Mining in Cornwall and Devon tin was found as alluvial deposits of cassiterite in the gravels of stream beds. Eventually tin was mined underground; underground mines sprang up as early as the 16th century. Tin lodes were also found in outcroppings of cliffs. Tin is one of the earliest metals to have been exploited in Britain. Chalcolithic metal workers discovered that by putting a small proportion of tin (5 – 20%) in molten copper, the alloy bronze was produced. The alloy is harder than copper. The oldest production of tin-bronze is in Turkey about 3500 BC, but exploitation of the tin resources in Britain is
Tin(II) chloride to maintain the equilibrium towards the left-hand side (using Le Chatelier's principle). Solutions of SnCl are also unstable towards oxidation by the air: This can be prevented by storing the solution over lumps of tin metal. There are many such cases where tin(II) chloride acts as a reducing agent, reducing silver and gold salts to the metal, and iron(III) salts to iron(II), for example: It also reduces copper(II) to copper(I). Solutions of tin(II) chloride can also serve simply as a source of Sn ions, which can form other tin(II) compounds via precipitation reactions. For example, reaction with sodium sulfide produces