Atmosphere of Earth the border between the atmosphere and outer space. Atmospheric effects become noticeable during atmospheric reentry of spacecraft at an altitude of around . Several layers can be distinguished in the atmosphere, based on characteristics such as temperature and composition. The study of Earth's atmosphere and its processes is called atmospheric science (aerology). Early pioneers in the field include Léon Teisserenc de Bort and Richard Assmann. The three major constituents of Earth's atmosphere are nitrogen, oxygen, and argon. Water vapor accounts for roughly 0.25% of the atmosphere by mass. The concentration of water vapor (a greenhouse gas) varies significantly from around
Atmosphere of Earth record of Earth's dynamic oxygenation evolution. These fluctuations in oxygenation were likely driven by the Lomagundi carbon isotope excursion. The constant re-arrangement of continents by plate tectonics influences the long-term evolution of the atmosphere by transferring carbon dioxide to and from large continental carbonate stores. Free oxygen did not exist in the atmosphere until about 2.4 billion years ago during the Great Oxygenation Event and its appearance is indicated by the end of the banded iron formations. Before this time, any oxygen produced by photosynthesis was consumed by oxidation of reduced materials, notably iron. Molecules of free oxygen did not