Temperature relevant coordinates are fixed. An exceptionally suitable system is the ideal gas, which can provide a temperature scale that matches the absolute Kelvin scale. The Kelvin scale is defined on the basis of the second law of thermodynamics. In the previous section certain properties of temperature were expressed by the zeroth law of thermodynamics. It is also possible to define temperature in terms of the second law of thermodynamics which deals with entropy. The second law states that any process will result in either no change or a net increase in the entropy of the universe. This can be understood
Absolute zero where "S" is the entropy. In such a circumstance, pure substances can (ideally) form perfect crystals as "T" → 0. Max Planck's strong form of the third law of thermodynamics states the entropy of a perfect crystal vanishes at absolute zero. The original Nernst "heat theorem" makes the weaker and less controversial claim that the entropy change for any isothermal process approaches zero as "T" → 0: The implication is that the entropy of a perfect crystal simply approaches a constant value. The Nernst postulate identifies the isotherm T = 0 as coincident with the adiabat S = 0, although