Cerium(IV) oxide used as a mixed conductor. Ceria is of interest as a material for solid oxide fuel cells (SOFCs) because of its relatively high oxygen ion conductivity (i.e. oxygen atoms readily move through it) at intermediate temperatures (500–650 °C) and lower association enthalpy compared to Zirconia system. The cerium(IV) oxide–cerium(III) oxide cycle or CeO/CeO cycle is a two step thermochemical water splitting process based on cerium(IV) oxide and cerium(III) oxide for hydrogen production. Cerium(IV) oxide Cerium(IV) oxide, also known as ceric oxide, ceric dioxide, ceria, cerium oxide or cerium dioxide, is an oxide of the rare-earth metal cerium. It is a
Dihydrogen bond Dihydrogen bond In chemistry, a dihydrogen bond is a kind of hydrogen bond, an interaction between a metal hydride bond and an OH or NH group or other proton donor. With a van der Waals radius of 1.2 Å, hydrogen atoms do not usually approach other hydrogen atoms closer than 2.4 Å. Close approaches near 1.8 Å, are, however, characteristic of dihydrogen bonding. An early example of this phenomenon is credited to Brown and Heseltine. They observed intense absorptions in the IR bands at 3300 and 3210 cm for a solution of (CH)NHBH. The higher energy band is assigned to