Formic anhydride can be isolated by low-temperature, low-pressure distillation, but decomposes on heating above room temperature. It decomposes into formic acid and carbon monoxide. The decomposition of formic anhydride may be catalyzed by formic acid. Formic anhydride can be detected in the gas-phase reaction of ozone with ethylene. The molecule is planar in the gas phase. Formic anhydride Formic anhydride, also called methanoic anhydride, is an organic compound with the chemical formula and a structural formula of (H(C=O)−)O. It can be viewed as the anhydride of formic acid (HCOOH). Formic anhydride can be obtained by reaction of formyl fluoride with sodium formate
Chlorosulfuric acid Chlorosulfuric acid Chlorosulfuric acid (IUPAC name: sulfurochloridic acid) is the inorganic compound with the formula HSOCl. It is also known as chlorosulfonic acid, being the sulfonic acid of chlorine. It is a distillable, colorless liquid which is hygroscopic and a powerful lachrymator. Salts and esters of chlorosulfuric acid are known as chlorosulfates. Chlorosulfuric acid is a tetrahedral molecule. The formula is more descriptively written SO(OH)Cl, but HSOCl is traditional. It is an intermediate, chemically and conceptually, between sulfuryl chloride (SOCl) and sulfuric acid (HSO). The compound is rarely obtained pure. Upon standing with excess sulfur trioxide, it decomposes to pyrosulfuryl