Cinnabar akin to that of HgO: each Hg center has two short Hg−S bonds (each 2.36 Å), and four longer contacts (with 3.10, 3.10, 3.30, and 3.30 Å separations). In addition, HgS is found in a black, non-cinnabar polymorph (metacinnabar) that has the zincblende structure. Cinnabar generally occurs as a vein-filling mineral associated with recent volcanic activity and alkaline hot springs. Cinnabar is deposited by epithermal ascending aqueous solutions (those near surface and not too hot) far removed from their igneous source. It is associated with native mercury, stibnite, realgar, pyrite, marcasite, opal, quartz, chalcedony, dolomite, calcite and barite. Cinnabar is
Metal subsurface mines. In some cases, the sale price of the metal/s involved make it economically feasible to mine lower concentration sources. Once the ore is mined, the metals must be extracted, usually by chemical or electrolytic reduction. Pyrometallurgy uses high temperatures to convert ore into raw metals, while hydrometallurgy employs aqueous chemistry for the same purpose. The methods used depend on the metal and their contaminants. When a metal ore is an ionic compound of that metal and a non-metal, the ore must usually be smelted—heated with a reducing agent—to extract the pure metal. Many common metals, such as iron,