Group 12 element by mass, and even the leanest concentrated deposits are at least 0.1% mercury (12,000 times average crustal abundance). It is found either as a native metal (rare) or in cinnabar (HgS), corderoite, livingstonite and other minerals, with cinnabar being the most common ore. While mercury and zinc minerals are found in large enough quantities to be mined, cadmium is too similar to zinc and therefore is always present in small quantities in zinc ores from where it is recovered. Identified world zinc resources total about 1.9 billion tonnes. Large deposits are in Australia, Canada and the United States with the
Metal ammine complex is ammonia (pK ~ 33). For highly cationic complexes such as [Pt(NH)], the conjugate base can be obtained. The deprotonation of cobalt(III) ammine-halide complexes, e.g. [CoCl(NH)] labilises the Co-Cl bond, according to the Sn1CB mechanism. Metal ammine complexes find many uses. Cisplatin (PtCl(NH)) is a coordination compound containing two chloro and two ammine ligands. This is a drug used in treating cancer. Many other amine complexes of the platinum group metals have been evaluated for this application. In the separation of the individual platinum metals from their ore, several schemes rely on the precipitation of [RhCl(NH)]Cl. In some separation schemes,