Silver cyanide reaction with other anions. Some silver cyanides are luminescent. Both AgCN and KAg(CN) have been used in silver-plating solutions since at least 1840 when the Elkington brothers patented their recipe for a silver-plating solution. A typical, traditional silver-plating solution would contain KAg(CN) 15-40 gL, KCN 12-120 gL and KCO gL. Silver cyanide Silver cyanide is the chemical compound with the formula AgCN. This white solid forms upon treatment of solutions containing Ag with cyanide. This precipitation step is used in some schemes to recover silver from solution. Silver cyanide is used in silver-plating. Its structure consist of -[Ag-CN]- chains in
Silver carbonate Silver carbonate Silver carbonate is the chemical compound with the formula AgCO. Silver carbonate is yellow but typical samples are grayish due to the presence of elemental silver. It is poorly soluble in water, like most transition metal carbonates. Silver carbonate can be prepared by combining aqueous solutions of sodium carbonate with a deficiency of silver nitrate. Freshly prepared silver carbonate is colourless, but the solid quickly turns yellow. Silver carbonate reacts with ammonia to give the explosive fulminating silver. With hydrofluoric acid, it gives silver fluoride. The thermal conversion of silver carbonate to silver metal proceeds via formation of