Solutional cave and most abundant solutional caves are located in limestone. Limestone caves are often adorned with calcium carbonate formations produced through slow precipitation. These include flowstones, stalactites, stalagmites, helictites, soda straws, calcite rafts and columns. These secondary mineral deposits in caves are called "speleothems". Limestone dissolves under the action of rainwater and groundwater charged with HCO (carbonic acid) and naturally occurring organic acids. The dissolution process produces a distinctive landform known as "karst", characterized by sinkholes, and underground drainage. Solutional caves in this landform—topography are often called karst caves. Lechuguilla Cave in New Mexico and nearby Carlsbad Cavern are now believed
Calcium carbonate Calcium carbonate shares the typical properties of other carbonates. Notably, Calcium carbonate will react with water that is saturated with carbon dioxide to form the soluble calcium bicarbonate. This reaction is important in the erosion of carbonate rock, forming caverns, and leads to hard water in many regions. An unusual form of calcium carbonate is the hexahydrate, ikaite, CaCO·6HO. Ikaite is stable only below 8 °C. The vast majority of calcium carbonate used in industry is extracted by mining or quarrying. Pure calcium carbonate (e.g. for food or pharmaceutical use), can be produced from a pure quarried source (usually marble).