Group 4 element doses and does not play any natural role inside the human body. Zirconium powder can cause irritation, but only contact with the eyes requires medical attention. OSHA recommendations for zirconium are 5 mg/m time weighted average limit and a 10 mg/m short-term exposure limit. Only limited data exists on the toxicology of hafnium. Group 4 element Group 4 is a group of elements in the periodic table. It contains the elements titanium (Ti), zirconium (Zr), hafnium (Hf) and rutherfordium (Rf). This group lies in the d-block of the periodic table. The group itself has not acquired a trivial name; it
Periodic table include a two-element s-block for elements 119 and 120, a new g-block for the next 18 elements, and 30 additional elements continuing the current f-, d-, and p-blocks, culminating in element 168, the next noble gas. More recently, physicists such as Pekka Pyykkö have theorized that these additional elements do not follow the Madelung rule, which predicts how electron shells are filled and thus affects the appearance of the present periodic table. There are currently several competing theoretical models for the placement of the elements of atomic number less than or equal to 172. In all of these it is