Air conditioning eventually reach the upper atmosphere. Once the refrigerant reaches the stratosphere, UV radiation from the Sun homolytically cleaves the chlorine-carbon bond, yielding a chlorine radical. These chlorine radicals catalyze the breakdown of ozone into diatomic oxygen, depleting the ozone layer that shields the Earth's surface from strong UV radiation. Each chlorine radical remains active as a catalyst until it binds with another radical, forming a stable molecule and quenching the chain reaction. Prior to 1994, most automotive air conditioning systems used R-12 as a refrigerant. It was replaced with R-134a refrigerant, which has no ozone depletion potential. Old R-12 systems
UV filter to sun irradiation, while swimming-pool water is required to be disinfected by chlorination, bromination, ozonation, or UV-irradiation. UV filters can undergo degradation and transformation to more toxic products. For example, Avobenzone undergoes transformation in the presence of chlorinated disinfection products and UV radiation to substituted chlorinated phenols and acetophenones, which are known for their toxicity. Some organic UV filters under UV radiation can generate reactive Oxygen Species (ROS) (OH, HO) (e.g. BP-3, octocrylene (OCR), OMC, phenylbenzimidazole sulphonic acid (PBS), PABA, etc.).The levels of HO in waters of Mediterranean beach reached 270 nM/day as a result of Sunscreens. HO as an