Compounds of fluorine heavier halogens (chlorine, bromine, and iodine) all form mono-, tri-, and pentafluorides: XF, XF, and XF. Of the neutral +7 species, only iodine heptafluoride is known. While chlorine and bromine heptafluorides are not known, the corresponding cations and , extremely strong oxidizers, are. Astatine is not well-studied, and although there is a report of a non-volatile astatine monofluoride, its existence is debated. Many of the halogen fluorides are powerful fluorinators. Chlorine trifluoride is particularly noteworthy—readily fluorinating asbestos and refractory oxides—and may be even more reactive than chlorine pentafluoride. Used industrially, ClF requires special precautions similar to those for fluorine gas
Chemistry: A Volatile History all the elements in their order: Notice carbon and silicon are in Group IV and the volatile gases fluorine, chlorine and bromine are in Group VII. Mendeleev was sufficiently confident in the layout of his table that he was willing to leave gaps for unknown elements to make the pattern fit – believing other elements would later be discovered that filled the gaps. So, for Mendeleev to be vindicated, the gaps needed to be filled, and luckily, in 1859, new instrumentation had been developed for discovering elements. Robert Bunsen knew that when certain elements burned in the flames of his