S-type star are two distinct classes of S-type stars: intrinsic S stars; and extrinsic S stars. The presence of Technetium is used to distinguish the two classes, only being found in the intrinsic S-type stars. Intrinsic S-type stars are thermal pulsing asymptotic giant branch (TP-AGB) stars. AGB stars have inert carbon-oxygen cores and undergo fusion both in an inner helium shell and an outer hydrogen shell. They are large cool M class giants. The thermal pulses, created by flashes from the helium shell, cause strong convection within the upper layers of the star. These pulses become stronger as the star evolves and
Giant star convection in the outer layers, triggers a second dredge-up, and causes a dramatic increase in size and luminosity. This is the asymptotic giant branch (AGB) analogous to the red-giant branch but more luminous, with a hydrogen-burning shell contributing most of the energy. Stars only remain on the AGB for around a million years, becoming increasingly unstable until they exhaust their fuel, go through a planetary nebula phase, and then become a carbon–oxygen white dwarf. Main-sequence stars with masses above about are already very luminous and they move horizontally across the HR diagram when they leave the main sequence, briefly becoming