Radium of radium Curie used the residues after extraction of uranium from pitchblende. The uranium had been extracted by dissolution in sulfuric acid leaving radium sulfate, which is similar to barium sulfate but even less soluble in the residues. The residues also contained rather substantial amounts of barium sulfate which thus acted as a carrier for the radium sulfate. The first steps of the radium extraction process involved boiling with sodium hydroxide followed by hydrochloric acid treatment to remove as much as possible of other compounds. The remaining residue was then treated with sodium carbonate to convert the barium sulfate into
Period 7 element corresponding to the filling of the 5f electron shell; actinium, a d-block element, is also generally considered an actinide. In comparison with the lanthanides, also mostly f-block elements, the actinides show much more variable valence. Of the actinides, thorium and uranium occur naturally in substantial, primordial, quantities. The radioactive decay of uranium produces transient amounts of actinium, protactinium and plutonium, and atoms of neptunium are occasionally produced from transmutation reactions in uranium ores. The other actinides are purely synthetic elements, although the first six actinides after plutonium would have been produced during the Oklo phenomenon (and long since decayed away),