Formula unit Formula unit A formula unit in chemistry is the empirical formula of any ionic or covalent network solid compound used as an independent entity for stoichiometric calculations. It is the lowest whole number ratio of ions represented in an ionic compound. Examples include ionic NaCl and KO and covalent networks such as SiO and C (as diamond or graphite). Ionic compounds do not exist as individual molecules; a formula unit thus indicates the lowest reduced ratio of ions in the compound. A "chemical formula" shows the kinds and numbers of atoms in the smallest representative unit of a substance. In
Chemical compound from chemical compounds, which require the fixed ratios. Many solid chemical substances—for example many silicate minerals—are chemical substances, but do not have simple formulae reflecting chemically bonding of elements to one another in fixed ratios; even so, these crystalline substances are often called "non-stoichiometric compounds". It may be argued that they are related to, rather than being chemical compounds, insofar as the variability in their compositions is often due to either the presence of foreign elements trapped within the crystal structure of an otherwise known true "chemical compound", or due to perturbations in structure relative to the known compound that