Liquid helium of liquid water. Helium was first liquefied on July 10, 1908, by the Dutch physicist Heike Kamerlingh Onnes at the University of Leiden in the Netherlands. At that time, helium-3 was unknown because the mass spectrometer had not yet been invented. In more recent decades, liquid helium has been used as a cryogenic refrigerant, and liquid helium is produced commercially for use in superconducting magnets such as those used in magnetic resonance imaging (MRI), nuclear magnetic resonance (NMR), Magnetoencephalography (MEG), and experiments in physics, such as low temperature Mössbauer spectroscopy. The temperature required to produce liquid helium is low because
Enthalpy older term "heat content", a term which is now mostly deprecated as misleading, as refers to the amount of heat absorbed in a process at constant pressure only, but not in the general case (when pressure is variable). Josiah Willard Gibbs used the term "a heat function for constant pressure" for clarity. Introduction of the concept of "heat content" is associated with Benoît Paul Émile Clapeyron and Rudolf Clausius (Clausius–Clapeyron relation, 1850). The term "enthalpy" first appeared in print in 1909. It is attributed to Heike Kamerlingh Onnes, who most likely introduced it orally the year before, at the first