Vapor-compression refrigeration replaced, such as sulfur dioxide. Haloalkanes are also an order(s) of magnitude more expensive than petroleum derived flammable alkanes of similar or better cooling performance. Unfortunately, chlorine- and fluorine-bearing refrigerants reach the upper atmosphere when they escape. In the stratosphere, CFCs break up due to UV radiation, releasing their chlorine free radicals. These chlorine free radicals act as catalysts in the breakdown of ozone through chain reactions. One CFC molecule can cause thousands of ozone molecules to break down. This causes severe damage to the ozone layer that shields the Earth's surface from the Sun's strong UV radiation, and has
UV filter oxidizing specie is responsible of damaging lipids, proteins and DNA and generating high stress levels in marine organisms. Inorganic UV-filters (i.e. TiO2) can also generate ROS, which is toxic for the marine phytoplankton .The toxicity of nano-TiO is due to its photochemical properties under solar radiation that depend on the radiation intensity, the crystalline structure and the concentration of the nanoparticles. In addition, the inert coating layer of the nanoparticles which protects against photoreactivity is dissolved in aquatic environments after being released from sunscreens. Photolysis is the main abiotic route for transformation of UV filters. Photolysis dissociates the organic filters