S-type star are two distinct classes of S-type stars: intrinsic S stars; and extrinsic S stars. The presence of Technetium is used to distinguish the two classes, only being found in the intrinsic S-type stars. Intrinsic S-type stars are thermal pulsing asymptotic giant branch (TP-AGB) stars. AGB stars have inert carbon-oxygen cores and undergo fusion both in an inner helium shell and an outer hydrogen shell. They are large cool M class giants. The thermal pulses, created by flashes from the helium shell, cause strong convection within the upper layers of the star. These pulses become stronger as the star evolves and
Blue giant both cooler and more luminous. Intermediate-mass stars will continue to expand and cool until they become red giants. Massive stars also continue to expand as hydrogen shell burning progresses, but they do so at approximately constant luminosity and move horizontally across the HR diagram. In this way they can quickly pass through blue giant, bright blue giant, blue supergiant, and yellow supergiant classes, until they become red supergiants. The luminosity class for such stars is determined from spectral lines that are sensitive to the surface gravity of the star, with more expanded and luminous stars being given I (supergiant) classifications