Isotopes of chlorine Isotopes of chlorine Chlorine (Cl) has 25 isotopes with mass numbers ranging from Cl to Cl and 2 isomers (Cl and Cl). There are two principal stable isotopes, Cl (75.78%) and Cl (24.22%), giving chlorine a standard atomic weight of 35.45. The longest-lived radioactive isotope is Cl, which has a half-life of 301,000 years. All other isotopes have half-lives under 1 hour, many less than one second. The shortest-lived are Cl and Cl, with half-lives less than 20 and 30 nanoseconds, respectively—the half-life of Cl is unknown. Bromine is the only other halogen with more than one stable isotope. Trace
Bromine disproportionating quickly and irreversibly into bromine, bromine trifluoride, and bromine pentafluoride. It thus cannot be obtained pure. It may be synthesised by the direct reaction of the elements, or by the comproportionation of bromine and bromine trifluoride at high temperatures. Bromine monochloride (BrCl), a red-brown gas, quite readily dissociates reversibly into bromine and chlorine at room temperature and thus also cannot be obtained pure, though it can be made by the reversible direct reaction of its elements in the gas phase or in carbon tetrachloride. Bromine monofluoride in ethanol readily leads to the monobromination of the aromatic compounds PhX ("para"-bromination