Standard electrode potential Standard electrode potential In electrochemistry, it is defined as the measure of the individual potential of reversible electrode at standard state with ions at an effective concentration of 1mol dm-3 at the pressure of 1 atm The basis for an electrochemical cell, such as the galvanic cell, is always a redox reaction which can be broken down into two half-reactions: oxidation at anode (loss of electron) and reduction at cathode (gain of electron). Electricity is generated due to electric potential difference between two electrodes. This potential difference is created as a result of the difference between individual potentials of the
Polarograph Polarograph A Polarograph is a chemical analysis instrument used to record automatic voltage-intensity curves. The Polarograph uses an electrolytic cell consisting of an electrode or microelectrode small area, generally of mercury drop type , which is a very fine capillary tube through which mercury flows slowly , which comes in the form of small droplets, which fall on the same surface of a much broader element, which is the other electrode . When one applies a variable voltage in this cell, the electrode large area remains unchanged, while the microelectrode undergoes a change of potential ,( i.e. is polarized). It