Radium of radium Curie used the residues after extraction of uranium from pitchblende. The uranium had been extracted by dissolution in sulfuric acid leaving radium sulfate, which is similar to barium sulfate but even less soluble in the residues. The residues also contained rather substantial amounts of barium sulfate which thus acted as a carrier for the radium sulfate. The first steps of the radium extraction process involved boiling with sodium hydroxide followed by hydrochloric acid treatment to remove as much as possible of other compounds. The remaining residue was then treated with sodium carbonate to convert the barium sulfate into
Stephanie Horovitz radiochemistry. It predicted that lead resulting from the radioactive decay of uranium or thorium would have different atomic weights than typical lead. Early experimental data was not considered authoritative by analytical chemists. Hönigschmid had studied under leading expert Theodore Williams Richards at Harvard and his work in determining precise atomic weights was well respected. Horovitz isolated lead from uranium-rich pitchblende samples from the St. Joachmistal mine. Her gravimetric analysis to the thousandth of a gram proved that lead created from the radioactive decay of uranium had a lower atomic weight than typical lead. This was the first widely-accepted experimental proof