Electrolytic capacitor to a smooth surface of the same area or the same volume. By applying a positive voltage to the above-mentioned anode material in an electrolytic bath an oxide barrier layer with a thickness corresponding to the applied voltage will be formed (formation). This oxide layer acts as dielectric in an electrolytic capacitor. The properties of this oxide layers are given in the following table: After forming a dielectric oxide on the rough anode structure, a counter electrode has to match the rough insulating oxide surface. This is accomplished by the electrolyte, which acts as the cathode electrode of an electrolytic
Electrolytic capacitor are therefore smaller than aluminium electrolytic capacitors. In practice different safety margins to reach reliable components makes a comparison difficult. The anodically generated insulating oxide layer is destroyed if the polarity of the applied voltage changes. Electrolytic capacitors are based on the principle of a "plate capacitor" whose capacitance increases with larger electrode area A, higher dielectric permittivity ε, and thinner dielectric (d). The dielectric thickness of electrolytic capacitors is very small, in the range of nanometers per volt. On the other hand, the voltage strengths of these oxide layers are quite high. With this very thin dielectric oxide layer