Electrical resistivity and conductivity results in the important concept of "quasineutrality", which says the density of negative charges is approximately equal to the density of positive charges over large volumes of the plasma ("n" = <Z>"n"), but on the scale of the Debye length there can be charge imbalance. In the special case that "double layers" are formed, the charge separation can extend some tens of Debye lengths. The magnitude of the potentials and electric fields must be determined by means other than simply finding the net charge density. A common example is to assume that the electrons satisfy the Boltzmann relation: Differentiating this
Isoelectric point is expected to be somewhat different than the point of zero charge at the particle surface, but this difference is often ignored in practice for so-called pristine surfaces, i.e., surfaces with no specifically adsorbed positive or negative charges. In this context, specific adsorption is understood as adsorption occurring in a Stern layer or chemisorption. Thus, point of zero charge at the surface is taken as equal to isoelectric point in the absence of specific adsorption on that surface. According to Jolivet, in the absence of positive or negative charges, the surface is best described by the point of zero charge.