Air conditioning eventually reach the upper atmosphere. Once the refrigerant reaches the stratosphere, UV radiation from the Sun homolytically cleaves the chlorine-carbon bond, yielding a chlorine radical. These chlorine radicals catalyze the breakdown of ozone into diatomic oxygen, depleting the ozone layer that shields the Earth's surface from strong UV radiation. Each chlorine radical remains active as a catalyst until it binds with another radical, forming a stable molecule and quenching the chain reaction. Prior to 1994, most automotive air conditioning systems used R-12 as a refrigerant. It was replaced with R-134a refrigerant, which has no ozone depletion potential. Old R-12 systems
UV degradation in LDPE, which had cracked prematurely in service. Many similar cones also failed because an anti-UV additive had not been used during processing. Other plastic products which failed included polypropylene mancabs used at roadworks which cracked after service of only a few months. UV attack by sunlight can be ameliorated or prevented by adding anti-UV chemicals to the polymer when mixing the ingredients, prior to shaping the product by injection moulding for example. UV stabilizers in plastics usually act by absorbing the UV radiation preferentially, and dissipating the energy as low-level heat. The chemicals used are similar to those in