Proton from different gases had different values of charge-to-mass ratio (e/m), they could not be identified with a single particle, unlike the negative electrons discovered by J. J. Thomson. Wilhelm Wien in 1898 identified the hydrogen ion as particle with highest charge-to-mass ratio in ionized gases. Following the discovery of the atomic nucleus by Ernest Rutherford in 1911, Antonius van den Broek proposed that the place of each element in the periodic table (its atomic number) is equal to its nuclear charge. This was confirmed experimentally by Henry Moseley in 1913 using X-ray spectra. In 1917 (in experiments reported in 1919),
Unique Particle Attribution which disambiguates it by saying that when an element matches both an element particle and a wildcard, the element particle wins. However, the UPA constraint itself remains in version 1.1. Unique Particle Attribution The Unique Particle Attribution (UPA) rule is a mechanism to prevent ambiguity in W3C XML Schema version 1.0. Due to the UPA rule the XML schema fragment given below is prohibited: Given the XML instance fragment: it is ambiguous whether <x> should be associated with the element declaration (xsd:element name="x"), or the wildcard (xsd:any). This ambiguity violates the UPA rule and the corresponding XML schema therefore needs