Electrolytic cell Electrolytic cell An electrolytic cell is an electrochemical cell that drives a non-spontaneous redox reaction through the application of electrical energy. They are often used to decompose chemical compounds, in a process called electrolysis—the Greek word lysis means "to break up". Important examples of electrolysis are the decomposition of water into hydrogen and oxygen, and bauxite into aluminium and other chemicals. Electroplating (e.g. of copper, silver, nickel or chromium) is done using an electrolytic cell. Electrolysis is a technique that uses a direct electric current (DC). An electrolytic cell has three component parts: an electrolyte and two electrodes (a cathode
Fluoride selective electrode where the fluoride transport number is 1. As transference of charge through the crystal is almost exclusively due to fluoride, the electrode is highly specific to fluoride. The only ion which significantly interferes is hydroxide (OH). Generally such "alkaline error" can be avoided by buffering the sample to a pH below 7. The cell diagram of a typical experimental arrangement is: where: Some commercially available reference electrodes have an internal junction which minimizes the liquid junction potential between the sample solution and the electrolyte in the reference electrode (KCl). The internal electrolyte is at fixed composition and the electrode response