Electrolytic capacitor Electrolytic capacitor An electrolytic capacitor (abbreviated e-cap) is a polarized capacitor whose anode or positive plate is made of a metal that forms an insulating oxide layer through anodization. This oxide layer acts as the dielectric of the capacitor. A solid, liquid, or gel electrolyte covers the surface of this oxide layer, serving as the (cathode) or negative plate of the capacitor. Due to their very thin dielectric oxide layer and enlarged anode surface, electrolytic capacitors have a much higher capacitance-voltage (CV) product per unit volume compared to ceramic capacitors or film capacitors, and so can have large capacitance values.
Electrode potential drawing): In case of non-zero net current on the electrode, it is essential to minimize the ohmic IR-drop in the electrolyte, e.g., by positioning the reference electrode near the surface of the working electrode (e.g., see Luggin capillary), or by using a supporting electrolyte of sufficiently high conductivity. The potential measurements are performed with the positive terminal of the electrometer connected to working electrode and the negative terminal to the reference electrode. Historically, two conventions for sign for the electrode potential have formed: In 1953 in Stockholm IUPAC recognized that either of the conventions is permissible; however, it unanimously recommended