Group 4 element Group 4 element Group 4 is a group of elements in the periodic table. It contains the elements titanium (Ti), zirconium (Zr), hafnium (Hf) and rutherfordium (Rf). This group lies in the d-block of the periodic table. The group itself has not acquired a trivial name; it belongs to the broader grouping of the transition metals. The three Group 4 elements that occur naturally are titanium, zirconium and hafnium. The first three members of the group share similar properties; all three are hard refractory metals under standard conditions. However, the fourth element rutherfordium (Rf), has been synthesized in the laboratory;
Block (periodic table) the s-block, with its outer (and only) electrons in the 1s atomic orbital, although its chemical properties are more similar to the p-block noble gases due to its full shell. In addition to the blocks listed in this table, there is a hypothetical g-block which is not pictured here. The g-block elements can be seen in the expanded extended periodic table. Lanthanum and actinium are placed under scandium and yttrium to reflect their status as d-block elements, as they have no electrons in the 4f and 5f orbitals, respectively, while lutetium and lawrencium do. The s-block is on the left