Standard electrode potential Standard electrode potential In electrochemistry, it is defined as the measure of the individual potential of reversible electrode at standard state with ions at an effective concentration of 1mol dm-3 at the pressure of 1 atm The basis for an electrochemical cell, such as the galvanic cell, is always a redox reaction which can be broken down into two half-reactions: oxidation at anode (loss of electron) and reduction at cathode (gain of electron). Electricity is generated due to electric potential difference between two electrodes. This potential difference is created as a result of the difference between individual potentials of the
Silver chloride electrode or electrochemically by oxidising the silver in a chloride solution. A porous plug on one end allows contact between the field environment with the silver chloride electrolyte. An insulated lead wire connects the silver rod with measuring instruments. A voltmeter negative lead is connected to the test wire. The electrode body contains potassium chloride to stabilize the silver chloride concentration. When working in seawater, this body can be removed and the chloride concentration is fixed by the stable salinity of the water. The potential of a silver:silver chloride reference electrode with respect to the standard hydrogen electrode depends on the