Calcium carbonate latter is especially evident in day-to-day life of people who have hard water. Water in aquifers underground can be exposed to levels of CO much higher than atmospheric. As such water percolates through calcium carbonate rock, the CaCO dissolves according to the second trend. When that same water then emerges from the tap, in time it comes into equilibrium with CO levels in the air by outgassing its excess CO. The calcium carbonate becomes less soluble as a result and the excess precipitates as lime scale. This same process is responsible for the formation of stalactites and stalagmites in limestone
Cave of the Mounds National Park Service designated the cave as a National Natural Landmark. The limestone from which the cave was carved began forming approximately 488 million years ago, during the Ordovician Period. During this time, much of North America was covered with warm, shallow seas. Over millions of years, calcium carbonate shells from tiny marine organisms accumulated on the sea floor, forming enormous quantities of limestone. The type of limestone in which the cave was formed is called galena dolomite because of its high concentration of the lead ore galena. The cave began forming about a million to a million and a