Ozone stratosphere was discovered to be declining, mostly because of increasing concentrations of chlorofluorocarbons (CFC) and similar chlorinated and brominated organic molecules. The concern over the health effects of the decline led to the 1987 Montreal Protocol, the ban on the production of many ozone depleting chemicals and in the first and second decade of the 21st Century the beginning of the recovery of stratospheric ozone concentrations. Ozone in the ozone layer filters out sunlight wavelengths from about 200 nm UV rays to 315 nm, with ozone peak absorption at about 250 nm. This ozone UV absorption is important to life,
Radiation by ozone (O) in particular. Ionizing UV therefore does not penetrate Earth's atmosphere to a significant degree, and is sometimes referred to as vacuum ultraviolet. Although present in space, this part of the UV spectrum is not of biological importance, because it does not reach living organisms on Earth. There is a zone of the atmosphere in which ozone absorbs some 98% of non-ionizing but dangerous UV-C and UV-B. This so-called ozone layer starts at about and extends upward. Some of the ultraviolet spectrum that does reach the ground (the part that begins above energies of 3.1 eV, a wavelength