Standard electrode potential Standard electrode potential In electrochemistry, it is defined as the measure of the individual potential of reversible electrode at standard state with ions at an effective concentration of 1mol dm-3 at the pressure of 1 atm The basis for an electrochemical cell, such as the galvanic cell, is always a redox reaction which can be broken down into two half-reactions: oxidation at anode (loss of electron) and reduction at cathode (gain of electron). Electricity is generated due to electric potential difference between two electrodes. This potential difference is created as a result of the difference between individual potentials of the
Electrode potential that only the magnitude expressed according to the convention (2) be called "the electrode potential". To avoid possible ambiguities, the electrode potential thus defined can also be referred to as "Gibbs–Stockholm electrode potential". In both conventions, the standard hydrogen electrode is defined to have a potential of 0 V. Both conventions also agree on the sign of "E" for a half-cell reaction when it is written as a reduction. The main difference between the two conventions is that upon reversing the direction of a half-cell reaction "as written", according to convention (1) the sign of "E" also switches, whereas in