Formic anhydride can be isolated by low-temperature, low-pressure distillation, but decomposes on heating above room temperature. It decomposes into formic acid and carbon monoxide. The decomposition of formic anhydride may be catalyzed by formic acid. Formic anhydride can be detected in the gas-phase reaction of ozone with ethylene. The molecule is planar in the gas phase. Formic anhydride Formic anhydride, also called methanoic anhydride, is an organic compound with the chemical formula and a structural formula of (H(C=O)−)O. It can be viewed as the anhydride of formic acid (HCOOH). Formic anhydride can be obtained by reaction of formyl fluoride with sodium formate
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