Atmosphere of Triton asymmetry was actually observed during star occultations by Triton in 1990s. Before Voyager 2 arrived, a nitrogen and methane atmosphere with a density as much as 30% that of Earth had been suggested. This proved to be a great overestimate, similar to the predictions of the atmospheric density of Mars, but like on Mars, a denser early atmosphere is postulated. Voyager 2 flew past Triton five hours after closest approach to Neptune in mid-late August 1989. During the flyby, Voyager 2 took measurements of the atmosphere, finding methane and nitrogen in the atmosphere. In the 1990s, observations from Earth were
Atmosphere of Earth record of Earth's dynamic oxygenation evolution. These fluctuations in oxygenation were likely driven by the Lomagundi carbon isotope excursion. The constant re-arrangement of continents by plate tectonics influences the long-term evolution of the atmosphere by transferring carbon dioxide to and from large continental carbonate stores. Free oxygen did not exist in the atmosphere until about 2.4 billion years ago during the Great Oxygenation Event and its appearance is indicated by the end of the banded iron formations. Before this time, any oxygen produced by photosynthesis was consumed by oxidation of reduced materials, notably iron. Molecules of free oxygen did not