Auxiliary electrode Auxiliary electrode The auxiliary electrode, often also called the counter electrode, is an electrode used in a three electrode electrochemical cell for voltammetric analysis or other reactions in which an electric current is expected to flow. The auxiliary electrode is distinct from the reference electrode, which establishes the electrical potential against which other potentials may be measured, and the working electrode, at which the cell reaction takes place. In a two-electrode system, either a known current or potential is applied between the working and auxiliary electrodes and the other variable may be measured. The auxiliary electrode functions as a cathode
Organic solar cell holes to the negative electrode. In 1958 the photovoltaic effect or the creation of voltage of a cell based on magnesium phthalocyanine (MgPc)—a macrocyclic compound having an alternating nitrogen atom-carbon atom ring structure—was discovered to have a photovoltage of 200 mV. An Al/MgPc/Ag cell obtained photovoltaic efficiency of 0.01% under illumination at 690 nm. Conjugated polymers were also used in this type of photovoltaic cell. One device used polyacetylene (Fig 1) as the organic layer, with Al and graphite, producing an open circuit voltage of 0.3 V and a charge collection efficiency of 0.3%. An Al/poly(3-nethyl-thiophene)/Pt cell had an external