Electrolytic cell Electrolytic cell An electrolytic cell is an electrochemical cell that drives a non-spontaneous redox reaction through the application of electrical energy. They are often used to decompose chemical compounds, in a process called electrolysis—the Greek word lysis means "to break up". Important examples of electrolysis are the decomposition of water into hydrogen and oxygen, and bauxite into aluminium and other chemicals. Electroplating (e.g. of copper, silver, nickel or chromium) is done using an electrolytic cell. Electrolysis is a technique that uses a direct electric current (DC). An electrolytic cell has three component parts: an electrolyte and two electrodes (a cathode
Absolute electrode potential defined analogously. In this approach, all three species taking part in the reaction, including the electron, must be placed in thermodynamically well-defined states. All species, including the electron, are at the same temperature, and appropriate standard states for all species, including the electron, must be fully defined. The absolute electrode potential is then defined as the Gibbs free energy for the absolute electrode process. To express this in volts one divides the Gibb’s free energy by the negative of Faraday’s constant. Rockwood's approach to absolute-electrode thermodynamics is easily expendable to other thermodynamic functions. For example, the absolute half-cell entropy has