Asphyxiant gas can smell the odorants, and assigning a different smell to each gas may be impractical. Another difficulty is that most odorants (e.g., the thiols) are chemically reactive. This is not a problem with natural gas intended to be burned as fuel, which is routinely odorized, but a major use of asphyxiants such as nitrogen, helium, argon and krypton is to protect reactive materials from the atmosphere. The dangers of excess concentrations of nontoxic gases has been recognized for centuries within the mining industry. The concept of black damp (or "stythe") reflects an understanding that certain gaseous mixtures could lead to
Natural gas in the United States sealed with rope and molten lead. In the 1800s and early 1900s, most natural gas discoveries were made while exploring for oil. Natural gas was usually an unwanted byproduct of oil production. In the 1870s steel pipe replaced cast iron. In 1883, Pittsburgh became the first major city supplied with natural gas. Other cities followed, but only if they were close to natural gas wells. Because natural gas was a byproduct, it was priced cheaply, and, where available, undercut the market for town gas. In 1891, one of the longest pipelines of the time was built, a 120-mile long pipeline