Compounds of fluorine heavier halogens (chlorine, bromine, and iodine) all form mono-, tri-, and pentafluorides: XF, XF, and XF. Of the neutral +7 species, only iodine heptafluoride is known. While chlorine and bromine heptafluorides are not known, the corresponding cations and , extremely strong oxidizers, are. Astatine is not well-studied, and although there is a report of a non-volatile astatine monofluoride, its existence is debated. Many of the halogen fluorides are powerful fluorinators. Chlorine trifluoride is particularly noteworthy—readily fluorinating asbestos and refractory oxides—and may be even more reactive than chlorine pentafluoride. Used industrially, ClF requires special precautions similar to those for fluorine gas
Bromine vigorous fluorinating agent, although chlorine trifluoride is still more violent. Bromine pentafluoride explodes on reaction with water and fluorinates silicates at 450 °C. Although dibromine is a strong oxidising agent with a high first ionisation energy, very strong oxidisers such as peroxydisulfuryl fluoride (SOF) can oxidise it to form the cherry-red cation. A few other bromine cations are known, namely the brown and dark brown . The tribromide anion, , has also been characterised; it is analogous to triiodide. Bromine oxides are not as well-characterised as chlorine oxides or iodine oxides, as they are all fairly unstable: it was once