Calcium carbonate latter is especially evident in day-to-day life of people who have hard water. Water in aquifers underground can be exposed to levels of CO much higher than atmospheric. As such water percolates through calcium carbonate rock, the CaCO dissolves according to the second trend. When that same water then emerges from the tap, in time it comes into equilibrium with CO levels in the air by outgassing its excess CO. The calcium carbonate becomes less soluble as a result and the excess precipitates as lime scale. This same process is responsible for the formation of stalactites and stalagmites in limestone
Calcium carbonate Calcium carbonate shares the typical properties of other carbonates. Notably, Calcium carbonate will react with water that is saturated with carbon dioxide to form the soluble calcium bicarbonate. This reaction is important in the erosion of carbonate rock, forming caverns, and leads to hard water in many regions. An unusual form of calcium carbonate is the hexahydrate, ikaite, CaCO·6HO. Ikaite is stable only below 8 °C. The vast majority of calcium carbonate used in industry is extracted by mining or quarrying. Pure calcium carbonate (e.g. for food or pharmaceutical use), can be produced from a pure quarried source (usually marble).