Fire extinguisher in the early 60s and Purple-K being developed by the US Navy in the late 1960s. Manually applied dry agents such as graphite for class D (metal) fires had existed since WWII, but it wasn't until 1949 that Ansul introduced a pressurized extinguisher using an external CO2 cartridge to discharge the agent. Met-L-X (sodium chloride) was the first extinguisher developed in the US, with graphite, copper, and several other types being developed later. In the 1970s, Halon 1211 came over to the United States from Europe where it had been used since the late 40s or early 50s. Halon 1301
Fire extinguisher gas that works by inhibiting the chain reaction of the fire and is the most toxic of the vaporizing liquids, used until the 1960s. The vapor and combustion by-products of all vaporizing liquids were highly toxic and could cause death in confined spaces. The carbon dioxide (CO) extinguisher was invented (at least in the US) by the Walter Kidde Company in 1924 in response to Bell Telephone's request for an electrically non-conductive chemical for extinguishing the previously difficult-to-extinguish fires in telephone switchboards. It consisted of a tall metal cylinder containing of CO with a wheel valve and a woven brass,