Vapor-compression refrigeration replaced, such as sulfur dioxide. Haloalkanes are also an order(s) of magnitude more expensive than petroleum derived flammable alkanes of similar or better cooling performance. Unfortunately, chlorine- and fluorine-bearing refrigerants reach the upper atmosphere when they escape. In the stratosphere, CFCs break up due to UV radiation, releasing their chlorine free radicals. These chlorine free radicals act as catalysts in the breakdown of ozone through chain reactions. One CFC molecule can cause thousands of ozone molecules to break down. This causes severe damage to the ozone layer that shields the Earth's surface from the Sun's strong UV radiation, and has
Electromagnetic radiation that the effect, if it exists, cannot be a large one. At higher frequencies (visible and beyond), the effects of individual photons begin to become important, as these now have enough energy individually to directly or indirectly damage biological molecules. All UV frequences have been classed as Group 1 carcinogens by the World Health Organization. Ultraviolet radiation from sun exposure is the primary cause of skin cancer. Thus, at UV frequencies and higher (and probably somewhat also in the visible range), electromagnetic radiation does more damage to biological systems than simple heating predicts. This is most obvious in the "far"