Lauryldimethylamine oxide intermolecular interactions), DDAO is a strongly hydrophilic surfactant: it forms normal micelles and normal liquid crystalline phases. High hydrophilicity of this surfactant can be explained by the fact that it forms very strong hydrogen bonds with water: the energy of DDAO – water hydrogen bond is about 50 kJ/mol. Lauryldimethylamine oxide Lauryldimethylamine oxide (LDAO), also known as dodecyldimethylamine oxide (DDAO), is an amine oxide based nonionic surfactant, with a C (dodecyl) alkyl tail. It is one of the most frequently-used surfactants of this type. Like other amine oxide based surfactants it is antimicrobial, being effective against common bacteria such as
Dihydrogen complex agostic interaction that is displaced by the H. In other cases, H will displace anionic ligands, sometimes even halides. Treatment of chlorobis(dppe)iron hydride with sodium tetrafluorborate under and atmostphere of hydrogen is one example: Many metal hydrides can be protonated to give dihydrogen complexes: In such cases the acid usually is derived from a weakly coordinating anion, e.g., Brookhart's acid. In 1984, Kubas et al. discovered that the addition of H to the purple-colored species M(CO)(PR) gave a yellow precipitate of mer-trans-M(CO)(PR)(H) (M = Mo or W; R = cyclohexyl, iso-propyl). This result rapidly led to the discovery of a