Indiana Caverns the calcium carbonate precipitates out of the water. The calcium carbonate, in the form of the mineral calcite, a solid, crystallizes onto the bottoms and sides of existing stalactites, stalagmites, helictites, and sheets of flowstone to grow the formations over time. Other minerals are brought into the cave by flowing of water to create white, red, tan, and gray colors on the formations and walls. St. Louis Limestone is primarily made of calcite, but is also known to contain magnesium sulfate, manganese dioxide, ferric oxide, gypsum, dolomite, and aragonite. On the show tour, deposits of calcite, manganese dioxide, and ferric
Carbonate hardness given in ppm. The term "carbonate hardness" is also sometimes used as a synonym for temporary hardness, in which case it refers to that portion of hard water that can be removed by processes such as boiling or lime softening, and then separation of water from the resulting precipitate. Carbonate hardness Carbonate hardness, is a measure of the water hardness caused by the presence of carbonate () and bicarbonate () anions. Carbonate hardness is usually expressed either in degrees KH (dKH) (from the German ""Karbonathärte""), or in "parts per million calcium carbonate" ( ppm or grams per litre|mg/l). One dKH