Solutional cave and most abundant solutional caves are located in limestone. Limestone caves are often adorned with calcium carbonate formations produced through slow precipitation. These include flowstones, stalactites, stalagmites, helictites, soda straws, calcite rafts and columns. These secondary mineral deposits in caves are called "speleothems". Limestone dissolves under the action of rainwater and groundwater charged with HCO (carbonic acid) and naturally occurring organic acids. The dissolution process produces a distinctive landform known as "karst", characterized by sinkholes, and underground drainage. Solutional caves in this landform—topography are often called karst caves. Lechuguilla Cave in New Mexico and nearby Carlsbad Cavern are now believed
Calcium sulfate retrograde solubility for the same thermodynamic reason: because its dissolution reaction is also exothermic and releases heat. So, to dissolve higher amounts of calcium sulfate or calcium hydroxide in water, it is necessary to cool down the solution close to its freezing point instead of increasing its temperature. The retrograde solubility of calcium sulfate is also responsible for its precipitation in the hottest zone of heating systems and for its contribution to the formation of scale in boilers along with the precipitation of calcium carbonate whose solubility also decreases when CO degasses from hot water or can escape out of