Tin mining to trace metal content in the copper ore It was soon discovered that the addition of tin or arsenic to copper increased its hardness and made casting much easier, which revolutionized metal working techniques and brought humanity from the Copper Age or Chalcolithic to the Bronze Age around 3000 BC. Early tin exploitation appears to have been centered on placer deposits of cassiterite. The first evidence of tin use for making bronze appears in the Near East and the Balkans around 3000 BC. It is still unclear where the earliest tin was mined, as tin deposits are very rare and
Copper interconnect is to use Cu-Ge alloy as the interconnect material so that buffer layer (e.g. TiN) is no longer needed. Epitaxial CuGe layer has been fabricated with an average resistivity of 6 ± 1 μΩ cm and work function of ~4.47 ± 0.02 eV respectively, qualifying it as a good alternative to Cu. Resistance to electromigration, the process by which a metal conductor changes shape under the influence of an electric current flowing through it and which eventually leads to the breaking of the conductor, is significantly better with copper than with aluminium. This improvement in electromigration resistance allows higher currents