Heavy metals elements and the more reactive of the d-block elements. They have a strong affinity for oxygen and mostly exist as relatively low density silicate minerals. Chalcophile heavy metals are mainly the less reactive d-block elements, and period 4–6 p-block metals and metalloids. They are usually found in (insoluble) sulfide minerals. Being denser than the lithophiles, hence sinking lower into the crust at the time of its solidification, the chalcophiles tend to be less abundant than the lithophiles. On the other hand, gold is a siderophile, or iron-loving element. It does not readily form compounds with either oxygen or sulfur. At
Heavy metals essential nutrients (typically iron, cobalt, and zinc), or relatively harmless (such as ruthenium, silver, and indium), but can be toxic in larger amounts or certain forms. Other heavy metals, such as cadmium, mercury, and lead, are highly poisonous. Potential sources of heavy metal poisoning include mining, tailings, industrial wastes, agricultural runoff, occupational exposure, paints and treated timber. Physical and chemical characterisations of heavy metals need to be treated with caution, as the metals involved are not always consistently defined. As well as being relatively dense, heavy metals tend to be less reactive than lighter metals and have much less soluble