Auxiliary electrode Auxiliary electrode The auxiliary electrode, often also called the counter electrode, is an electrode used in a three electrode electrochemical cell for voltammetric analysis or other reactions in which an electric current is expected to flow. The auxiliary electrode is distinct from the reference electrode, which establishes the electrical potential against which other potentials may be measured, and the working electrode, at which the cell reaction takes place. In a two-electrode system, either a known current or potential is applied between the working and auxiliary electrodes and the other variable may be measured. The auxiliary electrode functions as a cathode
Silver chloride electrode bond with silver of the electrode resulting in silver chloride and free electrons to deliver to the lead wire. The reaction allows current to pass from electrolyte to electrode and the electron current passes through the lead wire for the instrument to read. When there is an uneven distribution of cations and anions, there will be a small voltage called "half-cell potential" associated with the current. In the DC system that is used by the ECG and EEG instruments, the difference between the half-cell potential and the zero potential is shown as DC offset which is an undesirable characteristic. Silver/silver