Chlorine electron affinity, enthalpy of dissociation of the X molecule (X = Cl, Br, I), ionic radius, and X–X bond length. (Fluorine is anomalous due to its small size.) All four stable halogens experience intermolecular van der Waals forces of attraction, and their strength increases together with the number of electrons among all homonuclear diatomic halogen molecules. Thus, the melting and boiling points of chlorine are intermediate between those of fluorine and bromine: chlorine melts at −101.0 °C and boils at −34.0 °C. As a result of the increasing molecular weight of the halogens down the group, the density and heats
Bromine their oxides: as such, it is used to oxidise uranium to uranium hexafluoride in the nuclear industry. Refractory oxides tend to be only partially fluorinated, but here the derivatives KBrF and BrFSbF remain reactive. Bromine trifluoride is a useful nonaqueous ionising solvent, since it readily dissociates to form and and thus conducts electricity. Bromine pentafluoride (BrF) was first synthesised in 1930. It is produced on a large scale by direct reaction of bromine with excess fluorine at temperatures higher than 150 °C, and on a small scale by the fluorination of potassium bromide at 25 °C. It is a very