Standard electrode potential to produce an electric potential, Gibbs free energy Δ"G"° must be negative, in accordance with the following equation: where "n" is number of moles of electrons per mole of products and "F" is the Faraday constant, ~96485 C/mol. As such, the following rules apply: Thus in order to have a spontaneous reaction (ΔG° < 0), "E"° must be positive, where: where "E"° is the standard potential at the anode and "E"° is the standard potential at the cathode as given in the table of standard electrode potential. Standard electrode potential In electrochemistry, it is defined as the measure of the
Standard electrode potential two metal electrodes with respect to the electrolyte. (Reversible electrode is an electrode that owes its potential to changes of a reversible nature, in contrast to electrodes used in electroplating which are destroyed during their use.) It is the measure of reducing power of any element or compound Although the overall potential of a cell can be measured, there is no simple way to accurately measure the electrode/electrolyte potentials in isolation. The electric potential also varies with temperature, concentration and pressure. Since the oxidation potential of a half-reaction is the negative of the reduction potential in a redox reaction, it