Boiling point liquid is the highest temperature (and pressure) it will actually boil at. See also Vapour pressure of water. The element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure; because it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point. As can be seen from the above plot of the logarithm of the vapor pressure vs. the temperature for any given pure chemical compound, its normal boiling point can serve as an indication of that
Boiling point increases with increased pressure up to the critical point, where the gas and liquid properties become identical. The boiling point cannot be increased beyond the critical point. Likewise, the boiling point decreases with decreasing pressure until the triple point is reached. The boiling point cannot be reduced below the triple point. If the heat of vaporization and the vapor pressure of a liquid at a certain temperature are known, the boiling point can be calculated by using the Clausius–Clapeyron equation, thus: where: Saturation pressure is the pressure for a corresponding saturation temperature at which a liquid boils into its vapor