Greater scaup been described by Serebrovskij in 1941 from fossils recovered at Binagady, Azerbaijan. The greater scaup's name may come from "scalp", a Scottish and Northern English word for a shellfish bed, or from the duck's mating call: "scaup scaup". A phylogenetic analysis of the diving ducks, examining the skeletal anatomy and skin, found that the greater and lesser scaups are each other's closest relatives, with the tufted duck as the next closest relative of the pair. The adult greater scaup is long with a wingspan and a body mass of . It has a blue bill and yellow eyes and is
Greater scaup 100% of female greater scaup, and 77% of female lesser scaup, had escalated levels of selenium in their bodies. Selenium is an occurring semimetallic trace element that occurs naturally in some soils and minute amounts are necessary for animal life. However excessive selenium can cause reproductive harm and is highly toxic. On their migration across the Great Lakes, greater scaups are at risk of ingesting selenium by eating the invasive zebra mussels, which can render a hen infertile. This sterilization of hens is causing the population to decrease. In a study of 107 scaup, they all had traces of iron,