Classes of metals products with soft bases, which are bases with covalent bonds. The IUPAC Gold Book provides a more general definition of a class (a) metal ion, as "A metal ion that combines preferentially with ligands containing ligating atoms that are the lightest of their Periodic Group", and a class (b) metal as one that combines preferentially with ligands containing ligating atoms other than the lightest of their Periodic Group. Classes of metals Class A metals are metals that form hard acids. Hard acids are acids with relatively ionic bonds. These metals, such as iron, aluminium, titanium, sodium, calcium and the lanthanides,
Group 7 element high melting and boiling points. Group 7 contains the two naturally occurring transition metals discovered last: technetium and rhenium. Manganese was discovered much earlier owing to its much larger abundance in nature. Rhenium was discovered when Masataka Ogawa found what he thought was element 43 in thorianite, but this was dismissed; recent studies by H. K. Yoshihara suggest that he discovered rhenium instead, a fact not realized at the time. Walter Noddack, Otto Berg, and Ida Tacke were the first to conclusively identify rhenium; it was thought they discovered element 43 as well, but as the experiment could not be