyrite, chalcopyrite or gangue sulfides. The footwall to the mineralization is a psammopelite gneiss, consisting of feldspar, quartz, garnet, biotite and amphibole, with a pelite gneiss on the hanging wall. The footwall gneiss contains anomalous mineral chemistries including a rare lead-rich feldspar and manganese-rich garnet chemistries. Ore is predominantly hosted at this stratigraphic break, but much of the ore body is structurally remobilised or offset into both the hangingwall and footwall, and the geometry of the ore deposit is particularly complex on the