Atomic number and the mass defect of nucleon binding is always small compared to the nucleon mass, the atomic mass of any atom, when expressed in unified atomic mass units (making a quantity called the "relative isotopic mass"), is within 1% of the whole number "A". Atoms with the same atomic number "Z" but different neutron numbers "N", and hence different atomic masses, are known as isotopes. A little more than three-quarters of naturally occurring elements exist as a mixture of isotopes (see monoisotopic elements), and the average isotopic mass of an isotopic mixture for an element (called the relative atomic mass)
Atomic orbital polynomial series, and exponential and trigonometric functions. (see hydrogen atom). For atoms with two or more electrons, the governing equations can only be solved with the use of methods of iterative approximation. Orbitals of multi-electron atoms are "qualitatively" similar to those of hydrogen, and in the simplest models, they are taken to have the same form. For more rigorous and precise analysis, numerical approximations must be used. A given (hydrogen-like) atomic orbital is identified by unique values of three quantum numbers: , , and . The rules restricting the values of the quantum numbers, and their energies (see below), explain