Galvanic cell bridge zinc ions leave and anions enter the zinc half-cell. In the copper half-cell, the copper ions plate onto the copper electrode (reduction), taking up electrons that leave the external conductor. Since the Cu ions (cations) plate onto the copper electrode, the latter is called the cathode. Correspondingly the zinc electrode is the anode. The electrochemical reaction is: In addition, electrons flow through the external conductor, which is the primary application of the galvanic cell. As discussed under #Cell voltage, the emf of the cell is the difference of the half-cell potentials, a measure of the relative ease of dissolution
Dropping mercury electrode way. Each droplet grows until it reaches a diameter of about a millimeter and releases. The released droplet is no longer in contact with the working electrode whose contact is above the capillary. As the electrode is used mercury collects in the bottom of the cell. In some cell designs this mercury pool is connected to a lead and used as the cell's auxiliary electrode. Each released drop is immediately followed by the formation of another drop. The drops are generally produced at a rate of about 0.2 Hz. A major advantage of the DME is that each drop has