Silver tetrafluoroborate weakly coordinating tetrafluoroborate anions. The abstraction of the halide is driven by the precipitation of the appropriate silver halide. Silver tetrafluoroborate Silver tetrafluoroborate is an inorganic compound with the chemical formula AgBF. It is a white solid that dissolves in polar organic solvents as well as water. In its solid state, the Ag centers are bound to fluoride. Silver tetrafluoroborate is prepared by the reaction between boron trifluoride and silver oxide in the presence of benzene. In the inorganic and organometallic chemistry laboratory, silver tetrafluoroborate, sometimes referred to "silver BF-4", is a useful reagent. In dichloromethane, silver tetrafluoroborate is a
Silver usually obtained by reacting silver or silver monofluoride with the strongest known oxidizing agent, krypton difluoride. Silver and gold have rather low chemical affinities for oxygen, lower than copper, and it is therefore expected that silver oxides are thermally quite unstable. Soluble silver(I) salts precipitate dark-brown silver(I) oxide, AgO, upon the addition of alkali. (The hydroxide AgOH exists only in solution; otherwise it spontaneously decomposes to the oxide.) Silver(I) oxide is very easily reduced to metallic silver, and decomposes to silver and oxygen above 160 °C. This and other silver(I) compounds may be oxidized by the strong oxidizing agent peroxodisulfate