Are You an Egghead? head-to-heads to James' 2. However Dr. Bayley, surprisingly, slipped up on 2 consecutive questions in the final round and James answered his 4 correctly to win 4–2. Match Three: Alan Morgan v. David Edwards: Alan Morgan defeated David Edwards in a contest that was neck and neck all the way. Alan won 3 head-to-heads to David's 2 and with the final round level at 3–3 David slipped up on his final 2 questions to hand the advantage to Alan who won 4–3. Match Four: Shanker Menon v. Barry Simmons: In another close contest, Barry Simmons defeated Shanker Menon. Barry won
Are You an Egghead? round. Match Thirteen: Shaun Wallace v. Rob Swarbrick: Shaun Wallace, the 2004 winner of "Mastermind", came through a close contest with "Duel" winner Rob Swarbrick to win 7–6 in the final round. Despite Rob winning 3 head-to-heads to Shaun's 2, Rob required all his eggheads in the final round to get the score to 6–6 before eventually slipping up on a question. Match Fourteen: Danielle Cartwright v. Olav Bjortomt: Olav Bjortomt, a regular on the quiz circuit and former World Quiz Champion, defeated Danielle Cartwright in a close contest. Danielle, who is one of the few contestants in the series