Tropospheric ozone Tropospheric ozone Ozone (O) is a trace gas of the troposphere, with an average concentration of 20-30 parts per billion by volume (ppbv), with close to 100 ppbv in polluted areas. . Ozone is also an important constituent of the stratosphere, where the ozone layer exists. The troposphere is the lowest layer of the Earth's atmosphere. It extends from the ground up to a variable height of approximately 14 kilometers above sea level. Ozone is least concentrated in the ground layer (or planetary boundary layer) of the troposphere. It's concentration increases as height above sea level increases, with a maximum
Ozone often considered the higher elevations beneficial because of their ozone content. "There is quite a different atmosphere [at higher elevation] with enough ozone to sustain the necessary energy [to work]", wrote naturalist Henry Henshaw, working in Hawaii. Seaside air was considered to be healthy because of its believed ozone content; but the smell giving rise to this belief is in fact that of halogenated seaweed metabolites. Much of ozone's appeal seems to have resulted from its "fresh" smell, which evoked associations with purifying properties. Scientists, however, noted its harmful effects. In 1873 James Dewar and John Gray McKendrick documented that