Fire extinguisher class D fire extinguisher agents available; some will handle multiple types of metals, others will not. TMB was used experimentally by the US Air Force, specifically with regard to B-52 engine assemblies, and was tested in modified 10-gallon wheeled CBM extinguishers. Other agents were added to suppress the methanol flare up, such as chlorobromomethane (CBM), Halon 2402, and Halon 1211, with varied success. Halon 1211 was the most successful, and the combined TMB pressurized with halon 1211 and nitrogen was called Boralon was used experimentally by the Los Alamos National Laboratory for use on atomic metals, using sealed cylinder extinguishers
Fire extinguisher are some of the most collectable extinguishers as they cross into both the apparatus restoration and fire extinguisher areas of interest. In 1910, The Pyrene Manufacturing Company of Delaware filed a patent for using carbon tetrachloride (CTC, or CCl) to extinguish fires. The liquid vaporized and extinguished the flames by inhibiting the chemical chain reaction of the combustion process (it was an early 20th-century presupposition that the fire suppression ability of carbon tetrachloride relied on oxygen removal). In 1911, they patented a small, portable extinguisher that used the chemical. This consisted of a brass or chrome container with an integrated