Carbon–fluorine bond the molecule represented by CHX has a BDE of 115 kcal/mol for carbon–fluorine while values of 104.9, 83.7, 72.1, and 57.6 kcal/mol represent carbon–X bonds to hydrogen, chlorine, bromine, and iodine, respectively. The carbon–fluorine bond length is typically about 1.35 ångström (1.39 Å in fluoromethane). It is shorter than any other carbon–halogen bond, and shorter than single carbon–nitrogen and carbon–oxygen bonds, despite fluorine having a larger atomic mass. The short length of the bond can also be attributed to the ionic character/electrostatic attractions between the partial charges on carbon and fluorine. The carbon–fluorine bond length varies by several hundredths of
Graphite intercalation compound A stage n magnetic GIC has n graphite layers separating successive magnetic layers. As the stage number increases the interaction between spins in successive magnetic layers becomes weaker and 2D magnetic behaviour may arise. Chlorine and bromine reversibly intercalate into graphite. Iodine does not. Fluorine reacts irreversibly. In the case of bromine, the following stoichiometries are known: CBr for n = 8, 12, 14, 16, 20, and 28. Because it forms irreversibly, carbon monofluoride is often not classified as an intercalation compound. It has the formula (CF). It is prepared by reaction of gaseous fluorine with graphitic carbon at 215–230