Surface tension gases. The pressure inside an ideal (one surface) soap bubble can be derived from thermodynamic free energy considerations. At constant temperature and particle number, , the differential Helmholtz energy is given by where is the difference in pressure inside and outside of the bubble, and is the surface tension. In equilibrium, , and so, For a spherical bubble, the volume and surface area are given simply by and Substituting these relations into the previous expression, we find which is equivalent to the Young–Laplace equation when . For real soap bubbles, the pressure is doubled due to the presence of two
Control volume Control volume In continuum mechanics and thermodynamics, a control volume is a mathematical abstraction employed in the process of creating mathematical models of physical processes. In an inertial frame of reference, it is a volume fixed in space or moving with constant flow velocity through which the continuum (gas, liquid or solid) flows. The surface enclosing the control volume is referred to as the control surface. At steady state, a control volume can be thought of as an arbitrary volume in which the mass of the continuum remains constant. As a continuum moves through the control volume, the mass entering