Air conditioning eventually reach the upper atmosphere. Once the refrigerant reaches the stratosphere, UV radiation from the Sun homolytically cleaves the chlorine-carbon bond, yielding a chlorine radical. These chlorine radicals catalyze the breakdown of ozone into diatomic oxygen, depleting the ozone layer that shields the Earth's surface from strong UV radiation. Each chlorine radical remains active as a catalyst until it binds with another radical, forming a stable molecule and quenching the chain reaction. Prior to 1994, most automotive air conditioning systems used R-12 as a refrigerant. It was replaced with R-134a refrigerant, which has no ozone depletion potential. Old R-12 systems
Attribution of recent climate change in a cooling effect in the stratosphere. If the sun was responsible for observed warming, warming of the troposphere at the surface and warming at the top of the stratosphere would be expected as increase solar activity would replenish ozone and oxides of nitrogen. The stratosphere has a reverse temperature gradient than the troposphere so as the temperature of the troposphere cools with altitude, the stratosphere rises with altitude. Hadley cells are the mechanism by which equatorial generated ozone in the tropics (highest area of UV irradiance in the stratosphere) is moved poleward. Global climate models suggest that climate change