Dimer (chemistry) dimerise to give the dimer "A-A". An example is a diaminocarbene, which dimerise to give a tetraaminoethylene: Carbenes are highly reactive and readily form bonds. Dicyclopentadiene is an asymmetrical dimer of two cyclopentadiene molecules that have reacted in a Diels-Alder reaction to give the product. Upon heating, it "cracks" (undergoes a retro-Diels-Alder reaction) to give identical monomers: Many nonmetallic elements occur as dimers: hydrogen, nitrogen, oxygen, the halogens, i.e. fluorine, chlorine, bromine and iodine. Noble gases can form dimers linked by van der Waals bonds, for example dihelium or diargon. Mercury occurs as a mercury(I) cation (Hg), formally a dimeric
Fluorine other elements from carbon to magnesium are twenty or more times as common. This is because stellar nucleosynthesis processes bypass fluorine, and any fluorine atoms otherwise created have high nuclear cross sections, allowing further fusion with hydrogen or helium to generate oxygen or neon respectively. Beyond this transient existence, three explanations have been proposed for the presence of fluorine: Fluorine is the thirteenth most common element in Earth's crust at 600–700 ppm (parts per million) by mass. Elemental fluorine in Earth's atmosphere would easily react with atmospheric water vapor, precluding its natural occurrence; it is found only in combined mineral