Work (thermodynamics) of the energy went out as heat, and how much as work. This can be summarized by saying that heat and work are not state functions of the system. This is in contrast to classical mechanics, where net work exerted by a particle is a state function. Pressure–volume work (or "PV" work) occurs when the volume of a system changes. "PV" work is often measured in units of litre-atmospheres where = . However, the litre-atmosphere is not a recognised unit in the SI system of units, which measures P in Pascal (Pa), V in m, and PV in Joule (J),
Gibbs free energy we add the qualification that it is the energy available for "non-volume" work. (An analogous, but slightly different, meaning of "free" applies in conjunction with the Helmholtz free energy, for systems at constant temperature). However, an increasing number of books and journal articles do not include the attachment "free", referring to "G" as simply "Gibbs energy". This is the result of a 1988 IUPAC meeting to set unified terminologies for the international scientific community, in which the adjective "free" was supposedly banished. This standard, however, has not yet been universally adopted. The quantity called "free energy" is a more advanced