Infrared a wave and like its quantum particle, the photon. Infrared radiation was discovered in 1800 by astronomer Sir William Herschel, who discovered a type of invisible radiation in the spectrum lower in energy than red light, by means of its effect on a thermometer. Slightly more than half of the total energy from the Sun was eventually found to arrive on Earth in the form of infrared. The balance between absorbed and emitted infrared radiation has a critical effect on Earth's climate. Infrared radiation is emitted or absorbed by molecules when they change their rotational-vibrational movements. It excites vibrational modes
Photoacoustic effect added steady light does not produce any photoacoustic effect by itself, but changes the photoacoustic response due to the modulated/pulsed probing light. The resulting signal serves as a reference to all other measurements in absence of the background light. The photothermal part of the reference signal is maximal, since at photosynthetic saturation no energy is stored. At the same time the contribution of the other mechanisms tends to zero at saturation. Thus the reference signal is proportional to the total absorbed light energy. In order to separate and define the photobaric and photothermal contributions in spongy samples (leaves, lichens) one