Fractionation of carbon isotopes in oxygenic photosynthesis values more similar to C3 plants. In contrast to terrestrial plants, where CO diffusion in air is relatively fast and typically not limiting, diffusion of dissolved CO in water is considerably slower and can often limit carbon fixation in phytoplankton. As gaseous CO is dissolved into aqueous CO, it is fractionated by both kinetic and equilibrium effects that are temperature-dependent. Relative to plants, the dissolved CO source for phytoplankton can be enriched in C by about 8‰ from atmospheric CO. Isotope fractionation of C by phytoplankton photosynthesis is affected by the diffusion of extracellular aqueous CO into the cell, the
Ghetto Day/What I Need "What I Need" and "100% Pure Love", the album's first single, "ooze with giddy abandon—not to mention juicy grooves that seep deeper into the brain and body upon repeated spins." "What I Need" was claimed by "Spin" Bernstein to have "xeroxed" Clivillés and Cole's 1991 single "A Deeper Love". However, he predicted that it could have been a potential successor to her previous signature hits, "Gypsy Woman" and "Makin' Happy". "Ghetto Day" and "What I Need" were released as a double A-side single in June 1994. The joint release peaked at 40 on the UK Singles Chart and at No.