Stalactite of the abundance of limestone caves. The corresponding formation on the floor of the cave is known as a stalagmite. The most common stalactites are speleothems, which occur in limestone caves. They form through deposition of calcium carbonate and other minerals, which is precipitated from mineralized water solutions. Limestone is the chief form of calcium carbonate rock which is dissolved by water that contains carbon dioxide, forming a calcium bicarbonate solution in underground caverns. The chemical formula for this reaction is: This solution travels through the rock until it reaches an edge and if this is on the roof of
Calcium carbonate the solution must be electrically neutral, make it possible to solve simultaneously for the remaining five unknown concentrations (note that the above form of the neutrality equation is valid only if calcium carbonate has been put in contact with pure water or with a neutral pH solution; in the case where the initial water solvent pH is not neutral, the equation is modified). The adjacent table shows the result for [Ca] and [H] (in the form of pH) as a function of ambient partial pressure of CO ("K" = 4.47×10 has been taken for the calculation). The effect of the