Air conditioning eventually reach the upper atmosphere. Once the refrigerant reaches the stratosphere, UV radiation from the Sun homolytically cleaves the chlorine-carbon bond, yielding a chlorine radical. These chlorine radicals catalyze the breakdown of ozone into diatomic oxygen, depleting the ozone layer that shields the Earth's surface from strong UV radiation. Each chlorine radical remains active as a catalyst until it binds with another radical, forming a stable molecule and quenching the chain reaction. Prior to 1994, most automotive air conditioning systems used R-12 as a refrigerant. It was replaced with R-134a refrigerant, which has no ozone depletion potential. Old R-12 systems
The empire on which the sun never sets at the present time." In 1821, the "Caledonian Mercury" wrote of the British Empire, "On her dominions the sun never sets; before his evening rays leave the spires of Quebec, his morning beams have shone three hours on Port Jackson, and while sinking from the waters of Lake Superior, his eye opens upon the Mouth of the Ganges." Daniel Webster famously expressed a similar idea in 1834: "A power which has dotted over the surface of the whole globe with her possessions and military posts, whose morning drumbeat, following the sun and keeping company with the hours, circles the earth