Rawhiti Cave become increasingly finer deeper down into the cave. A short walking track leads halfway down into the cavernous opening to a viewing platform. The diverse twilight-zone flora near the entrance of Rawhiti Cave makes this cave nationally significant. Over long periods of time, plant growth on the cave formations causes them to grow towards the sunlight as more calcium carbonate is deposited regularly on top of the plant growth. This phenomenon, called phytokarst, is most evident on the larger stalactites near the cave entrance, which are strongly curved outwards due to the heavy moss and fern growth on their sunlit
Calcium carbonate contains calcium atoms coordinated by 6 oxygen atoms, in aragonite they are coordinated by 9 oxygen atoms. The vaterite structure is not fully understood. Magnesium carbonate MgCO has the calcite structure, whereas strontium and barium carbonate (SrCO and BaCO) adopt the aragonite structure, reflecting their larger ionic radii. Calcite, aragonite and vaterite are pure calcium carbonate minerals. Industrially important source rocks which are predominantly calcium carbonate include limestone, chalk, marble and travertine. Eggshells, snail shells and most seashells are predominantly calcium carbonate and can be used as industrial sources of that chemical. Oyster shells have enjoyed recent recognition as a