Indiana Caverns the calcium carbonate precipitates out of the water. The calcium carbonate, in the form of the mineral calcite, a solid, crystallizes onto the bottoms and sides of existing stalactites, stalagmites, helictites, and sheets of flowstone to grow the formations over time. Other minerals are brought into the cave by flowing of water to create white, red, tan, and gray colors on the formations and walls. St. Louis Limestone is primarily made of calcite, but is also known to contain magnesium sulfate, manganese dioxide, ferric oxide, gypsum, dolomite, and aragonite. On the show tour, deposits of calcite, manganese dioxide, and ferric
Calcium carbonate the solution must be electrically neutral, make it possible to solve simultaneously for the remaining five unknown concentrations (note that the above form of the neutrality equation is valid only if calcium carbonate has been put in contact with pure water or with a neutral pH solution; in the case where the initial water solvent pH is not neutral, the equation is modified). The adjacent table shows the result for [Ca] and [H] (in the form of pH) as a function of ambient partial pressure of CO ("K" = 4.47×10 has been taken for the calculation). The effect of the