Ozone depletion an ozone layer in the Earth's stratosphere were discovered by Sydney Chapman in 1930. Short-wavelength UV radiation splits an oxygen () molecule into two oxygen (O) atoms, which then combine with other oxygen molecules to form ozone. Ozone is removed when an oxygen atom and an ozone molecule "recombine" to form two oxygen molecules, i.e. O + → 2. In the 1950s, David Bates and Marcel Nicolet presented evidence that various free radicals, in particular hydroxyl (OH) and nitric oxide (NO), could catalyze this recombination reaction, reducing the overall amount of ozone. These free radicals were known to be present
Tropospheric ozone is the reaction of •OH with NO to form nitric acid at high NOx levels. If nitrogen monoxide (NO) is instead present at very low levels in the atmosphere (less than 10 approximately ppt), the of peroxy radicals (HO• ) formed from the oxidation will instead react with themselves to form peroxides, and not produce ozone. Health effects depend on ozone precursors, which is a group of pollutants, primarily generated during the combustion of fossil fuels. Reaction with daylight ultraviolet (UV) rays and these precursors create ground-level ozone pollution (Tropospheric Ozone). Ozone is known to have the following health effects