Tropospheric ozone concentration at the tropopause. About 90% of total ozone in the atmosphere is in the stratosphere, and 10% is in the troposphere. Although tropospheric ozone is less concentrated than stratospheric ozone, it is of concern because of its health effects. Ozone in the troposphere is considered a greenhouse gas, and may contribute to global warming. Photo-chemical and chemical reactions involving ozone drive many of the chemical processes that occur in the troposphere by day and by night. At abnormally high concentrations (the largest source being emissions from combustion of fossil fuels), it is a pollutant, and a constituent of smog.
Ozone layer geographically. The ozone layer was discovered in 1913 by the French physicists Charles Fabry and Henri Buisson. Measurements of the sun showed that the radiation sent out from its surface and reaching the ground on Earth is usually consistent with the spectrum of a black body with a temperature in the range of 5,500–6,000 K (5,227 to 5,727 °C), except that there was no radiation below a wavelength of about 310 nm at the ultraviolet end of the spectrum. It was deduced that the missing radiation was being absorbed by something in the atmosphere. Eventually the spectrum of the missing