Aluminum electrolytic capacitor or peak voltages is not possible. In every case transients arise, the application has to be carefully approved. Electrolytic capacitors with solid electrolyte cannot withstand transients or peak voltages higher than the surge voltage. Transients for this type of electrolytic capacitor may destroy the component. Electrolytic capacitors are polarized capacitors and generally require an anode electrode voltage to be positive relative to the cathode voltage. However, the cathode foil of aluminum electrolytic capacitors is provided with a very thin, natural air-originated oxide layer. This oxide layer has a voltage proof of approximately 1 to 1.5 V. Therefore, aluminum electrolytic capacitors
Electrode potential drawing): In case of non-zero net current on the electrode, it is essential to minimize the ohmic IR-drop in the electrolyte, e.g., by positioning the reference electrode near the surface of the working electrode (e.g., see Luggin capillary), or by using a supporting electrolyte of sufficiently high conductivity. The potential measurements are performed with the positive terminal of the electrometer connected to working electrode and the negative terminal to the reference electrode. Historically, two conventions for sign for the electrode potential have formed: In 1953 in Stockholm IUPAC recognized that either of the conventions is permissible; however, it unanimously recommended