Electrolytic cell electrons from the cathode and deposits on the cathode as sodium metal. NaCl dissolved in water can also be electrolyzed. The anode oxidizes chloride ions (Cl), and Cl gas is produced. However, at the cathode, instead of sodium ions being reduced to sodium metal, water molecules are reduced to hydroxide ions (OH) and hydrogen gas (H). The overall result of the electrolysis is the production of chlorine gas and aqueous sodium hydroxide (NaOH) solution. Commercially, electrolytic cells are used in electrorefining and electrowinning of several non-ferrous metals. Almost all high-purity aluminium, copper, zinc and lead is produced industrially in electrolytic
Electrode potential drawing): In case of non-zero net current on the electrode, it is essential to minimize the ohmic IR-drop in the electrolyte, e.g., by positioning the reference electrode near the surface of the working electrode (e.g., see Luggin capillary), or by using a supporting electrolyte of sufficiently high conductivity. The potential measurements are performed with the positive terminal of the electrometer connected to working electrode and the negative terminal to the reference electrode. Historically, two conventions for sign for the electrode potential have formed: In 1953 in Stockholm IUPAC recognized that either of the conventions is permissible; however, it unanimously recommended