Tin sources and trade in ancient times Bantu culture of Zimbabwe are known to have actively mined, smelted and traded tin between the 11th and 15th centuries AD . Tin deposits exist in many parts of South America, with minor deposits in southern Peru, Colombia, Brazil, and northwestern Argentina, and major deposits of exploitable cassiterite in northern Bolivia. These deposits were exploited as early as 1000 AD in the manufacture of tin bronze by Andean cultures, including the later Inca Empire, which considered tin bronze the "imperial alloy". In North America, the only known exploitable source of tin during ancient times is located in the Zacatecas tin
Copper in heat exchangers titanium. This article focuses on beneficial properties and common applications of copper in heat exchangers. New copper heat exchanger technologies for specific applications are also introduced. Heat exchangers using copper and its alloys have evolved along with heat transfer technologies over the past several hundred years. Copper condenser tubes were first used in 1769 for steam engines. Initially, the tubes were made of unalloyed copper. By 1870, Muntz metal, a 60% Cu-40% Zn brass alloy, was used for condensers in seawater cooling. Admiralty metal, a 70% Cu-30% Zn yellow brass alloy with 1% tin added to improve corrosion resistance, was