Vapor-compression refrigeration replaced, such as sulfur dioxide. Haloalkanes are also an order(s) of magnitude more expensive than petroleum derived flammable alkanes of similar or better cooling performance. Unfortunately, chlorine- and fluorine-bearing refrigerants reach the upper atmosphere when they escape. In the stratosphere, CFCs break up due to UV radiation, releasing their chlorine free radicals. These chlorine free radicals act as catalysts in the breakdown of ozone through chain reactions. One CFC molecule can cause thousands of ozone molecules to break down. This causes severe damage to the ozone layer that shields the Earth's surface from the Sun's strong UV radiation, and has
UV filter differ in biological behavior and effects. Swimming pool water is usually disinfected by chlorination, bromination, ozonation or UV radiation. Upon the presence of some UV filters such as Avobenzone in swimming pools, toxic products are produced as a result of the interaction between Avobenzone and the active chlorine and UV radiation. Benzophenones (BPs) are widely used in UV filters, fragrance enhancers,and plastic additives. The major sources of BP-3 are reported to be human recreational activities and wastewater treatment plant (WWTP) effluents.The anionic forms of both BP-3 and 4-OH-BP3 can undergo direct photodegradation. The photolytic rates of both compounds in natural