Electrode potential electrode component. In a cell, there is an electrode potential for the cathode and an electrode potential for the anode. The difference between the two electrode potentials equals the cell potential: The measured electrode potential may be either that at equilibrium on the working electrode ("reversible potential"), or a potential with a non-zero net reaction on the working electrode but zero net current ("corrosion potential", "mixed potential"), or a potential with a non-zero net current on the working electrode (like in galvanic corrosion or voltammetry). Reversible potentials can be sometimes converted to the standard electrode potential for a given electroactive
Auxiliary electrode species which exhibits reversible redox behavior. Auxiliary electrodes are often fabricated from electrochemically inert materials such as gold, platinum, or carbon. Auxiliary electrode The auxiliary electrode, often also called the counter electrode, is an electrode used in a three electrode electrochemical cell for voltammetric analysis or other reactions in which an electric current is expected to flow. The auxiliary electrode is distinct from the reference electrode, which establishes the electrical potential against which other potentials may be measured, and the working electrode, at which the cell reaction takes place. In a two-electrode system, either a known current or potential is