Mining in Cornwall and Devon tin was found as alluvial deposits of cassiterite in the gravels of stream beds. Eventually tin was mined underground; underground mines sprang up as early as the 16th century. Tin lodes were also found in outcroppings of cliffs. Tin is one of the earliest metals to have been exploited in Britain. Chalcolithic metal workers discovered that by putting a small proportion of tin (5 – 20%) in molten copper, the alloy bronze was produced. The alloy is harder than copper. The oldest production of tin-bronze is in Turkey about 3500 BC, but exploitation of the tin resources in Britain is
Zinc–copper couple greater than 90%, although an alloy containing similar proportions of zinc and copper is used in some cases. The couple is frequently prepared as a darkly-colored powder and is slurried in an ethereal solvent prior to being used in slight excess relative to the substrate. Activation of zinc by copper is essential to the couple’s utility, but the origin of this effect is poorly documented. It is speculated that copper enhances reactivity of zinc at the surface of the alloy. Zinc–copper couple has been prepared by numerous methods, which vary mainly with respect to the source of copper, but also