Fire extinguisher in the early 60s and Purple-K being developed by the US Navy in the late 1960s. Manually applied dry agents such as graphite for class D (metal) fires had existed since WWII, but it wasn't until 1949 that Ansul introduced a pressurized extinguisher using an external CO2 cartridge to discharge the agent. Met-L-X (sodium chloride) was the first extinguisher developed in the US, with graphite, copper, and several other types being developed later. In the 1970s, Halon 1211 came over to the United States from Europe where it had been used since the late 40s or early 50s. Halon 1301
Fire extinguisher in 1881 by Almon M. Granger. His extinguisher used the reaction between sodium bicarbonate solution and sulfuric acid to expel pressurized water onto a fire. A vial of concentrated sulfuric acid was suspended in the cylinder. Depending on the type of extinguisher, the vial of acid could be broken in one of two ways. One used a plunger to break the acid vial, while the second released a lead stopple that held the vial closed. Once the acid was mixed with the bicarbonate solution, carbon dioxide gas was expelled and thereby pressurized the water. The pressurized water was forced from