Group 4 element doses and does not play any natural role inside the human body. Zirconium powder can cause irritation, but only contact with the eyes requires medical attention. OSHA recommendations for zirconium are 5 mg/m time weighted average limit and a 10 mg/m short-term exposure limit. Only limited data exists on the toxicology of hafnium. Group 4 element Group 4 is a group of elements in the periodic table. It contains the elements titanium (Ti), zirconium (Zr), hafnium (Hf) and rutherfordium (Rf). This group lies in the d-block of the periodic table. The group itself has not acquired a trivial name; it
Block (periodic table) the s-block, with its outer (and only) electrons in the 1s atomic orbital, although its chemical properties are more similar to the p-block noble gases due to its full shell. In addition to the blocks listed in this table, there is a hypothetical g-block which is not pictured here. The g-block elements can be seen in the expanded extended periodic table. Lanthanum and actinium are placed under scandium and yttrium to reflect their status as d-block elements, as they have no electrons in the 4f and 5f orbitals, respectively, while lutetium and lawrencium do. The s-block is on the left