Halogen pure halogen with a smaller interhalogen such as . All interhalogens except can be produced by directly combining pure halogens in various conditions. Interhalogens are typically more reactive than all diatomic halogen molecules except F because interhalogen bonds are weaker. However, the chemical properties of interhalogens are still roughly the same as those of diatomic halogens. Many interhalogens consist of one or more atoms of fluorine bonding to a heavier halogen. Chlorine can bond with up to 3 fluorine atoms, bromine can bond with up to five fluorine atoms, and iodine can bond with up to seven fluorine atoms. Most
Chlorine than bromine or iodine. This can be seen from the standard electrode potentials of the X/X couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V). However, this trend is not shown in the bond energies because fluorine is singular due to its small size, low polarisability, and lack of low-lying d-orbitals available for bonding (which chlorine has). As another difference, chlorine has a significant chemistry in positive oxidation states while fluorine does not. Chlorination often leads to higher oxidation states than bromination or iodination but lower oxidation states to fluorination. Chlorine tends