Atomic orbital , the letters associated with those numbers are K, L, M, N, O, ... respectively. The simplest atomic orbitals are those that are calculated for systems with a single electron, such as the hydrogen atom. An atom of any other element ionized down to a single electron is very similar to hydrogen, and the orbitals take the same form. In the Schrödinger equation for this system of one negative and one positive particle, the atomic orbitals are the eigenstates of the Hamiltonian operator for the energy. They can be obtained analytically, meaning that the resulting orbitals are products of a
Particle in a box which is proportional to formula_44. The variance in the position is a measure of the uncertainty in position of the particle: The probability density for finding a particle with a given momentum is derived from the wavefunction as formula_46. As with position, the probability density for finding the particle at a given momentum depends upon its state, and is given by where, again, formula_33. The expectation value for the momentum is then calculated to be zero, and the variance in the momentum is calculated to be: The uncertainties in position and momentum (formula_50 and formula_51) are defined as being equal