Isomeric shift levels E, followed by emission of photons. Atomic levels are a manifestation of the electromagnetic interaction between electrons and nuclei. The energy levels of two atoms the nuclei of which are different isotopes of the same element are shifted one with respect to the other, despite the fact that the electric charges Z of the two isotopes are identical. This is so because isotopes differ by the number of neutrons and therefore the masses and volumes of two isotopes are different; these differences give rise to the isotopic shift on atomic spectral lines. In the case of two nuclear isomers
Isotope chemical properties (again with deuterium and tritium being the primary exceptions). The vibrational modes of a molecule are determined by its shape and by the masses of its constituent atoms; so different isotopologues have different sets of vibrational modes. Because vibrational modes allow a molecule to absorb photons of corresponding energies, isotopologues have different optical properties in the infrared range. Atomic nuclei consist of protons and neutrons bound together by the residual strong force. Because protons are positively charged, they repel each other. Neutrons, which are electrically neutral, stabilize the nucleus in two ways. Their copresence pushes protons slightly apart,