Tropospheric ozone concentration at the tropopause. About 90% of total ozone in the atmosphere is in the stratosphere, and 10% is in the troposphere. Although tropospheric ozone is less concentrated than stratospheric ozone, it is of concern because of its health effects. Ozone in the troposphere is considered a greenhouse gas, and may contribute to global warming. Photo-chemical and chemical reactions involving ozone drive many of the chemical processes that occur in the troposphere by day and by night. At abnormally high concentrations (the largest source being emissions from combustion of fossil fuels), it is a pollutant, and a constituent of smog.
Ozone of UV-B radiation at similar frequency reaches the ground to cause some sunburn, and these same wavelengths are also among those responsible for the production of vitamin D in humans. The ozone layer has little effect on the longer UV wavelengths called UV-A (315–400 nm), but this radiation does not cause sunburn or direct DNA damage, and while it probably does cause long-term skin damage in certain humans, it is not as dangerous to plants and to the health of surface-dwelling organisms on Earth in general (see ultraviolet for more information on near ultraviolet). Low level ozone (or tropospheric ozone)