Atmosphere of Earth and balloons, and too low to permit orbital spacecraft. The mesosphere is mainly accessed by sounding rockets and rocket-powered aircraft. The stratosphere is the second-lowest layer of Earth's atmosphere. It lies above the troposphere and is separated from it by the tropopause. This layer extends from the top of the troposphere at roughly above Earth's surface to the stratopause at an altitude of about . The atmospheric pressure at the top of the stratosphere is roughly 1/1000 the pressure at sea level. It contains the ozone layer, which is the part of Earth's atmosphere that contains relatively high concentrations of
Tropospheric ozone is the reaction of •OH with NO to form nitric acid at high NOx levels. If nitrogen monoxide (NO) is instead present at very low levels in the atmosphere (less than 10 approximately ppt), the of peroxy radicals (HO• ) formed from the oxidation will instead react with themselves to form peroxides, and not produce ozone. Health effects depend on ozone precursors, which is a group of pollutants, primarily generated during the combustion of fossil fuels. Reaction with daylight ultraviolet (UV) rays and these precursors create ground-level ozone pollution (Tropospheric Ozone). Ozone is known to have the following health effects