Isotopes of chlorine Isotopes of chlorine Chlorine (Cl) has 25 isotopes with mass numbers ranging from Cl to Cl and 2 isomers (Cl and Cl). There are two principal stable isotopes, Cl (75.78%) and Cl (24.22%), giving chlorine a standard atomic weight of 35.45. The longest-lived radioactive isotope is Cl, which has a half-life of 301,000 years. All other isotopes have half-lives under 1 hour, many less than one second. The shortest-lived are Cl and Cl, with half-lives less than 20 and 30 nanoseconds, respectively—the half-life of Cl is unknown. Bromine is the only other halogen with more than one stable isotope. Trace
Chlorine made on a large scale by direct fluorination of chlorine with excess fluorine gas at 350 °C and 250 atm, and on a small scale by reacting metal chlorides with fluorine gas at 100–300 °C. It melts at −103 °C and boils at −13.1 °C. It is a very strong fluorinating agent, although it is still not as effective as chlorine trifluoride. Only a few specific stoichiometric reactions have been characterised. Arsenic pentafluoride and antimony pentafluoride form ionic adducts of the form [ClF][MF] (M = As, Sb) and water reacts vigorously as follows: The product, chloryl fluoride, is one of