Dihydrogen monoxide parody story has since been used in science education to encourage critical thinking and discussion of the scientific method. A 1983 April Fools' Day edition of the "Durand Express", a weekly newspaper in Durand, Michigan, reported that "dihydrogen oxide" had been found in the city's water pipes, and warned that it was fatal if inhaled, and could produce blistering vapors. The first appearance of the parody on the Internet was attributed by the "Pittsburgh Post-Gazette" to the so-called "Coalition to Ban Dihydrogen Monoxide", a parody organization at UC Santa Cruz following on-campus postings and newsgroup discussions in 1990. This new version
Dihydrogen complex agostic interaction that is displaced by the H. In other cases, H will displace anionic ligands, sometimes even halides. Treatment of chlorobis(dppe)iron hydride with sodium tetrafluorborate under and atmostphere of hydrogen is one example: Many metal hydrides can be protonated to give dihydrogen complexes: In such cases the acid usually is derived from a weakly coordinating anion, e.g., Brookhart's acid. In 1984, Kubas et al. discovered that the addition of H to the purple-colored species M(CO)(PR) gave a yellow precipitate of mer-trans-M(CO)(PR)(H) (M = Mo or W; R = cyclohexyl, iso-propyl). This result rapidly led to the discovery of a