History of fluorine reaction. Scheele recognized the product of the reaction as an acid, which he called "fluss-spats-syran" (fluor-spar-acid); in English, it was known as "fluoric acid". In 1810, French physicist André-Marie Ampère suggested that hydrofluoric acid was a compound of hydrogen with an unknown element, analogous to chlorine. Fluorite was then shown to be mostly composed of calcium fluoride. Sir Humphry Davy originally suggested the name "fluorine", taking the root from the name of "fluoric acid" and the -ine suffix, similarly to other halogens. This name, with modifications, came to most European languages. (Greek, Russian, and several other languages use the name
Bromine trifluoride BrF molecule is T-shaped and planar. In the VSEPR formalism, the bromine center is assigned two electron pairs. The distance from the bromine each axial fluorine is 1.81 Å and to the equatorial fluorine is 1.72 Å. The angle between an axial fluorine and the equatorial fluorine is slightly smaller than 90° — the 86.2° angle observed is due to the repulsion generated by the electron pairs being greater than that of the Br-F bonds. BrF is a fluorinating agent, but less reactive than ClF. The liquid is conducting, owing to autoionisation: Many ionic fluorides dissolve readily in BrF forming