Electrode potential electrode component. In a cell, there is an electrode potential for the cathode and an electrode potential for the anode. The difference between the two electrode potentials equals the cell potential: The measured electrode potential may be either that at equilibrium on the working electrode ("reversible potential"), or a potential with a non-zero net reaction on the working electrode but zero net current ("corrosion potential", "mixed potential"), or a potential with a non-zero net current on the working electrode (like in galvanic corrosion or voltammetry). Reversible potentials can be sometimes converted to the standard electrode potential for a given electroactive
Half-cell a standard hydrogen half-cell, connected by a salt bridge. The standard hydrogen half-cell: The half-cells of a Daniell cell: Standard electrode potential (data page) Half-cell A half-cell is a structure that contains a conductive electrode and a surrounding conductive electrolyte separated by a naturally occurring Helmholtz double layer. Chemical reactions within this layer momentarily pump electric charges between the electrode and the electrolyte, resulting in a potential difference between the electrode and the electrolyte. The typical anode reaction involves a metal atom in the electrode dissolved and transported as a positive ion across the double layer, causing the electrolyte to