Work (thermodynamics) of the energy went out as heat, and how much as work. This can be summarized by saying that heat and work are not state functions of the system. This is in contrast to classical mechanics, where net work exerted by a particle is a state function. Pressure–volume work (or "PV" work) occurs when the volume of a system changes. "PV" work is often measured in units of litre-atmospheres where = . However, the litre-atmosphere is not a recognised unit in the SI system of units, which measures P in Pascal (Pa), V in m, and PV in Joule (J),
Surface energy it is the work required to build an area of a particular surface. Another way to view the surface energy is to relate it to the work required to cut a bulk sample, creating two surfaces. Cutting a solid body into pieces disrupts its bonds, and therefore increases free energy. If the cutting is done reversibly, then conservation of energy means that the energy consumed by the cutting process will be equal to the energy inherent in the two new surfaces created. The unit surface energy of a material would therefore be half of its energy of cohesion, all other