Van der Waals surface research use of a model showing the van der Waals surfaces of molecules. Related to the title concept are the ideas of a "van der Waals volume", V, and a "van der Waals surface area," abbreviated variously as A, vdWSA, VSA, and WSA. A van der Waals surface area is an abstract conception of the surface area of atoms or molecules from a mathematical estimation, either computing it from first principles or by integrating over a corresponding van der Waals volume. In simplest case, for a spherical monatomic gas, it is simply the computed surface area of a sphere of
Capillary surface and other energy potentials absent, the energy of the system is where the subscripts formula_40, formula_41, and formula_42 respectively indicate the liquid–gas, solid–gas, and solid–liquid interfaces. Note that inclusion of gravity would require consideration of the volume enclosed by the capillary surface and the solid walls. Typically the surface tension values between the solid–gas and solid–liquid interfaces are not known. This does not pose a problem; since only changes in energy are of primary interest. If the net solid area formula_43 is a constant, and the contact angle is known, it may be shown that (again, for two different fluids