Temperature of work done on the work reservoir, and the first law of thermodynamics. The amounts of energy transferred as heat respectively from reservoir 1 and from reservoir 2 may then be denoted respectively and . Then the absolute or thermodynamic temperatures, and , of the reservoirs are defined so that to be such that Kelvin's original work postulating absolute temperature was published in 1848. It was based on the work of Carnot, before the formulation of the first law of thermodynamics. Kelvin wrote in his 1848 paper that his scale was absolute in the sense that it was defined "independently
Absolute zero where "S" is the entropy. In such a circumstance, pure substances can (ideally) form perfect crystals as "T" → 0. Max Planck's strong form of the third law of thermodynamics states the entropy of a perfect crystal vanishes at absolute zero. The original Nernst "heat theorem" makes the weaker and less controversial claim that the entropy change for any isothermal process approaches zero as "T" → 0: The implication is that the entropy of a perfect crystal simply approaches a constant value. The Nernst postulate identifies the isotherm T = 0 as coincident with the adiabat S = 0, although