Bromine dioxide treatment of bromine gas with ozone in trichlorofluoromethane at −50 °C. When mixed with a base, bromine dioxide gives the bromide and bromate anions: Bromine dioxide Bromine dioxide is the chemical compound composed of bromine and oxygen with the formula BrO. It forms unstable yellow to yellow-orange crystals. It was first isolated by R. Schwarz and M. Schmeißer in 1937 and is hypothesized to be important in the atmospheric reaction of bromine with ozone. It is similar to chlorine dioxide, the dioxide of its halogen neighbor one period higher on the periodic table. Bromine dioxide is formed when an electric
Bromine production in the United States rail access, and difficult highway access, and was shut down in 1945. Dow found a better permanent location at Freeport, Texas, where a seawater extraction plant started in 1940, and a second in 1943. The Freeport plants recovered magnesium, sodium compounds, and chlorine, in addition to the bromine. The Freeport chemical operations are still active, but they stopped extracting bromine in 1969. Brine mining Bromine production in the United States Bromine production in the United States of 225,000 tonnes in 2013 made that country the second-largest producer of bromine, after Israel. The US supplied 29 percent of world production. Since