Electrolytic capacitor An unambiguous and general specification of tolerable transients or peak voltages is not possible. In every case transients arise, the application has to be approved very carefully. Electrolytic capacitors with solid manganese oxide or polymer electrolyte, and aluminum as well as tantalum electrolytic capacitors can not withstand transients or peak voltages higher than surge voltage. Transients for this type of e-caps may destroy the components. Standard electrolytic capacitors, and aluminum as well as tantalum and niobium electrolytic capacitors are polarized and generally require the anode electrode voltage to be positive relative to the cathode voltage. Nevertheless, electrolytic capacitors can withstand
Fluoride selective electrode where the fluoride transport number is 1. As transference of charge through the crystal is almost exclusively due to fluoride, the electrode is highly specific to fluoride. The only ion which significantly interferes is hydroxide (OH). Generally such "alkaline error" can be avoided by buffering the sample to a pH below 7. The cell diagram of a typical experimental arrangement is: where: Some commercially available reference electrodes have an internal junction which minimizes the liquid junction potential between the sample solution and the electrolyte in the reference electrode (KCl). The internal electrolyte is at fixed composition and the electrode response