Trimethylamine N-oxide Trimethylamine N-oxide Trimethylamine "N"-oxide (TMAO) is an organic compound with the formula (CH)NO. It is in the class of amine oxides. Although the anhydrous compound is known, trimethylamine "N"-oxide is usually encountered as the dihydrate. It is a product of the oxidation of trimethylamine, a common metabolite in animals. Both the anhydrous and hydrated materials are white, water-soluble solids. Trimethylamine "N"-oxide is an osmolyte found in saltwater fishes, sharks, rays, molluscs, and crustaceans. It is considered as a protein stabilizer that may serve to counteract urea, the major osmolyte of sharks, skates and rays. It is also higher in deep-sea
Dihydrogen complex some cases, hydrogen ligands are usefully characterized by X-ray crystallography, but often the presence of metals, which strongly scatter X-rays, complicates the analysis. The triangular MH subunit has six normal modes of vibration, one of which is mainly of ν character. In free H, this very strong bond absorbs at 4300 cm, whereas in dihydrogen complexes the frequency drops to around 2800 cm. Two preparation methods involve the direct reactions with H gas. The first entails the addition of H to an unsaturated metal center, as originally reported for W(CO)(P-i-Pr)(H). In such cases, the unsaturated complex in fact features an