Fluorine in annual revenue. Due to the danger from direct hydrocarbon–fluorine reactions above −150 °C (−240 °F), industrial fluorocarbon production is indirect, mostly through halogen exchange reactions such as Swarts fluorination, in which chlorocarbon chlorines are substituted for fluorines by hydrogen fluoride under catalysts. Electrochemical fluorination subjects hydrocarbons to electrolysis in hydrogen fluoride, and the Fowler process treats them with solid fluorine carriers like cobalt trifluoride. Halogenated refrigerants, termed Freons in informal contexts, are identified by R-numbers that denote the amount of fluorine, chlorine, carbon, and hydrogen present. Chlorofluorocarbons (CFCs) like R-11, R-12, and R-114 once dominated organofluorines, peaking in production
Fluorine other elements from carbon to magnesium are twenty or more times as common. This is because stellar nucleosynthesis processes bypass fluorine, and any fluorine atoms otherwise created have high nuclear cross sections, allowing further fusion with hydrogen or helium to generate oxygen or neon respectively. Beyond this transient existence, three explanations have been proposed for the presence of fluorine: Fluorine is the thirteenth most common element in Earth's crust at 600–700 ppm (parts per million) by mass. Elemental fluorine in Earth's atmosphere would easily react with atmospheric water vapor, precluding its natural occurrence; it is found only in combined mineral