Proton from different gases had different values of charge-to-mass ratio (e/m), they could not be identified with a single particle, unlike the negative electrons discovered by J. J. Thomson. Wilhelm Wien in 1898 identified the hydrogen ion as particle with highest charge-to-mass ratio in ionized gases. Following the discovery of the atomic nucleus by Ernest Rutherford in 1911, Antonius van den Broek proposed that the place of each element in the periodic table (its atomic number) is equal to its nuclear charge. This was confirmed experimentally by Henry Moseley in 1913 using X-ray spectra. In 1917 (in experiments reported in 1919),
Point of zero charge Point of zero charge The point of zero charge (pzc), in physical chemistry, is a concept relating to the phenomenon of adsorption, and it describes the condition when the electrical charge density on a surface is zero. It is usually determined in relation to an electrolyte's pH, and the pzc value is assigned to a given substrate or colloidal particle. For example, the pzc of solid FeOOH is 9. In other words, pzc is (usually) the pH value at which a solid submerged in an electrolyte exhibits zero net electrical charge on the surface. A related concept in electrochemistry is