Mass-to-charge ratio refers to the molecular or atomic mass number and "z" to the charge number of the ion; however, the quantity of "m"/"z" is dimensionless by definition. An ion of 100 atomic mass units ("m" = 100) carrying two charges ("z" = 2) will be observed at "m"/"z" = 50. In the 19th century, the mass-to-charge ratios of some ions were measured by electrochemical methods. In 1897, the mass-to-charge ratio of the electron was first measured by J. J. Thomson. By doing this, he showed that the electron was in fact a particle with a mass and a charge, and that
Point of zero charge Point of zero charge The point of zero charge (pzc), in physical chemistry, is a concept relating to the phenomenon of adsorption, and it describes the condition when the electrical charge density on a surface is zero. It is usually determined in relation to an electrolyte's pH, and the pzc value is assigned to a given substrate or colloidal particle. For example, the pzc of solid FeOOH is 9. In other words, pzc is (usually) the pH value at which a solid submerged in an electrolyte exhibits zero net electrical charge on the surface. A related concept in electrochemistry is