Mining in Cornwall and Devon tin was found as alluvial deposits of cassiterite in the gravels of stream beds. Eventually tin was mined underground; underground mines sprang up as early as the 16th century. Tin lodes were also found in outcroppings of cliffs. Tin is one of the earliest metals to have been exploited in Britain. Chalcolithic metal workers discovered that by putting a small proportion of tin (5 – 20%) in molten copper, the alloy bronze was produced. The alloy is harder than copper. The oldest production of tin-bronze is in Turkey about 3500 BC, but exploitation of the tin resources in Britain is
Chinese sun and moon mirrors most (1 part tin per 1 part copper) for "metallic mirrors", namely, the "jiànsuì" 鑒燧 "mirror-igniter" alloy (Hirth 1907: 217-218). However, these ratios are based on Chinese numerology instead of practical metallurgy. Beyond about 32% the alloy becomes excessively brittle, and increasing tin content brings no further advantages of any kind; this the Han metallurgists evidently knew. Indeed they knew much more, for they almost always added up to 9% of lead, a constituent which greatly improved the casting properties. Han specular metal is truly white, reflects without tinning or silvering, resists scratching and corrosion well, and was admirably adapted