Tin of protons. It has two main allotropes: at room temperature, the stable allotrope is β-tin, a silvery-white, malleable metal, but at low temperatures it transforms into the less dense grey α-tin, which has the diamond cubic structure. Metallic tin does not easily oxidize in air. The first tin alloy used on a large scale was bronze, made of tin and copper, from as early as 3000 BC. After 600 BC, pure metallic tin was produced. Pewter, which is an alloy of 85–90% tin with the remainder commonly consisting of copper, antimony, and lead, was used for flatware from the Bronze
Chinese sun and moon mirrors most (1 part tin per 1 part copper) for "metallic mirrors", namely, the "jiànsuì" 鑒燧 "mirror-igniter" alloy (Hirth 1907: 217-218). However, these ratios are based on Chinese numerology instead of practical metallurgy. Beyond about 32% the alloy becomes excessively brittle, and increasing tin content brings no further advantages of any kind; this the Han metallurgists evidently knew. Indeed they knew much more, for they almost always added up to 9% of lead, a constituent which greatly improved the casting properties. Han specular metal is truly white, reflects without tinning or silvering, resists scratching and corrosion well, and was admirably adapted