Group 4 element Group 4 element Group 4 is a group of elements in the periodic table. It contains the elements titanium (Ti), zirconium (Zr), hafnium (Hf) and rutherfordium (Rf). This group lies in the d-block of the periodic table. The group itself has not acquired a trivial name; it belongs to the broader grouping of the transition metals. The three Group 4 elements that occur naturally are titanium, zirconium and hafnium. The first three members of the group share similar properties; all three are hard refractory metals under standard conditions. However, the fourth element rutherfordium (Rf), has been synthesized in the laboratory;
History of the periodic table were "earth", "water", "air" and "fire". Similar ideas about these four elements also existed in other ancient traditions, such as Indian philosophy. The history of the periodic table is also a history of the discovery of the chemical elements. The first person in history to discover a new element was Hennig Brand, a bankrupt German merchant. Brand tried to discover the Philosopher's Stone — a mythical object that was supposed to turn inexpensive base metals into gold. In 1669 (or later), his experiments with distilled human urine resulted in the production of a glowing white substance, which he called "cold