Electrolytic cell electrons from the cathode and deposits on the cathode as sodium metal. NaCl dissolved in water can also be electrolyzed. The anode oxidizes chloride ions (Cl), and Cl gas is produced. However, at the cathode, instead of sodium ions being reduced to sodium metal, water molecules are reduced to hydroxide ions (OH) and hydrogen gas (H). The overall result of the electrolysis is the production of chlorine gas and aqueous sodium hydroxide (NaOH) solution. Commercially, electrolytic cells are used in electrorefining and electrowinning of several non-ferrous metals. Almost all high-purity aluminium, copper, zinc and lead is produced industrially in electrolytic
Auxiliary electrode whenever the working electrode is operating as an anode and vice versa. The auxiliary electrode often has a surface area much larger than that of the working electrode to ensure that the half-reaction occurring at the auxiliary electrode can occur fast enough so as not to limit the process at the working electrode. When a three electrode cell is used to perform electroanalytical chemistry, the auxiliary electrode, along with the working electrode, provides circuit over which current is either applied or measured. Here, the potential of the auxiliary electrode is usually not measured and is adjusted so as to balance