Compounds of fluorine heavier halogens (chlorine, bromine, and iodine) all form mono-, tri-, and pentafluorides: XF, XF, and XF. Of the neutral +7 species, only iodine heptafluoride is known. While chlorine and bromine heptafluorides are not known, the corresponding cations and , extremely strong oxidizers, are. Astatine is not well-studied, and although there is a report of a non-volatile astatine monofluoride, its existence is debated. Many of the halogen fluorides are powerful fluorinators. Chlorine trifluoride is particularly noteworthy—readily fluorinating asbestos and refractory oxides—and may be even more reactive than chlorine pentafluoride. Used industrially, ClF requires special precautions similar to those for fluorine gas
Compounds of fluorine state is −1. It differs from this value in elemental fluorine, where the atoms are bonded to each other and thus at oxidation state 0, and a few polyatomic ions: the very unstable anions and with intermediate oxidation states exist at very low temperatures, decomposing at around 40 K. Also, the cation and a few related species have been predicted to be stable. Fluorine forms compounds with all elements except neon and helium. In particular, it forms binary compounds, named fluorides, with all said elements except argon. All of the elements up to einsteinium, element 99, have been checked except