Radium of radium Curie used the residues after extraction of uranium from pitchblende. The uranium had been extracted by dissolution in sulfuric acid leaving radium sulfate, which is similar to barium sulfate but even less soluble in the residues. The residues also contained rather substantial amounts of barium sulfate which thus acted as a carrier for the radium sulfate. The first steps of the radium extraction process involved boiling with sodium hydroxide followed by hydrochloric acid treatment to remove as much as possible of other compounds. The remaining residue was then treated with sodium carbonate to convert the barium sulfate into
Synthetic element of the Earth. Only minute traces of technetium occur naturally in the Earth's crust—as a spontaneous fission product of uranium-238 or by neutron capture in molybdenum ores—but technetium is present naturally in red giant stars. The first discovered purely synthetic element was curium, synthesized in 1944 by Glenn T. Seaborg, Ralph A. James, and Albert Ghiorso by bombarding plutonium with alpha particles. The discoveries of americium, berkelium, and californium followed soon. Einsteinium and fermium were discovered by a team of scientists led by Albert Ghiorso in 1952 while studying the radioactive debris from the detonation of the first hydrogen bomb.