Standard electrode potential Standard electrode potential In electrochemistry, it is defined as the measure of the individual potential of reversible electrode at standard state with ions at an effective concentration of 1mol dm-3 at the pressure of 1 atm The basis for an electrochemical cell, such as the galvanic cell, is always a redox reaction which can be broken down into two half-reactions: oxidation at anode (loss of electron) and reduction at cathode (gain of electron). Electricity is generated due to electric potential difference between two electrodes. This potential difference is created as a result of the difference between individual potentials of the
Absolute electrode potential defined analogously. In this approach, all three species taking part in the reaction, including the electron, must be placed in thermodynamically well-defined states. All species, including the electron, are at the same temperature, and appropriate standard states for all species, including the electron, must be fully defined. The absolute electrode potential is then defined as the Gibbs free energy for the absolute electrode process. To express this in volts one divides the Gibb’s free energy by the negative of Faraday’s constant. Rockwood's approach to absolute-electrode thermodynamics is easily expendable to other thermodynamic functions. For example, the absolute half-cell entropy has