Compounds of fluorine heavier halogens (chlorine, bromine, and iodine) all form mono-, tri-, and pentafluorides: XF, XF, and XF. Of the neutral +7 species, only iodine heptafluoride is known. While chlorine and bromine heptafluorides are not known, the corresponding cations and , extremely strong oxidizers, are. Astatine is not well-studied, and although there is a report of a non-volatile astatine monofluoride, its existence is debated. Many of the halogen fluorides are powerful fluorinators. Chlorine trifluoride is particularly noteworthy—readily fluorinating asbestos and refractory oxides—and may be even more reactive than chlorine pentafluoride. Used industrially, ClF requires special precautions similar to those for fluorine gas
Chlorine pentafluoride with water to produce chloryl fluoride and hydrogen fluoride: It is also a strong fluorinating agent. At room temperature it reacts readily with all elements (including otherwise "inert" elements like platinum and gold) except noble gases, nitrogen, oxygen and fluorine. Chlorine pentafluoride Chlorine pentafluoride is an interhalogen compound with formula ClF. This colourless gas is a strong oxidant that was once a candidate oxidizer for rockets. The molecule adopts a square pyramidal structure with C symmetry, as confirmed by its high-resolution F NMR spectrum. Some of the earliest research on the preparation was classified. It was first prepared by fluorination