Atomic orbital many modes of the vibrating disk form patterns that trace the various shapes of atomic orbitals. The basic reason for this correspondence lies in the fact that the distribution of kinetic energy and momentum in a matter-wave is predictive of where the particle associated with the wave will be. That is, the probability of finding an electron at a given place is also a function of the electron's average momentum at that point, since high electron momentum at a given position tends to "localize" the electron in that position, via the properties of electron wave-packets (see the Heisenberg uncertainty principle
Particle in a box not strictly hold for the measured momentum ; the energy eigenstate formula_38 is not a momentum eigenstate, and, in fact, not even a superposition of two momentum eigenstates, as one might be tempted to imagine from equation () above: peculiarly, it has no well-defined momentum before measurement! In classical physics, the particle can be detected anywhere in the box with equal probability. In quantum mechanics, however, the probability density for finding a particle at a given position is derived from the wavefunction as formula_39 For the particle in a box, the probability density for finding the particle at a given