Gay-Lussac's law gases and the gaseous products can be expressed in simple whole numbers. For example, Gay-Lussac found that 2 volumes of hydrogen and 1 volume of oxygen would react to form 2 volumes of gaseous water. Based on Gay-Lussac's results, Amedeo Avogadro theorized that, at the same temperature and pressure, equal volumes of gas contain equal numbers of molecules (Avogadro's law). This hypothesis meant that the previously stated result could also be expressed as The law of combining gases was made public by Joseph Louis Gay-Lussac in 1808. Avogadro's hypothesis, however, was not initially accepted by chemists until the Italian chemist
Inversion temperature Inversion temperature The inversion temperature in thermodynamics and cryogenics is the critical temperature below which a non-ideal gas (all gases in reality) that is expanding at constant enthalpy will experience a temperature decrease, and above which will experience a temperature increase. This temperature change is known as the Joule-Thomson effect, and is exploited in the liquefaction of gases. Inversion temperature depends on the nature of the gas. For a van der Waals gas we can calculate the enthalpy formula_1 using statistical mechanics as where formula_3 is the number of molecules, formula_4 is volume, formula_5 is temperature (in the Kelvin scale),