Electrolysis of water a small-scale electrolytic cell. It consists of three joined upright cylinders. The inner cylinder is open at the top to allow the addition of water and the electrolyte. A platinum electrode is placed at the bottom of each of the two side cylinders, connected to the positive and negative terminals of a source of electricity. When current is run through the Hofmann voltameter, gaseous oxygen forms at the anode (positive) and gaseous hydrogen at the cathode (negative). Each gas displaces water and collects at the top of the two outer tubes, where it can be drawn off with a stopcock.
Standard hydrogen electrode Standard hydrogen electrode The Standard hydrogen electrode (abbreviated SHE), is a redox electrode which forms the basis of the thermodynamic scale of oxidation-reduction potentials. Its absolute electrode potential is estimated to be at 25 °C, but to form a basis for comparison with all other electrode reactions, hydrogen's standard electrode potential ("E") is declared to be zero volts only at 298K. Potentials of any other electrodes are compared with that of the standard hydrogen electrode at the same temperature. Hydrogen electrode is based on the redox half cell: This redox reaction occurs at a platinized platinum electrode. The electrode is