Amine oxide Amine oxide An amine oxide, also known as amine-"N"-oxide and "N"-oxide, is a chemical compound that contains the functional group RN−O, an N−O coordinate covalent bond with three additional hydrogen and/or hydrocarbon side chains attached to N. Sometimes it is written as RN→O or, wrongly, as RN=O. In the strict sense, the term "amine oxide" applies only to oxides of tertiary amines. Sometimes it is also used for the analogous derivatives of primary and secondary amines. Examples of amine oxides include pyridine-"N"-oxide, a water-soluble crystalline solid with melting point 62–67 °C, and "N"-methylmorpholine "N"-oxide, which is an oxidant. Amine oxides
Dihydrogen complex some cases, hydrogen ligands are usefully characterized by X-ray crystallography, but often the presence of metals, which strongly scatter X-rays, complicates the analysis. The triangular MH subunit has six normal modes of vibration, one of which is mainly of ν character. In free H, this very strong bond absorbs at 4300 cm, whereas in dihydrogen complexes the frequency drops to around 2800 cm. Two preparation methods involve the direct reactions with H gas. The first entails the addition of H to an unsaturated metal center, as originally reported for W(CO)(P-i-Pr)(H). In such cases, the unsaturated complex in fact features an