Tin allowed for the much more complex shapes cast in closed moulds of the Bronze Age. Arsenical bronze objects appear first in the Near East where arsenic is commonly found in association with copper ore, but the health risks were quickly realized and the quest for sources of the much less hazardous tin ores began early in the Bronze Age. This created the demand for rare tin metal and formed a trade network that linked the distant sources of tin to the markets of Bronze Age cultures. Cassiterite (SnO), the tin oxide form of tin, was most likely the original source
Sundown Tin and Copper Mine to calcine the tin concentrates and drive of arsenic and sulphur. In 1917 a Merton calciner was erected and flues for arsenic recovery constructed. It is likely that these replaced the old reverberatory furnace and calciner. Arsenic became and important product of the mines, the demand escalating during the prickly pear infestation. New shafts were sunk at both the tin and copper mines. The lack of water reduced output in 1918, only 23 tons of tin and 12.5 tons of copper concentrates being produced, but the new shafts were continued, the three compartment copper shaft having poppet legs and ore