Effective mass (solid-state physics) from both sides gives where is the th element of , is the th element of , and are the th and th elements of , respectively, and is the total energy of the particle according to the Planck–Einstein relation. The index is contracted by the use of Einstein notation (there is an implicit summation over ). Since Newton's second law uses the inertial mass (not the gravitational mass), we can identify the inverse of this mass in the equation above as the tensor This tensor expresses the change in group velocity due to a change in crystal momentum. Its
Mass spectrometry the time they take to reach the detector. If the particles all have the same charge, the kinetic energies tends to be identical, and their velocities, in this case, will depend only on their masses. Ions with a lower mass will reach the detector first. However, in reality, even particles with the same m/z can arrive at different times at the detector, because they have different initial velocities. The initial velocity is not dependent on the mass of the ion what becomes a problem for the TOF-MS. The difference in initial velocity turns into difference in the final velocity. In