Isotopes of chlorine Isotopes of chlorine Chlorine (Cl) has 25 isotopes with mass numbers ranging from Cl to Cl and 2 isomers (Cl and Cl). There are two principal stable isotopes, Cl (75.78%) and Cl (24.22%), giving chlorine a standard atomic weight of 35.45. The longest-lived radioactive isotope is Cl, which has a half-life of 301,000 years. All other isotopes have half-lives under 1 hour, many less than one second. The shortest-lived are Cl and Cl, with half-lives less than 20 and 30 nanoseconds, respectively—the half-life of Cl is unknown. Bromine is the only other halogen with more than one stable isotope. Trace
Bromine weaker reducing agent than iodide, but a stronger one than chloride. These similarities led to chlorine, bromine, and iodine together being classified as one of the original triads of Johann Wolfgang Döbereiner, whose work foreshadowed the periodic law for chemical elements. It is intermediate in atomic radius between chlorine and iodine, and this leads to many of its atomic properties being similarly intermediate in value between chlorine and iodine, such as first ionisation energy, electron affinity, enthalpy of dissociation of the X molecule (X = Cl, Br, I), ionic radius, and X–X bond length. The volatility of bromine accentuates its