Mining in Cornwall and Devon tin was found as alluvial deposits of cassiterite in the gravels of stream beds. Eventually tin was mined underground; underground mines sprang up as early as the 16th century. Tin lodes were also found in outcroppings of cliffs. Tin is one of the earliest metals to have been exploited in Britain. Chalcolithic metal workers discovered that by putting a small proportion of tin (5 – 20%) in molten copper, the alloy bronze was produced. The alloy is harder than copper. The oldest production of tin-bronze is in Turkey about 3500 BC, but exploitation of the tin resources in Britain is
Printed circuit board coated with solder by hot air solder levelling (HASL). The HASL finish prevents oxidation from the underlying copper, thereby guaranteeing a solderable surface. This solder was a tin-lead alloy, however new solder compounds are now used to achieve compliance with the RoHS directive in the EU, which restricts the use of lead. One of these lead-free compounds is SN100CL, made up of 99.3% tin, 0.7% copper, 0.05% nickel, and a nominal of 60 ppm germanium. It is important to use solder compatible with both the PCB and the parts used. An example is ball grid array (BGA) using tin-lead solder