Electrolytic capacitor An unambiguous and general specification of tolerable transients or peak voltages is not possible. In every case transients arise, the application has to be approved very carefully. Electrolytic capacitors with solid manganese oxide or polymer electrolyte, and aluminum as well as tantalum electrolytic capacitors can not withstand transients or peak voltages higher than surge voltage. Transients for this type of e-caps may destroy the components. Standard electrolytic capacitors, and aluminum as well as tantalum and niobium electrolytic capacitors are polarized and generally require the anode electrode voltage to be positive relative to the cathode voltage. Nevertheless, electrolytic capacitors can withstand
Electrode potential drawing): In case of non-zero net current on the electrode, it is essential to minimize the ohmic IR-drop in the electrolyte, e.g., by positioning the reference electrode near the surface of the working electrode (e.g., see Luggin capillary), or by using a supporting electrolyte of sufficiently high conductivity. The potential measurements are performed with the positive terminal of the electrometer connected to working electrode and the negative terminal to the reference electrode. Historically, two conventions for sign for the electrode potential have formed: In 1953 in Stockholm IUPAC recognized that either of the conventions is permissible; however, it unanimously recommended