Vapor-compression refrigeration replaced, such as sulfur dioxide. Haloalkanes are also an order(s) of magnitude more expensive than petroleum derived flammable alkanes of similar or better cooling performance. Unfortunately, chlorine- and fluorine-bearing refrigerants reach the upper atmosphere when they escape. In the stratosphere, CFCs break up due to UV radiation, releasing their chlorine free radicals. These chlorine free radicals act as catalysts in the breakdown of ozone through chain reactions. One CFC molecule can cause thousands of ozone molecules to break down. This causes severe damage to the ozone layer that shields the Earth's surface from the Sun's strong UV radiation, and has
Attribution of recent climate change in a cooling effect in the stratosphere. If the sun was responsible for observed warming, warming of the troposphere at the surface and warming at the top of the stratosphere would be expected as increase solar activity would replenish ozone and oxides of nitrogen. The stratosphere has a reverse temperature gradient than the troposphere so as the temperature of the troposphere cools with altitude, the stratosphere rises with altitude. Hadley cells are the mechanism by which equatorial generated ozone in the tropics (highest area of UV irradiance in the stratosphere) is moved poleward. Global climate models suggest that climate change