History of Earth the third atmosphere, rich in oxygen, emerged when bacteria began to produce oxygen about 2.8 Ga. In early models for the formation of the atmosphere and ocean, the second atmosphere was formed by outgassing of volatiles from the Earth's interior. Now it is considered likely that many of the volatiles were delivered during accretion by a process known as "impact degassing" in which incoming bodies vaporize on impact. The ocean and atmosphere would, therefore, have started to form even as the Earth formed. The new atmosphere probably contained water vapor, carbon dioxide, nitrogen, and smaller amounts of other gases. Planetesimals
Atmosphere of Earth sublimated into polar-mesospheric noctilucent clouds. These are the highest clouds in the atmosphere and may be visible to the naked eye if sunlight reflects off them about an hour or two after sunset or a similar length of time before sunrise. They are most readily visible when the Sun is around 4 to 16 degrees below the horizon. Lightning-induced discharges known as transient luminous events (TLEs) occasionally form in the mesosphere above tropospheric thunderclouds. The mesosphere is also the layer where most meteors burn up upon atmospheric entrance. It is too high above Earth to be accessible to jet-powered aircraft