Electrolytic cell drive current in opposite directions. The cell with the larger voltage is discharged, making it a galvanic cell, so P is the cathode and N is the anode as described above. But, the cell with the smaller voltage charges, making it an electrolytic cell. In the electrolytic cell, negative ions are driven towards P and positive ions towards N. Thus, the P electrode of the electrolytic cell meets the definition of anode while the electrolytic cell is being charged. Similarly, the N electrode of the electrolytic cell is the cathode while the electrolytic cell is being charged. As already noted,
Electrolytic capacitor are therefore smaller than aluminium electrolytic capacitors. In practice different safety margins to reach reliable components makes a comparison difficult. The anodically generated insulating oxide layer is destroyed if the polarity of the applied voltage changes. Electrolytic capacitors are based on the principle of a "plate capacitor" whose capacitance increases with larger electrode area A, higher dielectric permittivity ε, and thinner dielectric (d). The dielectric thickness of electrolytic capacitors is very small, in the range of nanometers per volt. On the other hand, the voltage strengths of these oxide layers are quite high. With this very thin dielectric oxide layer