Formula unit Formula unit A formula unit in chemistry is the empirical formula of any ionic or covalent network solid compound used as an independent entity for stoichiometric calculations. It is the lowest whole number ratio of ions represented in an ionic compound. Examples include ionic NaCl and KO and covalent networks such as SiO and C (as diamond or graphite). Ionic compounds do not exist as individual molecules; a formula unit thus indicates the lowest reduced ratio of ions in the compound. A "chemical formula" shows the kinds and numbers of atoms in the smallest representative unit of a substance. In
Chemical substance regard. A chemical substance may well be defined as "any material with a definite chemical composition" in an introductory general chemistry textbook. According to this definition a chemical substance can either be a pure chemical element or a pure chemical compound. But, there are exceptions to this definition; a pure substance can also be defined as a form of matter that has both definite composition and distinct properties. The chemical substance index published by CAS also includes several alloys of uncertain composition. Non-stoichiometric compounds are a special case (in inorganic chemistry) that violates the law of constant composition, and for