Polonium the Curies while they were investigating the cause of pitchblende radioactivity. Pitchblende, after removal of the radioactive elements uranium and thorium, was more radioactive than the uranium and thorium combined. This spurred the Curies to search for additional radioactive elements. They first separated out polonium from pitchblende in July 1898, and five months later, also isolated radium. German scientist Willy Marckwald successfully isolated 3 milligrams of polonium in 1902, though at the time he believed it was a new element, which he dubbed "radio-tellurium", and it was not until 1905 that it was demonstrated to be the same as polonium.
Period 7 element corresponding to the filling of the 5f electron shell; actinium, a d-block element, is also generally considered an actinide. In comparison with the lanthanides, also mostly f-block elements, the actinides show much more variable valence. Of the actinides, thorium and uranium occur naturally in substantial, primordial, quantities. The radioactive decay of uranium produces transient amounts of actinium, protactinium and plutonium, and atoms of neptunium are occasionally produced from transmutation reactions in uranium ores. The other actinides are purely synthetic elements, although the first six actinides after plutonium would have been produced during the Oklo phenomenon (and long since decayed away),