Isotopes of helium a thousand times lower than helium-4 (2.17 K). This difference is explained by quantum statistics, since helium-3 atoms are fermions, while helium-4 atoms are bosons, which condense to a superfluid more easily. The most common isotope, , is produced on Earth by alpha decay of heavier radioactive elements; the alpha particles that emerge are fully ionized nuclei. is an unusually stable nucleus because its nucleons are arranged into complete shells. It was also formed in enormous quantities during Big Bang nucleosynthesis. Terrestrial helium consists almost exclusively (99.99986%) of this isotope. Its boiling point of 4.2 K is the lowest of
Boiling point otherwise very large, the compound often decomposes at high temperature before the boiling point is reached. Another factor that affects the normal boiling point of a compound is the polarity of its molecules. As the polarity of a compound's molecules increases, its normal boiling point increases, other factors being equal. Closely related is the ability of a molecule to form hydrogen bonds (in the liquid state), which makes it harder for molecules to leave the liquid state and thus increases the normal boiling point of the compound. Simple carboxylic acids dimerize by forming hydrogen bonds between molecules. A minor factor