Tin mining to trace metal content in the copper ore It was soon discovered that the addition of tin or arsenic to copper increased its hardness and made casting much easier, which revolutionized metal working techniques and brought humanity from the Copper Age or Chalcolithic to the Bronze Age around 3000 BC. Early tin exploitation appears to have been centered on placer deposits of cassiterite. The first evidence of tin use for making bronze appears in the Near East and the Balkans around 3000 BC. It is still unclear where the earliest tin was mined, as tin deposits are very rare and
Copper in heat exchangers introduced in 1890 for seawater service. By the 1920s, a 70% Cu-30% Ni alloy was developed for naval condensers. Soon afterwards, a 2% manganese and 2% iron copper alloy was introduced for better erosion resistance. A 90% Cu-10% Ni alloy first became available in the 1950s, initially for seawater piping. This alloy is now the most widely used copper-nickel alloy in marine heat exchangers. Today, steam, evaporator, and condenser coils are made from copper and copper alloys. These heat exchangers are used in air conditioning and refrigeration systems, industrial and central heating and cooling systems, radiators, hot water tanks, and