Fire extinguisher in the early 60s and Purple-K being developed by the US Navy in the late 1960s. Manually applied dry agents such as graphite for class D (metal) fires had existed since WWII, but it wasn't until 1949 that Ansul introduced a pressurized extinguisher using an external CO2 cartridge to discharge the agent. Met-L-X (sodium chloride) was the first extinguisher developed in the US, with graphite, copper, and several other types being developed later. In the 1970s, Halon 1211 came over to the United States from Europe where it had been used since the late 40s or early 50s. Halon 1301
Fire extinguisher equipment (such as first aid kits). Most licensing authorities have regulations describing the standard appearance of these signs (e.g., text height, pictographs used and so on). Photoluminescent fire extinguisher signs are made with nontoxic photoluminescent phosphor that absorbs ambient light and releases it slowly in dark conditions – the sign "glows in the dark". Such signs are independent of an external power supply, and so offer a low-cost, reliable means of indicating the position of emergency equipment in dark or smoky conditions. The luminance performance for life safety appliance location signs should meet the requirements of International Standard ISO 17398