Fluorine in annual revenue. Due to the danger from direct hydrocarbon–fluorine reactions above −150 °C (−240 °F), industrial fluorocarbon production is indirect, mostly through halogen exchange reactions such as Swarts fluorination, in which chlorocarbon chlorines are substituted for fluorines by hydrogen fluoride under catalysts. Electrochemical fluorination subjects hydrocarbons to electrolysis in hydrogen fluoride, and the Fowler process treats them with solid fluorine carriers like cobalt trifluoride. Halogenated refrigerants, termed Freons in informal contexts, are identified by R-numbers that denote the amount of fluorine, chlorine, carbon, and hydrogen present. Chlorofluorocarbons (CFCs) like R-11, R-12, and R-114 once dominated organofluorines, peaking in production
Origin and use of the term metalloid their ability to form oxyanions. A common oxyanion of sulfur, for example, is the sulfate ion SO. Many metals can do the same. Chromium, for instance, can form the chromate ion CrO. Berzelius' terminology was widely adopted although it was subsequently regarded by some commentators as counterintuitive, misapplied, incorrect or invalid. In 1825, in a revised German edition of his "Textbook of Chemistry," Berzelius subdivided the metalloids into three classes. These were: constantly gaseous 'gazolyta' (hydrogen, nitrogen, oxygen); real metalloids (sulfur, phosphorus, carbon, boron, silicon); and salt-forming 'halogenia' (fluorine, chlorine, bromine, iodine). In 1844, Jackson gave the meaning of 'metalloid'