Isotopes of chlorine Isotopes of chlorine Chlorine (Cl) has 25 isotopes with mass numbers ranging from Cl to Cl and 2 isomers (Cl and Cl). There are two principal stable isotopes, Cl (75.78%) and Cl (24.22%), giving chlorine a standard atomic weight of 35.45. The longest-lived radioactive isotope is Cl, which has a half-life of 301,000 years. All other isotopes have half-lives under 1 hour, many less than one second. The shortest-lived are Cl and Cl, with half-lives less than 20 and 30 nanoseconds, respectively—the half-life of Cl is unknown. Bromine is the only other halogen with more than one stable isotope. Trace
Bromine occurs for X = Me, Bu, OMe, Br; "meta"-bromination occurs for the deactivating X = –COEt, –CHO, –NO); this is due to heterolytic fission of the Br–F bond, leading to rapid electrophilic bromination by Br. At room temperature, bromine trifluoride (BrF) is a straw-coloured liquid. It may be formed by directly fluorinating bromine at room temperature and is purified through distillation. It reacts explosively with water and hydrocarbons, but is a less violent fluorinating reagent than chlorine trifluoride. It reacts vigorously with boron, carbon, silicon, arsenic, antimony, iodine, and sulfur to give fluorides, and also reacts with most metals and