Silver tetrafluoroborate weakly coordinating tetrafluoroborate anions. The abstraction of the halide is driven by the precipitation of the appropriate silver halide. Silver tetrafluoroborate Silver tetrafluoroborate is an inorganic compound with the chemical formula AgBF. It is a white solid that dissolves in polar organic solvents as well as water. In its solid state, the Ag centers are bound to fluoride. Silver tetrafluoroborate is prepared by the reaction between boron trifluoride and silver oxide in the presence of benzene. In the inorganic and organometallic chemistry laboratory, silver tetrafluoroborate, sometimes referred to "silver BF-4", is a useful reagent. In dichloromethane, silver tetrafluoroborate is a
Silver hexafluorophosphate Silver hexafluorophosphate Silver hexafluorophosphate, sometimes referred to "silver PF-6," is an inorganic compound with the chemical formula AgPF. Silver hexafluorophosphate is a commonly encountered reagent in inorganic and organometallic chemistry. It is commonly used to replace halide ligands with the weakly coordinating hexafluorophosphate anion; the abstraction of the halide is driven by the precipitation of the appropriate silver halide. Illustrative is the preparation of acetonitrile complexes from a metal bromide, a reaction that would typically be conducted in a solution of acetonitrile: AgPF can act as an oxidant, forming silver metal as a by-product. For example, in solution in dichloromethane,