Tropospheric ozone concentration at the tropopause. About 90% of total ozone in the atmosphere is in the stratosphere, and 10% is in the troposphere. Although tropospheric ozone is less concentrated than stratospheric ozone, it is of concern because of its health effects. Ozone in the troposphere is considered a greenhouse gas, and may contribute to global warming. Photo-chemical and chemical reactions involving ozone drive many of the chemical processes that occur in the troposphere by day and by night. At abnormally high concentrations (the largest source being emissions from combustion of fossil fuels), it is a pollutant, and a constituent of smog.
Planetary boundary layer Planetary boundary layer In meteorology the planetary boundary layer (PBL), also known as the atmospheric boundary layer (ABL) or "peplosphere", is the lowest part of the atmosphere and its behavior is directly influenced by its contact with a planetary surface . On Earth it usually responds to changes in surface radiative forcing in an hour or less. In this layer physical quantities such as flow velocity, temperature, moisture, etc., display rapid fluctuations (turbulence) and vertical mixing is strong. Above the PBL is the "free atmosphere" where the wind is approximately geostrophic (parallel to the isobars) , while within the PBL