Bromine water, because of the easy oxidation of bromide to the equivalent of Br, a potent electrophile. The enzyme bromoperoxidase catalyzes this reaction. The oceans are estimated to release 1–2 million tons of bromoform and 56,000 tons of bromomethane annually. An old qualitative test for the presence of the alkene functional group is that alkenes turn brown aqueous bromine solutions colourless, forming a bromohydrin with some of the dibromoalkane also produced. The reaction passes through a short-lived strongly electrophilic bromonium intermediate. This is an example of a halogen addition reaction. Bromine is significantly less abundant in the crust than fluorine or
Origin and occurrence of fluorine fluorine in antozonite. It was suggested that radiation from small amounts of uranium within the crystals had caused the free fluorine defects. Origin and occurrence of fluorine Fluorine is relatively rare in the universe compared to other elements of nearby atomic weight. On earth, fluorine is essentially found only in mineral compounds because of its reactivity. The main commercial source, fluorite, is a common mineral. At 400 ppb, fluorine is estimated to be the 24th most common element in the universe. It is comparably rare for a light element (elements tend to be more common the lighter they are). All