Mass-to-charge ratio refers to the molecular or atomic mass number and "z" to the charge number of the ion; however, the quantity of "m"/"z" is dimensionless by definition. An ion of 100 atomic mass units ("m" = 100) carrying two charges ("z" = 2) will be observed at "m"/"z" = 50. In the 19th century, the mass-to-charge ratios of some ions were measured by electrochemical methods. In 1897, the mass-to-charge ratio of the electron was first measured by J. J. Thomson. By doing this, he showed that the electron was in fact a particle with a mass and a charge, and that
Mass-to-charge ratio a scalar property, meaning that it can be either positive (+) or negative (−). The Coulomb (C) is the SI unit of charge; however, other units can be used, such as expressing charge in terms of the elementary charge (e). The SI unit of the physical quantity "m"/"Q" is kilogram per coulomb. The units and notation above are used when dealing with the physics of mass spectrometry; however, the "m"/"z" notation is used for the independent variable in a mass spectrum. This notation eases data interpretation since it is numerically more related to the unified atomic mass unit. The "m"