Bromine very penetrating, choking, and unpleasant odour. All four stable halogens experience intermolecular van der Waals forces of attraction, and their strength increases together with number of electrons among all homonuclear diatomic halogen molecules. Thus, the melting and boiling points of bromine are intermediate between those of chlorine and iodine. As a result of the increasing molecular weight of the halogens down the group, the density and heats of fusion and vaporisation of bromine are again intermediate between those of chlorine and iodine, although all their heats of vaporisation are fairly low (leading to high volatility) thanks to their diatomic molecular
Chlorine then be separated and purified from chlorine trifluoride and its reactants. Its properties are mostly intermediate between those of chlorine and fluorine. It will react with many metals and nonmetals from room temperature and above, fluorinating them and liberating chlorine. It will also act as a chlorofluorinating agent, adding chlorine and fluorine across a multiple bond or by oxidation: for example, it will attack carbon monoxide to form carbonyl chlorofluoride, COFCl. It will react analogously with hexafluoroacetone, (CF)CO, with a potassium fluoride catalyst to produce heptafluoroisopropyl hypochlorite, (CF)CFOCl; with nitriles RCN to produce RCFNCl; and with the sulfur oxides SO