Tin sources and trade in ancient times shapes cast in closed molds of the Bronze Age. Arsenical bronze objects appear first in the Middle East where arsenic is commonly found in association with copper ore, but the health risks were quickly realized and the quest for sources of the much less hazardous tin ores began early in the Bronze Age . This created the demand for rare tin metal and formed a trade network that linked the distant sources of tin to the markets of Bronze Age cultures. Cassiterite (SnO), oxidized tin, most likely was the original source of tin in ancient times. Other forms of tin
Sundown Tin and Copper Mine and were mined from different shafts. With rising prices the mine was operating again in 1897, and much development work was carried out in 1898. By 1899 a smelter must have been erected, as 470 tons of ore was smelted for 53 tons of matte containing 30% copper and 50oz silver per ton, and 20 men were employed. More ore was raised in 1900, but the mine was under exemption through 1901-1903, a time of low copper prices. In 1904 the mine was described as having an open-cut on the tin portion, and on the copper section a tramway ran