Vapor-compression refrigeration replaced, such as sulfur dioxide. Haloalkanes are also an order(s) of magnitude more expensive than petroleum derived flammable alkanes of similar or better cooling performance. Unfortunately, chlorine- and fluorine-bearing refrigerants reach the upper atmosphere when they escape. In the stratosphere, CFCs break up due to UV radiation, releasing their chlorine free radicals. These chlorine free radicals act as catalysts in the breakdown of ozone through chain reactions. One CFC molecule can cause thousands of ozone molecules to break down. This causes severe damage to the ozone layer that shields the Earth's surface from the Sun's strong UV radiation, and has
Volcano above the Earth's surface. The most significant impacts from these injections come from the conversion of sulfur dioxide to sulfuric acid (HSO), which condenses rapidly in the stratosphere to form fine sulfate aerosols. The SO emissions alone of two different eruptions are sufficient to compare their potential climatic impact. The aerosols increase the Earth's albedo—its reflection of radiation from the Sun back into space—and thus cool the Earth's lower atmosphere or troposphere; however, they also absorb heat radiated up from the Earth, thereby warming the stratosphere. Several eruptions during the past century have caused a decline in the average temperature