Indiana Caverns the calcium carbonate precipitates out of the water. The calcium carbonate, in the form of the mineral calcite, a solid, crystallizes onto the bottoms and sides of existing stalactites, stalagmites, helictites, and sheets of flowstone to grow the formations over time. Other minerals are brought into the cave by flowing of water to create white, red, tan, and gray colors on the formations and walls. St. Louis Limestone is primarily made of calcite, but is also known to contain magnesium sulfate, manganese dioxide, ferric oxide, gypsum, dolomite, and aragonite. On the show tour, deposits of calcite, manganese dioxide, and ferric
Calcium carbonate with the molar concentration of dissolved CO cannot exceed the value of "K". This seemingly simple solubility equation, however, must be taken along with the more complicated equilibrium of carbon dioxide with water (see carbonic acid). Some of the CO combines with H in the solution according to: HCO is known as the bicarbonate ion. Calcium bicarbonate is many times more soluble in water than calcium carbonate—indeed it exists "only" in solution. Some of the HCO combines with H in solution according to: Some of the HCO breaks up into water and dissolved carbon dioxide according to: And dissolved carbon