Bromine dioxide treatment of bromine gas with ozone in trichlorofluoromethane at −50 °C. When mixed with a base, bromine dioxide gives the bromide and bromate anions: Bromine dioxide Bromine dioxide is the chemical compound composed of bromine and oxygen with the formula BrO. It forms unstable yellow to yellow-orange crystals. It was first isolated by R. Schwarz and M. Schmeißer in 1937 and is hypothesized to be important in the atmospheric reaction of bromine with ozone. It is similar to chlorine dioxide, the dioxide of its halogen neighbor one period higher on the periodic table. Bromine dioxide is formed when an electric
Bromine trifluoride fluoroanions: Bromine trifluoride Bromine trifluoride is an interhalogen compound with the formula BrF. It is a straw-coloured liquid with a pungent odor. It is soluble in sulfuric acid but reacts violently with water and organic compounds. It is a powerful fluorinating agent and an ionizing inorganic solvent. It is used to produce uranium hexafluoride (UF) in the processing and reprocessing of nuclear fuel. Bromine trifluoride was first described by Paul Lebeau in 1906, who obtained the material by the reaction of bromine with fluorine at 20 °C: The disproportionation of bromine monofluoride also gives bromine trifluoride: Like ClF and IF,