Indiana Caverns the calcium carbonate precipitates out of the water. The calcium carbonate, in the form of the mineral calcite, a solid, crystallizes onto the bottoms and sides of existing stalactites, stalagmites, helictites, and sheets of flowstone to grow the formations over time. Other minerals are brought into the cave by flowing of water to create white, red, tan, and gray colors on the formations and walls. St. Louis Limestone is primarily made of calcite, but is also known to contain magnesium sulfate, manganese dioxide, ferric oxide, gypsum, dolomite, and aragonite. On the show tour, deposits of calcite, manganese dioxide, and ferric
Amorphous calcium carbonate following Ostwald's step rule, which states that the least stable polymorph will precipitate first. But while ACC is the first product to precipitate, it rapidly transforms into one of the more stable polymorphs within seconds. When in pure CaCO, ACC transforms within seconds into one of the crystalline calcium carbonate polymorphs. This transformation from amorphous to crystalline is proposed to be a dissolution-reprecipitation mechanism. Despite ACC’s highly unstable nature, some organisms are able to produce stable ACC. For example, the American Lobster "Homarus americanus", maintains stable ACC throughout its yearly molt cycle. Studies of biogenic ACC have also shown that