Kramers–Heisenberg formula Kramers–Heisenberg formula The Kramers–Heisenberg dispersion formula is an expression for the cross section for scattering of a photon by an atomic electron. It was derived before the advent of quantum mechanics by Hendrik Kramers and Werner Heisenberg in 1925, based on the correspondence principle applied to the classical dispersion formula for light. The quantum mechanical derivation was given by Paul Dirac in 1927. The Kramers–Heisenberg formula was an important achievement when it was published, explaining the notion of "negative absorption" (stimulated emission), the Thomas–Reiche–Kuhn sum rule, and inelastic scattering — where the energy of the scattered photon may be larger
Werner Heisenberg main new idea, non-commuting matrices, is justified only by a rejection of unobservable quantities. It introduces the non-commutative multiplication of matrices by physical reasoning, based on the correspondence principle, despite the fact that Heisenberg was not then familiar with the mathematical theory of matrices. The path leading to these results has been reconstructed in MacKinnon, 1977, and the detailed calculations are worked out in Aitchison et al. In Copenhagen, Heisenberg and Hans Kramers collaborated on a paper on dispersion, or the scattering from atoms of radiation whose wavelength is larger than the atoms. They showed that the successful formula Kramers