Kramers–Heisenberg formula Kramers–Heisenberg formula The Kramers–Heisenberg dispersion formula is an expression for the cross section for scattering of a photon by an atomic electron. It was derived before the advent of quantum mechanics by Hendrik Kramers and Werner Heisenberg in 1925, based on the correspondence principle applied to the classical dispersion formula for light. The quantum mechanical derivation was given by Paul Dirac in 1927. The Kramers–Heisenberg formula was an important achievement when it was published, explaining the notion of "negative absorption" (stimulated emission), the Thomas–Reiche–Kuhn sum rule, and inelastic scattering — where the energy of the scattered photon may be larger
Heisenberg picture some sense, the Heisenberg picture is more natural and convenient than the equivalent Schrödinger picture, especially for relativistic theories. Lorentz invariance is manifest in the Heisenberg picture, since the state vectors do not single out the time or space. This approach also has a more direct similarity to classical physics: by simply replacing the commutator above by the Poisson bracket, the Heisenberg equation reduces to an equation in Hamiltonian mechanics. For the sake of pedagogy, the Heisenberg picture is introduced here from the subsequent, but more familiar, Schrödinger picture. The expectation value of an observable "A", which is a Hermitian