Air conditioning eventually reach the upper atmosphere. Once the refrigerant reaches the stratosphere, UV radiation from the Sun homolytically cleaves the chlorine-carbon bond, yielding a chlorine radical. These chlorine radicals catalyze the breakdown of ozone into diatomic oxygen, depleting the ozone layer that shields the Earth's surface from strong UV radiation. Each chlorine radical remains active as a catalyst until it binds with another radical, forming a stable molecule and quenching the chain reaction. Prior to 1994, most automotive air conditioning systems used R-12 as a refrigerant. It was replaced with R-134a refrigerant, which has no ozone depletion potential. Old R-12 systems
Electromagnetic radiation that the effect, if it exists, cannot be a large one. At higher frequencies (visible and beyond), the effects of individual photons begin to become important, as these now have enough energy individually to directly or indirectly damage biological molecules. All UV frequences have been classed as Group 1 carcinogens by the World Health Organization. Ultraviolet radiation from sun exposure is the primary cause of skin cancer. Thus, at UV frequencies and higher (and probably somewhat also in the visible range), electromagnetic radiation does more damage to biological systems than simple heating predicts. This is most obvious in the "far"