Tin sources and trade in ancient times Bantu culture of Zimbabwe are known to have actively mined, smelted and traded tin between the 11th and 15th centuries AD . Tin deposits exist in many parts of South America, with minor deposits in southern Peru, Colombia, Brazil, and northwestern Argentina, and major deposits of exploitable cassiterite in northern Bolivia. These deposits were exploited as early as 1000 AD in the manufacture of tin bronze by Andean cultures, including the later Inca Empire, which considered tin bronze the "imperial alloy". In North America, the only known exploitable source of tin during ancient times is located in the Zacatecas tin
Tin(II) chloride to maintain the equilibrium towards the left-hand side (using Le Chatelier's principle). Solutions of SnCl are also unstable towards oxidation by the air: This can be prevented by storing the solution over lumps of tin metal. There are many such cases where tin(II) chloride acts as a reducing agent, reducing silver and gold salts to the metal, and iron(III) salts to iron(II), for example: It also reduces copper(II) to copper(I). Solutions of tin(II) chloride can also serve simply as a source of Sn ions, which can form other tin(II) compounds via precipitation reactions. For example, reaction with sodium sulfide produces