Kramers–Heisenberg formula Kramers–Heisenberg formula The Kramers–Heisenberg dispersion formula is an expression for the cross section for scattering of a photon by an atomic electron. It was derived before the advent of quantum mechanics by Hendrik Kramers and Werner Heisenberg in 1925, based on the correspondence principle applied to the classical dispersion formula for light. The quantum mechanical derivation was given by Paul Dirac in 1927. The Kramers–Heisenberg formula was an important achievement when it was published, explaining the notion of "negative absorption" (stimulated emission), the Thomas–Reiche–Kuhn sum rule, and inelastic scattering — where the energy of the scattered photon may be larger
Werner Heisenberg explain the outstanding problem of the anomalous Zeeman effect, led Heisenberg to use the virtual oscillator model to try to calculate spectral frequencies. The method proved too difficult to immediately apply to realistic problems, so Heisenberg turned to a simpler example, the anharmonic oscillator. The dipole oscillator consists of a simple harmonic oscillator, which is thought of as a charged particle on a spring, perturbed by an external force, like an external charge. The motion of the oscillating charge can be expressed as a Fourier series in the frequency of the oscillator. Heisenberg solved for the quantum behavior by two