Cave rainwater and groundwater charged with HCO (carbonic acid) and naturally occurring organic acids. The dissolution process produces a distinctive landform known as "karst", characterized by sinkholes and underground drainage. Limestone caves are often adorned with calcium carbonate formations produced through slow precipitation. These include flowstones, stalactites, stalagmites, helictites, soda straws and columns. These secondary mineral deposits in caves are called "speleothems". The portions of a solutional cave that are below the water table or the local level of the groundwater will be flooded. Lechuguilla Cave in New Mexico and nearby Carlsbad Cavern are now believed to be examples of another
Calcium bicarbonate matter, in the formation of the caves themselves. As water containing carbon dioxide (including extra CO acquired from soil organisms) passes through limestone or other calcium carbonate-containing minerals, it dissolves part of the calcium carbonate, hence becomes richer in bicarbonate. As the groundwater enters the cave, the excess carbon dioxide is released from the solution of the bicarbonate, causing the much less soluble calcium carbonate to be deposited. In the reverse process, dissolved carbon dioxide (CO) in rainwater (HO) reacts with limestone calcium carbonate (CaCO) to form soluble calcium bicarbonate (Ca(HCO)). This soluble compound is then washed away with the