Cathode is positive and therefore would be expected to repel the positively charged cations; this is due to electrode potential relative to the electrolyte solution being different for the anode and cathode metal/electrolyte systems in a galvanic cell). The cathodic current, in electrochemistry, is the flow of electrons from the cathode interface to a species in solution. The anodic current is the flow of electrons into the anode from a species in solution. In an electrolytic cell, the cathode is where the negative polarity is applied to drive the cell. Common results of reduction at the cathode are hydrogen gas or
Auxiliary electrode whenever the working electrode is operating as an anode and vice versa. The auxiliary electrode often has a surface area much larger than that of the working electrode to ensure that the half-reaction occurring at the auxiliary electrode can occur fast enough so as not to limit the process at the working electrode. When a three electrode cell is used to perform electroanalytical chemistry, the auxiliary electrode, along with the working electrode, provides circuit over which current is either applied or measured. Here, the potential of the auxiliary electrode is usually not measured and is adjusted so as to balance