Indiana Caverns the calcium carbonate precipitates out of the water. The calcium carbonate, in the form of the mineral calcite, a solid, crystallizes onto the bottoms and sides of existing stalactites, stalagmites, helictites, and sheets of flowstone to grow the formations over time. Other minerals are brought into the cave by flowing of water to create white, red, tan, and gray colors on the formations and walls. St. Louis Limestone is primarily made of calcite, but is also known to contain magnesium sulfate, manganese dioxide, ferric oxide, gypsum, dolomite, and aragonite. On the show tour, deposits of calcite, manganese dioxide, and ferric
Sodium carbonate sodium sulfate was blended with crushed limestone (calcium carbonate) and coal, and the mixture was burnt, producing calcium sulfide. The sodium carbonate was extracted from the ashes with water, and then collected by allowing the water to evaporate. The hydrochloric acid produced by the Leblanc process was a major source of air pollution, and the calcium sulfide byproduct also presented waste disposal issues. However, it remained the major production method for sodium carbonate until the late 1880s. In 1861, the Belgian industrial chemist Ernest Solvay developed a method to convert sodium chloride to sodium carbonate using ammonia. The Solvay process