Paul Methuen (diplomat) gained valuable diplomatic experience and the esteem of King Pedro. During two absences of his father he became chargé d'affaires, rising to Minister on his father's appointment as Lord Chancellor of Ireland in 1697. He was unable to prevent a Portuguese-French alliance in 1701. When his father returned to Portugal a special envoy in 1702, they were successful in breaking the alliance in 1703. The led to the Methuen commercial treaty between England and Portugal, the basis of Britain's monopoly of Portuguese trade for much of the 18th century. His father remained in Portugal as ambassador. In 1705, Methuen served
Boundary Treaty of 1874 between Chile and Bolivia Plenipotentiary in Bolivia) as follows: In 1874, Peruvian Navy officer Miguel Grau (Commander of the Navy during the war) advised to the diplomacy of his country the internationalization of the Bolivian province of Antofagasta In August 1874, Bolivia and Chile substituted the Treaty of 1866 with a new Treaty that kept the 24th degree parallel as the boundary between both countries but ended the Mutual Benefits Zone defined in 1866 between the 23°S and 25°S. Further, Chile relinquished its share of export taxes on minerals shipped from Bolivia, and Bolivia agreed not to raise taxes on Chilean enterprises in Bolivia