Anode to what occurs in an electrolytic cell, no anions flow to the anode, the internal current being entirely accounted for by the cations flowing away from it (cf drawing). In the United States, many battery manufacturers regard the positive electrode as the anode, particularly in their technical literature. Though technically incorrect, it does resolve the problem of which electrode is the anode in a secondary (or rechargeable) cell. Using the traditional definition, the anode switches ends between charge and discharge cycles. In electronic vacuum devices such as a cathode ray tube, the anode is the positively charged electron collector. In
Standard electrode potential is sufficient to calculate either one of the potentials. Therefore, standard electrode potential is commonly written as standard reduction potential. The electrode potential cannot be obtained empirically. The galvanic cell potential results from a "pair" of electrodes. Thus, only one empirical value is available in a pair of electrodes and it is not possible to determine the value for each electrode in the pair using the empirically obtained galvanic cell potential. A reference electrode, standard hydrogen electrode (SHE), for which the potential is "defined" or agreed upon by convention, needed to be established. In this case SHE is set to