Chlorine electron affinity, enthalpy of dissociation of the X molecule (X = Cl, Br, I), ionic radius, and X–X bond length. (Fluorine is anomalous due to its small size.) All four stable halogens experience intermolecular van der Waals forces of attraction, and their strength increases together with the number of electrons among all homonuclear diatomic halogen molecules. Thus, the melting and boiling points of chlorine are intermediate between those of fluorine and bromine: chlorine melts at −101.0 °C and boils at −34.0 °C. As a result of the increasing molecular weight of the halogens down the group, the density and heats
Chemistry: A Volatile History all the elements in their order: Notice carbon and silicon are in Group IV and the volatile gases fluorine, chlorine and bromine are in Group VII. Mendeleev was sufficiently confident in the layout of his table that he was willing to leave gaps for unknown elements to make the pattern fit – believing other elements would later be discovered that filled the gaps. So, for Mendeleev to be vindicated, the gaps needed to be filled, and luckily, in 1859, new instrumentation had been developed for discovering elements. Robert Bunsen knew that when certain elements burned in the flames of his