Calcium carbonate latter is especially evident in day-to-day life of people who have hard water. Water in aquifers underground can be exposed to levels of CO much higher than atmospheric. As such water percolates through calcium carbonate rock, the CaCO dissolves according to the second trend. When that same water then emerges from the tap, in time it comes into equilibrium with CO levels in the air by outgassing its excess CO. The calcium carbonate becomes less soluble as a result and the excess precipitates as lime scale. This same process is responsible for the formation of stalactites and stalagmites in limestone
Calcium carbonate with the molar concentration of dissolved CO cannot exceed the value of "K". This seemingly simple solubility equation, however, must be taken along with the more complicated equilibrium of carbon dioxide with water (see carbonic acid). Some of the CO combines with H in the solution according to: HCO is known as the bicarbonate ion. Calcium bicarbonate is many times more soluble in water than calcium carbonate—indeed it exists "only" in solution. Some of the HCO combines with H in solution according to: Some of the HCO breaks up into water and dissolved carbon dioxide according to: And dissolved carbon