Silver tetrafluoroborate Silver tetrafluoroborate Silver tetrafluoroborate is an inorganic compound with the chemical formula AgBF. It is a white solid that dissolves in polar organic solvents as well as water. In its solid state, the Ag centers are bound to fluoride. Silver tetrafluoroborate is prepared by the reaction between boron trifluoride and silver oxide in the presence of benzene. In the inorganic and organometallic chemistry laboratory, silver tetrafluoroborate, sometimes referred to "silver BF-4", is a useful reagent. In dichloromethane, silver tetrafluoroborate is a moderately strong oxidant. Similar to silver hexafluorophosphate, it is commonly used to replace halide anions or ligands with the
Silver perchlorate and toluene (1010 g/L). In these solvents, the silver cation binds to the arene, as has been demonstrated by extensive crystallographic studies on crystals obtained from such solutions. It is also amazingly soluble in water, up to 500 g per 100 mL of water. Similar to silver nitrate, silver perchlorate is an effective reagent for replacing halides ligands with perchlorate, which is a weakly or non-coordinating anion. The use of silver perchlorate in chemical synthesis has declined due to concerns about explosiveness of perchlorate salts. Other silver reagents are silver tetrafluoroborate, and the related silver trifluoromethanesulfonate and silver hexafluorophosphate. Silver