Group 4 element Group 4 element Group 4 is a group of elements in the periodic table. It contains the elements titanium (Ti), zirconium (Zr), hafnium (Hf) and rutherfordium (Rf). This group lies in the d-block of the periodic table. The group itself has not acquired a trivial name; it belongs to the broader grouping of the transition metals. The three Group 4 elements that occur naturally are titanium, zirconium and hafnium. The first three members of the group share similar properties; all three are hard refractory metals under standard conditions. However, the fourth element rutherfordium (Rf), has been synthesized in the laboratory;
History of the periodic table managed to get thallium, lead, mercury and platinum into the right groups, which is something that Mendeleev failed to do at his first attempt. Odling failed to achieve recognition, however, since it is suspected that he, as Secretary of the Chemical Society of London, was instrumental in discrediting Newlands' earlier work on the periodic table. By 1912 almost 50 different radioactive elements had been found, too many for the periodic table. Frederick Soddy in 1913 found that although they emitted different radiation, many elements were alike in their chemical characteristics so shared the same place on the table. They became