Group 4 element Group 4 element Group 4 is a group of elements in the periodic table. It contains the elements titanium (Ti), zirconium (Zr), hafnium (Hf) and rutherfordium (Rf). This group lies in the d-block of the periodic table. The group itself has not acquired a trivial name; it belongs to the broader grouping of the transition metals. The three Group 4 elements that occur naturally are titanium, zirconium and hafnium. The first three members of the group share similar properties; all three are hard refractory metals under standard conditions. However, the fourth element rutherfordium (Rf), has been synthesized in the laboratory;
Chemical element of the four elements nor Paracelsus' view of three fundamental elements, left open the question of the number of elements. The first modern list of chemical elements was given in Antoine Lavoisier's 1789 "Elements of Chemistry", which contained thirty-three elements, including light and caloric. By 1818, Jöns Jakob Berzelius had determined atomic weights for forty-five of the forty-nine then-accepted elements. Dmitri Mendeleev had sixty-six elements in his periodic table of 1869. From Boyle until the early 20th century, an element was defined as a pure substance that could not be decomposed into any simpler substance. Put another way, a chemical