Gay-Lussac's law gases and the gaseous products can be expressed in simple whole numbers. For example, Gay-Lussac found that 2 volumes of hydrogen and 1 volume of oxygen would react to form 2 volumes of gaseous water. Based on Gay-Lussac's results, Amedeo Avogadro theorized that, at the same temperature and pressure, equal volumes of gas contain equal numbers of molecules (Avogadro's law). This hypothesis meant that the previously stated result could also be expressed as The law of combining gases was made public by Joseph Louis Gay-Lussac in 1808. Avogadro's hypothesis, however, was not initially accepted by chemists until the Italian chemist
Entropy of mixing one of the respective gases, so that the respective volumes available to each gas remain constant during the merge. Either one of the common temperature or the common pressure is chosen to be independently controlled by the experimenter, the other being allowed to vary so as to maintain constant volume for each mass of gas. In this kind of "mixing", the final common volume is equal to each of the respective separate initial volumes, and each gas finally occupies the same volume as it did initially. This constant volume kind of "mixing", in the special case of perfect gases, is