Silver halide Silver halide A silver halide (or silver salt) is one of the chemical compounds that can form between the element silver and one of the halogens. In particular, bromine, chlorine, iodine and fluorine may each combine with silver to produce silver bromide (AgBr), silver chloride (AgCl), silver iodide (AgI), and three forms of silver fluoride, respectively. As a group, they are often referred to as the silver halides, and are often given the pseudo-chemical notation AgX. Although most silver halides involve silver atoms with oxidation states of +1 (Ag), silver halides in which the silver atoms have oxidation states of
Silver hexafluorophosphate Silver hexafluorophosphate Silver hexafluorophosphate, sometimes referred to "silver PF-6," is an inorganic compound with the chemical formula AgPF. Silver hexafluorophosphate is a commonly encountered reagent in inorganic and organometallic chemistry. It is commonly used to replace halide ligands with the weakly coordinating hexafluorophosphate anion; the abstraction of the halide is driven by the precipitation of the appropriate silver halide. Illustrative is the preparation of acetonitrile complexes from a metal bromide, a reaction that would typically be conducted in a solution of acetonitrile: AgPF can act as an oxidant, forming silver metal as a by-product. For example, in solution in dichloromethane,