Cave rainwater and groundwater charged with HCO (carbonic acid) and naturally occurring organic acids. The dissolution process produces a distinctive landform known as "karst", characterized by sinkholes and underground drainage. Limestone caves are often adorned with calcium carbonate formations produced through slow precipitation. These include flowstones, stalactites, stalagmites, helictites, soda straws and columns. These secondary mineral deposits in caves are called "speleothems". The portions of a solutional cave that are below the water table or the local level of the groundwater will be flooded. Lechuguilla Cave in New Mexico and nearby Carlsbad Cavern are now believed to be examples of another
Sodium carbonate sodium sulfate was blended with crushed limestone (calcium carbonate) and coal, and the mixture was burnt, producing calcium sulfide. The sodium carbonate was extracted from the ashes with water, and then collected by allowing the water to evaporate. The hydrochloric acid produced by the Leblanc process was a major source of air pollution, and the calcium sulfide byproduct also presented waste disposal issues. However, it remained the major production method for sodium carbonate until the late 1880s. In 1861, the Belgian industrial chemist Ernest Solvay developed a method to convert sodium chloride to sodium carbonate using ammonia. The Solvay process