Primary cell dioxide is used in the Leclanché cell and zinc–carbon cell, and nitric acid is used in the Bunsen cell and Grove cell. Attempts have been made to make simple cells self-depolarizing by roughening the surface of the copper plate to facilitate the detachment of hydrogen bubbles with little success. Electrochemical depolarization exchanges the hydrogen for a metal, such as copper (e.g., Daniell cell), or silver (e.g., Silver-oxide cell).so called The battery terminal (electrode) that develops a positive voltage polarity (the carbon electrode in a dry cell) is called the cathode and the electrode with a negative polarity (zinc in a
Concentration polarization Concentration polarization Concentration polarization is a term used in the scientific fields of electrochemistry and membrane science. In electrochemistry, concentration polarization denotes the part of the polarization of an electrolytic cell resulting from changes in the electrolyte concentration due to the passage of current through the electrode/solution interface. Here "polarization" is understood as the shift of the Electrochemical potential difference across the cell from its equilibrium value. When the term is used in this sense, it is equivalent to “concentration overpotential”. the changes in concentration (emergence of concentration gradients in the solution adjacent to the electrode surface) is the difference