Atmosphere of Earth the border between the atmosphere and outer space. Atmospheric effects become noticeable during atmospheric reentry of spacecraft at an altitude of around . Several layers can be distinguished in the atmosphere, based on characteristics such as temperature and composition. The study of Earth's atmosphere and its processes is called atmospheric science (aerology). Early pioneers in the field include Léon Teisserenc de Bort and Richard Assmann. The three major constituents of Earth's atmosphere are nitrogen, oxygen, and argon. Water vapor accounts for roughly 0.25% of the atmosphere by mass. The concentration of water vapor (a greenhouse gas) varies significantly from around
Carbon dioxide in Earth's atmosphere may have been higher, with estimated partial pressure as large as , because there was no bacterial photosynthesis to reduce the gas to carbon compounds and oxygen. Methane, a very active greenhouse gas which reacts with oxygen to produce and water vapor, may have been more prevalent as well, with a mixing ratio of 10 (100 parts per million by volume). Though water is responsible for most (about 36-70%) of the total greenhouse effect, the role of water vapor as a greenhouse gas depends on temperature. On Earth, carbon dioxide is the most relevant, direct anthropologically influenced greenhouse gas. Carbon