Tin sources and trade in ancient times Bantu culture of Zimbabwe are known to have actively mined, smelted and traded tin between the 11th and 15th centuries AD . Tin deposits exist in many parts of South America, with minor deposits in southern Peru, Colombia, Brazil, and northwestern Argentina, and major deposits of exploitable cassiterite in northern Bolivia. These deposits were exploited as early as 1000 AD in the manufacture of tin bronze by Andean cultures, including the later Inca Empire, which considered tin bronze the "imperial alloy". In North America, the only known exploitable source of tin during ancient times is located in the Zacatecas tin
Copper toxicity the interaction of fruit acid with copper, permitting the use of the metal for its efficient thermal transfer properties. OSHA has set safety standards for grinding and sharpening copper and copper alloy tools, which are often used in nonsparking applications. These standards are recorded in the Code of Federal Regulations 29 CFR 1910.134 and 1910.1000. Note: The most important nonsparking copper alloy is beryllium copper, and can lead to beryllium poisoning. With an of 30 mg/kg in rats, "gram quantities" of copper sulfate are potentially lethal in humans. The suggested safe level of copper in drinking water for humans varies