Tin mining to trace metal content in the copper ore It was soon discovered that the addition of tin or arsenic to copper increased its hardness and made casting much easier, which revolutionized metal working techniques and brought humanity from the Copper Age or Chalcolithic to the Bronze Age around 3000 BC. Early tin exploitation appears to have been centered on placer deposits of cassiterite. The first evidence of tin use for making bronze appears in the Near East and the Balkans around 3000 BC. It is still unclear where the earliest tin was mined, as tin deposits are very rare and
Tin-silver-copper been increasing. Large companies such as Sony and Intel switched from using lead-containing solder to a tin-silver-copper alloy. The process requirements for SAC solders (Pb-free) and Sn-Pb solders are different both materially and logistically for electronic assembly. In addition, the reliability of Sn-Pb solders is well established, while SAC solders are still undergoing study, (though much work has been done to justify the use of SAC solders, such as the iNEMI Lead Free Solder Project). One important difference is that Pb-free soldering requires higher temperatures and increased process control to achieve the same results as that of the tin-lead method.