History of Earth the third atmosphere, rich in oxygen, emerged when bacteria began to produce oxygen about 2.8 Ga. In early models for the formation of the atmosphere and ocean, the second atmosphere was formed by outgassing of volatiles from the Earth's interior. Now it is considered likely that many of the volatiles were delivered during accretion by a process known as "impact degassing" in which incoming bodies vaporize on impact. The ocean and atmosphere would, therefore, have started to form even as the Earth formed. The new atmosphere probably contained water vapor, carbon dioxide, nitrogen, and smaller amounts of other gases. Planetesimals
Atmosphere may have outer atmospheres with compound molecules. Atmospheric pressure at a particular location is the force per unit area perpendicular to a surface determined by the weight of the vertical column of atmosphere above that location. On Earth, units of air pressure are based on the internationally recognized standard atmosphere (atm), which is defined as 101.325 kPa (760 Torr or 14.696 psi). It is measured with a barometer. Atmospheric pressure decreases with increasing altitude due to the diminishing mass of gas above. The height at which the pressure from an atmosphere declines by a factor of "e" (an irrational number