Silver cyanide reaction with other anions. Some silver cyanides are luminescent. Both AgCN and KAg(CN) have been used in silver-plating solutions since at least 1840 when the Elkington brothers patented their recipe for a silver-plating solution. A typical, traditional silver-plating solution would contain KAg(CN) 15-40 gL, KCN 12-120 gL and KCO gL. Silver cyanide Silver cyanide is the chemical compound with the formula AgCN. This white solid forms upon treatment of solutions containing Ag with cyanide. This precipitation step is used in some schemes to recover silver from solution. Silver cyanide is used in silver-plating. Its structure consist of -[Ag-CN]- chains in
Silver perchlorate and toluene (1010 g/L). In these solvents, the silver cation binds to the arene, as has been demonstrated by extensive crystallographic studies on crystals obtained from such solutions. It is also amazingly soluble in water, up to 500 g per 100 mL of water. Similar to silver nitrate, silver perchlorate is an effective reagent for replacing halides ligands with perchlorate, which is a weakly or non-coordinating anion. The use of silver perchlorate in chemical synthesis has declined due to concerns about explosiveness of perchlorate salts. Other silver reagents are silver tetrafluoroborate, and the related silver trifluoromethanesulfonate and silver hexafluorophosphate. Silver