Electrode reaction cannot be reversed, and the identities of the anode and cathode are therefore fixed. The anode is always the negative electrode. The cell can be discharged but not recharged. A secondary cell, for example a rechargeable battery, is a cell in which the chemical reactions are reversible. When the cell is being charged, the anode becomes the positive (+) and the cathode the negative (−) electrode. This is also the case in an electrolytic cell. When the cell is being discharged, it behaves like a primary cell, with the anode as the negative and the cathode as the positive
Electrolytic capacitor are therefore smaller than aluminium electrolytic capacitors. In practice different safety margins to reach reliable components makes a comparison difficult. The anodically generated insulating oxide layer is destroyed if the polarity of the applied voltage changes. Electrolytic capacitors are based on the principle of a "plate capacitor" whose capacitance increases with larger electrode area A, higher dielectric permittivity ε, and thinner dielectric (d). The dielectric thickness of electrolytic capacitors is very small, in the range of nanometers per volt. On the other hand, the voltage strengths of these oxide layers are quite high. With this very thin dielectric oxide layer