Ozone layer bromine (Br). While there are natural sources for all of these species, the concentrations of chlorine and bromine increased markedly in recent decades because of the release of large quantities of man-made organohalogen compounds, especially chlorofluorocarbons (CFCs) and bromofluorocarbons. These highly stable compounds are capable of surviving the rise to the stratosphere, where Cl and Br radicals are liberated by the action of ultraviolet light. Each radical is then free to initiate and catalyze a chain reaction capable of breaking down over 100,000 ozone molecules. By 2009, nitrous oxide was the largest ozone-depleting substance (ODS) emitted through human activities. The
Planetary boundary layer Planetary boundary layer In meteorology the planetary boundary layer (PBL), also known as the atmospheric boundary layer (ABL) or "peplosphere", is the lowest part of the atmosphere and its behavior is directly influenced by its contact with a planetary surface . On Earth it usually responds to changes in surface radiative forcing in an hour or less. In this layer physical quantities such as flow velocity, temperature, moisture, etc., display rapid fluctuations (turbulence) and vertical mixing is strong. Above the PBL is the "free atmosphere" where the wind is approximately geostrophic (parallel to the isobars) , while within the PBL