Ultraviolet divergence short distances. The name comes from the earliest example of such a divergence, the "ultraviolet catastrophe" first encountered in understanding blackbody radiation. According to classical physics at the end of the nineteenth century, the quantity of radiation in the form of light released at any specific wavelength should increase with decreasing wavelength—in particular, there should be considerably more ultraviolet light released from a blackbody radiator than infrared light. Measurements showed the opposite, with maximal energy released at intermediate wavelengths, suggesting a failure of classical mechanics. This problem eventually led to the development of quantum mechanics. The successful resolution of the
Ultraviolet–visible spectroscopy non-bonding electrons (n-electrons) can absorb energy in the form of ultraviolet or visible light to excite these electrons to higher anti-bonding molecular orbitals. The more easily excited the electrons (i.e. lower energy gap between the HOMO and the LUMO), the longer the wavelength of light it can absorb. There are four possible types of transitions (π–π*, n–π*, σ–σ*, and n–σ*), and they can be ordered as follows: σ–σ* > n–σ* > π–π* > n–π*. UV/Vis spectroscopy is routinely used in analytical chemistry for the quantitative determination of different analytes, such as transition metal ions, highly conjugated organic compounds, and biological