Metalworking oxidation is one of the main reasons that gold is found in nuggets. These nuggets are relatively pure gold and are workable as they are found. Copper ore, being relatively abundant, and tin ore became the next important players in the story of metalworking. Using heat to smelt copper from ore, a great deal of copper was produced. It was used for both jewelry and simple tools. However, copper by itself was too soft for tools requiring edges and stiffness. At some point tin was added into the molten copper and bronze was born. Bronze is an alloy of copper
Niobium alloy is also necessary to take care (e.g. hard chrome-plating of all copper tooling) to avoid copper contamination. Niobium alloy A niobium alloy is one in which the most common element is niobium. The most common commercial niobium alloys are ferroniobium and nickel-niobium, produced by thermite reduction of appropriate mixtures of the oxides; these are not usable as engineering materials, but are used as convenient sources of niobium for specialist steels and nickel-based superalloys. Going via an iron-niobium or nickel-niobium alloy avoids problems associated with the high melting point of niobium. Niobium-tin and Niobium-titanium are essential alloys for the industrial use