Standard electrode potential to produce an electric potential, Gibbs free energy Δ"G"° must be negative, in accordance with the following equation: where "n" is number of moles of electrons per mole of products and "F" is the Faraday constant, ~96485 C/mol. As such, the following rules apply: Thus in order to have a spontaneous reaction (ΔG° < 0), "E"° must be positive, where: where "E"° is the standard potential at the anode and "E"° is the standard potential at the cathode as given in the table of standard electrode potential. Standard electrode potential In electrochemistry, it is defined as the measure of the
Electrolytic capacitor are therefore smaller than aluminium electrolytic capacitors. In practice different safety margins to reach reliable components makes a comparison difficult. The anodically generated insulating oxide layer is destroyed if the polarity of the applied voltage changes. Electrolytic capacitors are based on the principle of a "plate capacitor" whose capacitance increases with larger electrode area A, higher dielectric permittivity ε, and thinner dielectric (d). The dielectric thickness of electrolytic capacitors is very small, in the range of nanometers per volt. On the other hand, the voltage strengths of these oxide layers are quite high. With this very thin dielectric oxide layer