Silver oxide Silver oxide Silver(I) oxide is the chemical compound with the formula AgO. It is a fine black or dark brown powder that is used to prepare other silver compounds. Silver oxide can be prepared by combining aqueous solutions of silver nitrate and an alkali hydroxide. This reaction does not afford appreciable amounts of silver hydroxide due to the favorable energetics for the following reaction: US patent 20050050990 describes the preparation of AgO with properties suitable for use as a fine grained conductive paste filler. AgO features linear, two-coordinate Ag centers linked by tetrahedral oxides. It is isostructural with CuO. It
Silver hexafluorophosphate Silver hexafluorophosphate Silver hexafluorophosphate, sometimes referred to "silver PF-6," is an inorganic compound with the chemical formula AgPF. Silver hexafluorophosphate is a commonly encountered reagent in inorganic and organometallic chemistry. It is commonly used to replace halide ligands with the weakly coordinating hexafluorophosphate anion; the abstraction of the halide is driven by the precipitation of the appropriate silver halide. Illustrative is the preparation of acetonitrile complexes from a metal bromide, a reaction that would typically be conducted in a solution of acetonitrile: AgPF can act as an oxidant, forming silver metal as a by-product. For example, in solution in dichloromethane,