Air conditioning eventually reach the upper atmosphere. Once the refrigerant reaches the stratosphere, UV radiation from the Sun homolytically cleaves the chlorine-carbon bond, yielding a chlorine radical. These chlorine radicals catalyze the breakdown of ozone into diatomic oxygen, depleting the ozone layer that shields the Earth's surface from strong UV radiation. Each chlorine radical remains active as a catalyst until it binds with another radical, forming a stable molecule and quenching the chain reaction. Prior to 1994, most automotive air conditioning systems used R-12 as a refrigerant. It was replaced with R-134a refrigerant, which has no ozone depletion potential. Old R-12 systems
Atmospheric physics radiation (emitted by the sun) and terrestrial radiation (emitted by Earth's surface and atmosphere). Solar radiation contains variety of wavelengths. Visible light has wavelengths between 0.4 and 0.7 micrometers. Shorter wavelengths are known as the ultraviolet (UV) part of the spectrum, while longer wavelengths are grouped into the infrared portion of the spectrum. Ozone is most effective in absorbing radiation around 0.25 micrometers, where UV-c rays lie in the spectrum. This increases the temperature of the nearby stratosphere. Snow reflects 88% of UV rays, while sand reflects 12%, and water reflects only 4% of incoming UV radiation. The more glancing