Greater scaup been described by Serebrovskij in 1941 from fossils recovered at Binagady, Azerbaijan. The greater scaup's name may come from "scalp", a Scottish and Northern English word for a shellfish bed, or from the duck's mating call: "scaup scaup". A phylogenetic analysis of the diving ducks, examining the skeletal anatomy and skin, found that the greater and lesser scaups are each other's closest relatives, with the tufted duck as the next closest relative of the pair. The adult greater scaup is long with a wingspan and a body mass of . It has a blue bill and yellow eyes and is
Greater scaup wing shows a white stripe. The females are mostly brown, again with white on the wing. They have dull blue bills and white on the face. Greater scaup nest near water, typically on islands in northern lakes or on floating mats of vegetation. They begin breeding at age two, but start building nests in the first year. The drakes have a complex courtship, which takes place on the return migration to the summer breeding grounds and concludes with the formation of monogamous pairs. Females lay a clutch of six to nine olive-buff-colored eggs. The eggs hatch in 24 to 28