Infrared a wave and like its quantum particle, the photon. Infrared radiation was discovered in 1800 by astronomer Sir William Herschel, who discovered a type of invisible radiation in the spectrum lower in energy than red light, by means of its effect on a thermometer. Slightly more than half of the total energy from the Sun was eventually found to arrive on Earth in the form of infrared. The balance between absorbed and emitted infrared radiation has a critical effect on Earth's climate. Infrared radiation is emitted or absorbed by molecules when they change their rotational-vibrational movements. It excites vibrational modes
Ultraviolet photoelectron spectroscopy Ultraviolet photoelectron spectroscopy Ultraviolet photoelectron spectroscopy (UPS) refers to the measurement of kinetic energy spectra of photoelectrons emitted by molecules which have absorbed ultraviolet photons, in order to determine molecular orbital energies in the valence region. If Einstein's photoelectric law is applied to a free molecule, the kinetic energy (formula_1) of an emitted photoelectron is given by where "h" is Planck's constant, ν is the frequency of the ionizing light, and I is an ionization energy for the formation of a singly charged ion in either the ground state or an excited state. According to Koopmans' theorem, each such ionization