Electrode Electrode An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or air). The word was coined by William Whewell at the request of the scientist Michael Faraday from two Greek words: "elektron", meaning amber (from which the word electricity is derived), and "hodos", a way. The electrophore, invented by Johan Wilcke, was an early version of an electrode used to study static electricity. An electrode in an electrochemical cell is referred to as either an "anode" or a "cathode" (words that were coined by William
Auxiliary electrode whenever the working electrode is operating as an anode and vice versa. The auxiliary electrode often has a surface area much larger than that of the working electrode to ensure that the half-reaction occurring at the auxiliary electrode can occur fast enough so as not to limit the process at the working electrode. When a three electrode cell is used to perform electroanalytical chemistry, the auxiliary electrode, along with the working electrode, provides circuit over which current is either applied or measured. Here, the potential of the auxiliary electrode is usually not measured and is adjusted so as to balance