Ozone depletion an ozone layer in the Earth's stratosphere were discovered by Sydney Chapman in 1930. Short-wavelength UV radiation splits an oxygen () molecule into two oxygen (O) atoms, which then combine with other oxygen molecules to form ozone. Ozone is removed when an oxygen atom and an ozone molecule "recombine" to form two oxygen molecules, i.e. O + → 2. In the 1950s, David Bates and Marcel Nicolet presented evidence that various free radicals, in particular hydroxyl (OH) and nitric oxide (NO), could catalyze this recombination reaction, reducing the overall amount of ozone. These free radicals were known to be present
Planetary boundary layer Planetary boundary layer In meteorology the planetary boundary layer (PBL), also known as the atmospheric boundary layer (ABL) or "peplosphere", is the lowest part of the atmosphere and its behavior is directly influenced by its contact with a planetary surface . On Earth it usually responds to changes in surface radiative forcing in an hour or less. In this layer physical quantities such as flow velocity, temperature, moisture, etc., display rapid fluctuations (turbulence) and vertical mixing is strong. Above the PBL is the "free atmosphere" where the wind is approximately geostrophic (parallel to the isobars) , while within the PBL