Electrode potential Electrode potential Electrode potential, "E", in chemistry or electrochemistry, according to a IUPAC definition, is the electromotive force of a cell built of two electrodes: The SHE is defined to have a potential of 0 V, so the signed cell potential from the above setup is SHE is cathode and electrode is anode Electrode potential appears at the interface between an electrode and electrolyte due to the transfer of charged species across the interface, specific adsorption of ions at the interface, and specific adsorption/orientation of polar molecules, including those of the solvent. Electrode potential is the electric potential on an
Standard electrode potential potentials are independent of the number of electrons transferred —they are expressed in volts, which measure energy per electron transferred—and so the two electrode potentials can be simply combined to give the overall "cell" potential even if different numbers of electrons are involved in the two electrode reactions. For practical measurements, the electrode in question is connected to the positive terminal of the electrometer, while SHE is connected to the negative terminal. The larger the value of the standard reduction potentials, the easier it is for the element to be reduced (accept electrons); in other words, they are better oxidizing