S-type star are two distinct classes of S-type stars: intrinsic S stars; and extrinsic S stars. The presence of Technetium is used to distinguish the two classes, only being found in the intrinsic S-type stars. Intrinsic S-type stars are thermal pulsing asymptotic giant branch (TP-AGB) stars. AGB stars have inert carbon-oxygen cores and undergo fusion both in an inner helium shell and an outer hydrogen shell. They are large cool M class giants. The thermal pulses, created by flashes from the helium shell, cause strong convection within the upper layers of the star. These pulses become stronger as the star evolves and
Red giant temperature and pressure are adequate to cause fusion to resume in a shell around the core. The outer layers of the star then expand greatly, thus beginning the red-giant phase of the star's life. As the star expands, the energy produced in the burning shell of the star is spread over a much larger surface area, resulting in a lower surface temperature and a shift in the star's visible light output towards the red—hence it becomes a "red giant". At this time, the star is said to be ascending the red-giant branch of the Hertzsprung–Russell (H–R) diagram. The evolutionary path