Fluorine in annual revenue. Due to the danger from direct hydrocarbon–fluorine reactions above −150 °C (−240 °F), industrial fluorocarbon production is indirect, mostly through halogen exchange reactions such as Swarts fluorination, in which chlorocarbon chlorines are substituted for fluorines by hydrogen fluoride under catalysts. Electrochemical fluorination subjects hydrocarbons to electrolysis in hydrogen fluoride, and the Fowler process treats them with solid fluorine carriers like cobalt trifluoride. Halogenated refrigerants, termed Freons in informal contexts, are identified by R-numbers that denote the amount of fluorine, chlorine, carbon, and hydrogen present. Chlorofluorocarbons (CFCs) like R-11, R-12, and R-114 once dominated organofluorines, peaking in production
Origin and occurrence of fluorine fluorine in antozonite. It was suggested that radiation from small amounts of uranium within the crystals had caused the free fluorine defects. Origin and occurrence of fluorine Fluorine is relatively rare in the universe compared to other elements of nearby atomic weight. On earth, fluorine is essentially found only in mineral compounds because of its reactivity. The main commercial source, fluorite, is a common mineral. At 400 ppb, fluorine is estimated to be the 24th most common element in the universe. It is comparably rare for a light element (elements tend to be more common the lighter they are). All