Halogen bond the electron density on H or X appears to be reduced. Electron density transfers results in a penetration of the van der Waals volumes. Halogens participating in halogen bonding include: iodine (I), bromine (Br), chlorine (Cl), and sometimes fluorine (F). All four halogens are capable of acting as XB donors (as proven through theoretical and experimental data) and follow the general trend: F < Cl < Br < I, with iodine normally forming the strongest interactions. Dihalogens (I, Br, etc.) tend to form strong halogen bonds. The strength and effectiveness of chlorine and fluorine in XB formation depend on the
Chlorine pentafluoride with water to produce chloryl fluoride and hydrogen fluoride: It is also a strong fluorinating agent. At room temperature it reacts readily with all elements (including otherwise "inert" elements like platinum and gold) except noble gases, nitrogen, oxygen and fluorine. Chlorine pentafluoride Chlorine pentafluoride is an interhalogen compound with formula ClF. This colourless gas is a strong oxidant that was once a candidate oxidizer for rockets. The molecule adopts a square pyramidal structure with C symmetry, as confirmed by its high-resolution F NMR spectrum. Some of the earliest research on the preparation was classified. It was first prepared by fluorination