Isomeric shift levels E, followed by emission of photons. Atomic levels are a manifestation of the electromagnetic interaction between electrons and nuclei. The energy levels of two atoms the nuclei of which are different isotopes of the same element are shifted one with respect to the other, despite the fact that the electric charges Z of the two isotopes are identical. This is so because isotopes differ by the number of neutrons and therefore the masses and volumes of two isotopes are different; these differences give rise to the isotopic shift on atomic spectral lines. In the case of two nuclear isomers
Atomic number neutral atom, which is "Z" (the atomic number). The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element's electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. Hence, it is the atomic number alone that determines the chemical properties of an element; and it is for this reason that an element can be defined as consisting of "any" mixture of atoms with a given atomic number. The quest for new elements is usually described using atomic numbers. As of 2010, all elements with