Group 4 element doses and does not play any natural role inside the human body. Zirconium powder can cause irritation, but only contact with the eyes requires medical attention. OSHA recommendations for zirconium are 5 mg/m time weighted average limit and a 10 mg/m short-term exposure limit. Only limited data exists on the toxicology of hafnium. Group 4 element Group 4 is a group of elements in the periodic table. It contains the elements titanium (Ti), zirconium (Zr), hafnium (Hf) and rutherfordium (Rf). This group lies in the d-block of the periodic table. The group itself has not acquired a trivial name; it
History of the periodic table the Periodic Law for the chemical elements". He contributed the word 'periodic' in chemistry. The Russian chemist Dmitri Mendeleev was the first scientist to make a periodic table similar to the one used today. Mendeleev arranged the elements by atomic mass, corresponding to relative molar mass. It is sometimes said that he played 'chemical solitaire' on long train journeys, using cards with various facts about the known elements. On March 6, 1869, Mendeleev gave a formal presentation, "The Dependence Between the Properties of the Atomic Weights of the Elements", to the Russian Chemical Society. In 1869, the table was published