Isotopes of chlorine Isotopes of chlorine Chlorine (Cl) has 25 isotopes with mass numbers ranging from Cl to Cl and 2 isomers (Cl and Cl). There are two principal stable isotopes, Cl (75.78%) and Cl (24.22%), giving chlorine a standard atomic weight of 35.45. The longest-lived radioactive isotope is Cl, which has a half-life of 301,000 years. All other isotopes have half-lives under 1 hour, many less than one second. The shortest-lived are Cl and Cl, with half-lives less than 20 and 30 nanoseconds, respectively—the half-life of Cl is unknown. Bromine is the only other halogen with more than one stable isotope. Trace
Bromine trifluoride BrF molecule is T-shaped and planar. In the VSEPR formalism, the bromine center is assigned two electron pairs. The distance from the bromine each axial fluorine is 1.81 Å and to the equatorial fluorine is 1.72 Å. The angle between an axial fluorine and the equatorial fluorine is slightly smaller than 90° — the 86.2° angle observed is due to the repulsion generated by the electron pairs being greater than that of the Br-F bonds. BrF is a fluorinating agent, but less reactive than ClF. The liquid is conducting, owing to autoionisation: Many ionic fluorides dissolve readily in BrF forming