Fractionation of carbon isotopes in oxygenic photosynthesis the bundle sheath cells. Different forms of CCM in phytoplankton include the active uptake of bicarbonate and CO through the cell membrane, the active transport of inorganic carbon from the cellular membrane to the chloroplasts, and active, unidirectional conversion of CO to bicarbonate. The parameters affecting C fractionation in phytoplankton contribute to "δ"C values between -18 to -25‰. Fractionation of carbon isotopes in oxygenic photosynthesis Photosynthesis converts carbon dioxide to carbohydrates via several metabolic pathways that provide energy to an organism and preferentially react with certain stable isotopes of carbon. The selective enrichment of one stable isotope over another creates
Fractionation of carbon isotopes in oxygenic photosynthesis values more similar to C3 plants. In contrast to terrestrial plants, where CO diffusion in air is relatively fast and typically not limiting, diffusion of dissolved CO in water is considerably slower and can often limit carbon fixation in phytoplankton. As gaseous CO is dissolved into aqueous CO, it is fractionated by both kinetic and equilibrium effects that are temperature-dependent. Relative to plants, the dissolved CO source for phytoplankton can be enriched in C by about 8‰ from atmospheric CO. Isotope fractionation of C by phytoplankton photosynthesis is affected by the diffusion of extracellular aqueous CO into the cell, the