Sugars in wine as chaptalization solely in order to boost the alcohol content – chaptalization does not increase the "sweetness" of a wine. Glucose, along with fructose, is one of the primary sugars found in wine grapes. In wine, glucose tastes less sweet than fructose. It is a six-carbon sugar molecule derived from the breakdown of sucrose. At the beginning of the ripening stage there is usually more glucose than fructose present in the grape (as much as five times more) but the rapid development of fructose shifts the ratio to where at harvest there are generally equal amounts. Grapes that are over
Phenolic content in wine into wine, most notably vanillin which adds vanilla aroma to wines. Most wine phenols are classified as secondary metabolites and were not thought to be active in the primary metabolism and function of the grapevine. However, there is evidence that in some plants flavonoids play a role as endogenous regulators of auxin transport. They are water-soluble and are usually secreted into the vacuole of the grapevine as glycosides. "Vitis vinifera" produces many phenolic compounds. There is a varietal effect on the relative composition. In red wine, up to 90% of the wine's phenolic content falls under the classification of flavonoids.