Tropospheric ozone concentration at the tropopause. About 90% of total ozone in the atmosphere is in the stratosphere, and 10% is in the troposphere. Although tropospheric ozone is less concentrated than stratospheric ozone, it is of concern because of its health effects. Ozone in the troposphere is considered a greenhouse gas, and may contribute to global warming. Photo-chemical and chemical reactions involving ozone drive many of the chemical processes that occur in the troposphere by day and by night. At abnormally high concentrations (the largest source being emissions from combustion of fossil fuels), it is a pollutant, and a constituent of smog.
Ozone depletion and climate change dubbed "monumental" and a combined synopsis provided. There are some parallels between atmospheric chemistry and anthropogenic emissions in the discussions which have taken place and the regulatory attempts which have been made. Most important is that the gases causing both problems have long lifetimes after emission to the atmosphere, thus causing problems which are difficult to reverse. However, the Vienna Convention for the Protection of the Ozone Layer and the Montreal Protocol that amended it are seen as success stories, while the Kyoto Protocol on anthropogenic climate change has largely failed. Currently efforts are being undertaken to assess the reasons