History of Earth the third atmosphere, rich in oxygen, emerged when bacteria began to produce oxygen about 2.8 Ga. In early models for the formation of the atmosphere and ocean, the second atmosphere was formed by outgassing of volatiles from the Earth's interior. Now it is considered likely that many of the volatiles were delivered during accretion by a process known as "impact degassing" in which incoming bodies vaporize on impact. The ocean and atmosphere would, therefore, have started to form even as the Earth formed. The new atmosphere probably contained water vapor, carbon dioxide, nitrogen, and smaller amounts of other gases. Planetesimals
Atmosphere of Earth vapor, on average around 1% at sea level, and 0.4% over the entire atmosphere. Air content and atmospheric pressure vary at different layers, and air suitable for use in photosynthesis by terrestrial plants and breathing of terrestrial animals is found only in Earth's troposphere and in artificial atmospheres. The atmosphere has a mass of about 5.15 kg, three quarters of which is within about of the surface. The atmosphere becomes thinner and thinner with increasing altitude, with no definite boundary between the atmosphere and outer space. The Kármán line, at , or 1.57% of Earth's radius, is often used as