Electrolytic capacitor Electrolytic capacitor An electrolytic capacitor (abbreviated e-cap) is a polarized capacitor whose anode or positive plate is made of a metal that forms an insulating oxide layer through anodization. This oxide layer acts as the dielectric of the capacitor. A solid, liquid, or gel electrolyte covers the surface of this oxide layer, serving as the (cathode) or negative plate of the capacitor. Due to their very thin dielectric oxide layer and enlarged anode surface, electrolytic capacitors have a much higher capacitance-voltage (CV) product per unit volume compared to ceramic capacitors or film capacitors, and so can have large capacitance values.
Auxiliary electrode whenever the working electrode is operating as an anode and vice versa. The auxiliary electrode often has a surface area much larger than that of the working electrode to ensure that the half-reaction occurring at the auxiliary electrode can occur fast enough so as not to limit the process at the working electrode. When a three electrode cell is used to perform electroanalytical chemistry, the auxiliary electrode, along with the working electrode, provides circuit over which current is either applied or measured. Here, the potential of the auxiliary electrode is usually not measured and is adjusted so as to balance