Electrode reaction cannot be reversed, and the identities of the anode and cathode are therefore fixed. The anode is always the negative electrode. The cell can be discharged but not recharged. A secondary cell, for example a rechargeable battery, is a cell in which the chemical reactions are reversible. When the cell is being charged, the anode becomes the positive (+) and the cathode the negative (−) electrode. This is also the case in an electrolytic cell. When the cell is being discharged, it behaves like a primary cell, with the anode as the negative and the cathode as the positive
Aluminum electrolytic capacitor sensitive to voltages spikes or current surges. The anodic generated insulating oxide layer is destroyed if the polarity of the applied voltage changes. Every electrolytic capacitor in principle forms a "plate capacitor" whose capacitance is greater the larger the electrode area A and the permittivity ε, and the thinner the thickness (d) of the dielectric. The capacitance is proportional to the product of the area of one plate multiplied with the permittivity, divided by the thickness of the dielectric. Electrolytic capacitors obtain their large capacitance values by a large area and small dielectric thickness. The dielectric thickness of electrolytic capacitors