Air conditioning eventually reach the upper atmosphere. Once the refrigerant reaches the stratosphere, UV radiation from the Sun homolytically cleaves the chlorine-carbon bond, yielding a chlorine radical. These chlorine radicals catalyze the breakdown of ozone into diatomic oxygen, depleting the ozone layer that shields the Earth's surface from strong UV radiation. Each chlorine radical remains active as a catalyst until it binds with another radical, forming a stable molecule and quenching the chain reaction. Prior to 1994, most automotive air conditioning systems used R-12 as a refrigerant. It was replaced with R-134a refrigerant, which has no ozone depletion potential. Old R-12 systems
UV filter differ in biological behavior and effects. Swimming pool water is usually disinfected by chlorination, bromination, ozonation or UV radiation. Upon the presence of some UV filters such as Avobenzone in swimming pools, toxic products are produced as a result of the interaction between Avobenzone and the active chlorine and UV radiation. Benzophenones (BPs) are widely used in UV filters, fragrance enhancers,and plastic additives. The major sources of BP-3 are reported to be human recreational activities and wastewater treatment plant (WWTP) effluents.The anionic forms of both BP-3 and 4-OH-BP3 can undergo direct photodegradation. The photolytic rates of both compounds in natural