Solutional cave and most abundant solutional caves are located in limestone. Limestone caves are often adorned with calcium carbonate formations produced through slow precipitation. These include flowstones, stalactites, stalagmites, helictites, soda straws, calcite rafts and columns. These secondary mineral deposits in caves are called "speleothems". Limestone dissolves under the action of rainwater and groundwater charged with HCO (carbonic acid) and naturally occurring organic acids. The dissolution process produces a distinctive landform known as "karst", characterized by sinkholes, and underground drainage. Solutional caves in this landform—topography are often called karst caves. Lechuguilla Cave in New Mexico and nearby Carlsbad Cavern are now believed
Calcium carbonate contains calcium atoms coordinated by 6 oxygen atoms, in aragonite they are coordinated by 9 oxygen atoms. The vaterite structure is not fully understood. Magnesium carbonate MgCO has the calcite structure, whereas strontium and barium carbonate (SrCO and BaCO) adopt the aragonite structure, reflecting their larger ionic radii. Calcite, aragonite and vaterite are pure calcium carbonate minerals. Industrially important source rocks which are predominantly calcium carbonate include limestone, chalk, marble and travertine. Eggshells, snail shells and most seashells are predominantly calcium carbonate and can be used as industrial sources of that chemical. Oyster shells have enjoyed recent recognition as a