Air conditioning eventually reach the upper atmosphere. Once the refrigerant reaches the stratosphere, UV radiation from the Sun homolytically cleaves the chlorine-carbon bond, yielding a chlorine radical. These chlorine radicals catalyze the breakdown of ozone into diatomic oxygen, depleting the ozone layer that shields the Earth's surface from strong UV radiation. Each chlorine radical remains active as a catalyst until it binds with another radical, forming a stable molecule and quenching the chain reaction. Prior to 1994, most automotive air conditioning systems used R-12 as a refrigerant. It was replaced with R-134a refrigerant, which has no ozone depletion potential. Old R-12 systems
Volcano above the Earth's surface. The most significant impacts from these injections come from the conversion of sulfur dioxide to sulfuric acid (HSO), which condenses rapidly in the stratosphere to form fine sulfate aerosols. The SO emissions alone of two different eruptions are sufficient to compare their potential climatic impact. The aerosols increase the Earth's albedo—its reflection of radiation from the Sun back into space—and thus cool the Earth's lower atmosphere or troposphere; however, they also absorb heat radiated up from the Earth, thereby warming the stratosphere. Several eruptions during the past century have caused a decline in the average temperature