Lava Vesuvius between May 14 and June 4, 1737. Serao described "a flow of fiery lava" as an analogy to the flow of water and mud down the flanks of the volcano following heavy rain. The composition of almost all lava of the Earth's crust is dominated by silicate minerals, mostly feldspars, olivine, pyroxenes, amphiboles, micas and quartz. Igneous rocks, which form lava flows when erupted, can be classified into three chemical types: "felsic", "intermediate", and "mafic" (four if one includes the super-heated "ultramafic"). These classes are primarily chemical, however, the chemistry of lava also tends to correlate with the magma
Samarium–neodymium dating minerals, so a mafic rock which crystallises mafic minerals will concentrate neodymium in the melt phase relative to samarium. Thus, as a melt undergoes fractional crystallization from a mafic to a more felsic composition, the abundance of Sm and Nd changes, as does the ratio between Sm and Nd. Thus, ultramafic rocks have high Sm and low Nd and therefore "high" Sm/Nd ratios. Felsic rocks have low concentrations of Sm and high Nd and therefore "low" Sm/Nd ratios (for example komatiite has 1.14 parts per million (ppm) Sm and 3.59 ppm Nd versus 4.65 ppm Sm and 21.6 ppm Nd