Infrared a wave and like its quantum particle, the photon. Infrared radiation was discovered in 1800 by astronomer Sir William Herschel, who discovered a type of invisible radiation in the spectrum lower in energy than red light, by means of its effect on a thermometer. Slightly more than half of the total energy from the Sun was eventually found to arrive on Earth in the form of infrared. The balance between absorbed and emitted infrared radiation has a critical effect on Earth's climate. Infrared radiation is emitted or absorbed by molecules when they change their rotational-vibrational movements. It excites vibrational modes
Photovoltaic effect electric energy. The photovoltaic effect can also occur when two photons are absorbed simultaneously in a process called two-photon photovoltaic effect... The photovoltaic effect was first observed by French physicist A. E. Becquerel in 1839. He explained his discovery in "Comptes rendus de l'Académie des sciences", "the production of an electric current when two plates of platinum or gold immersed in an acid, neutral, or alkaline solution are exposed in an uneven way to solar radiation." Besides the direct excitation of free electrons, a photovoltaic effect can also arise simply due to the heating caused by absorption of the light.