Alloy are relatively similar in size, the atom exchange method usually happens, where some of the atoms composing the metallic crystals are substituted with atoms of the other constituent. This is called a "substitutional alloy". Examples of substitutional alloys include bronze and brass, in which some of the copper atoms are substituted with either tin or zinc atoms respectively. In the case of the interstitial mechanism, one atom is usually much smaller than the other and can not successfully substitute for the other type of atom in the crystals of the base metal. Instead, the smaller atoms become trapped in the
Sundown Tin and Copper Mine to calcine the tin concentrates and drive of arsenic and sulphur. In 1917 a Merton calciner was erected and flues for arsenic recovery constructed. It is likely that these replaced the old reverberatory furnace and calciner. Arsenic became and important product of the mines, the demand escalating during the prickly pear infestation. New shafts were sunk at both the tin and copper mines. The lack of water reduced output in 1918, only 23 tons of tin and 12.5 tons of copper concentrates being produced, but the new shafts were continued, the three compartment copper shaft having poppet legs and ore