Fluorine in annual revenue. Due to the danger from direct hydrocarbon–fluorine reactions above −150 °C (−240 °F), industrial fluorocarbon production is indirect, mostly through halogen exchange reactions such as Swarts fluorination, in which chlorocarbon chlorines are substituted for fluorines by hydrogen fluoride under catalysts. Electrochemical fluorination subjects hydrocarbons to electrolysis in hydrogen fluoride, and the Fowler process treats them with solid fluorine carriers like cobalt trifluoride. Halogenated refrigerants, termed Freons in informal contexts, are identified by R-numbers that denote the amount of fluorine, chlorine, carbon, and hydrogen present. Chlorofluorocarbons (CFCs) like R-11, R-12, and R-114 once dominated organofluorines, peaking in production
Compounds of fluorine state is −1. It differs from this value in elemental fluorine, where the atoms are bonded to each other and thus at oxidation state 0, and a few polyatomic ions: the very unstable anions and with intermediate oxidation states exist at very low temperatures, decomposing at around 40 K. Also, the cation and a few related species have been predicted to be stable. Fluorine forms compounds with all elements except neon and helium. In particular, it forms binary compounds, named fluorides, with all said elements except argon. All of the elements up to einsteinium, element 99, have been checked except