Auxiliary electrode Auxiliary electrode The auxiliary electrode, often also called the counter electrode, is an electrode used in a three electrode electrochemical cell for voltammetric analysis or other reactions in which an electric current is expected to flow. The auxiliary electrode is distinct from the reference electrode, which establishes the electrical potential against which other potentials may be measured, and the working electrode, at which the cell reaction takes place. In a two-electrode system, either a known current or potential is applied between the working and auxiliary electrodes and the other variable may be measured. The auxiliary electrode functions as a cathode
Standard hydrogen electrode from the previous one it was given the name 'Standard Hydrogen Electrode'. In summary, The choice of platinum for the hydrogen electrode is due to several factors: The surface of platinum is platinized (i.e., covered with platinum black) to: Other metals can be used for building electrodes with a similar function such as the palladium-hydrogen electrode. Because of the high adsorption activity of the platinized platinum electrode, it's very important to protect electrode surface and solution from the presence of organic substances as well as from atmospheric oxygen. Inorganic ions that can reduce to a lower valency state at the