Temperature of work done on the work reservoir, and the first law of thermodynamics. The amounts of energy transferred as heat respectively from reservoir 1 and from reservoir 2 may then be denoted respectively and . Then the absolute or thermodynamic temperatures, and , of the reservoirs are defined so that to be such that Kelvin's original work postulating absolute temperature was published in 1848. It was based on the work of Carnot, before the formulation of the first law of thermodynamics. Kelvin wrote in his 1848 paper that his scale was absolute in the sense that it was defined "independently
Absolute zero their zero points at absolute zero by definition. It is commonly thought of as the lowest temperature possible, but it is not the lowest "enthalpy" state possible, because all real substances begin to depart from the ideal gas when cooled as they approach the change of state to liquid, and then to solid; and the sum of the enthalpy of vaporization (gas to liquid) and enthalpy of fusion (liquid to solid) exceeds the ideal gas's change in enthalpy to absolute zero. In the quantum-mechanical description, matter (solid) at absolute zero is in its ground state, the point of lowest internal