Kramers–Heisenberg formula Kramers–Heisenberg formula The Kramers–Heisenberg dispersion formula is an expression for the cross section for scattering of a photon by an atomic electron. It was derived before the advent of quantum mechanics by Hendrik Kramers and Werner Heisenberg in 1925, based on the correspondence principle applied to the classical dispersion formula for light. The quantum mechanical derivation was given by Paul Dirac in 1927. The Kramers–Heisenberg formula was an important achievement when it was published, explaining the notion of "negative absorption" (stimulated emission), the Thomas–Reiche–Kuhn sum rule, and inelastic scattering — where the energy of the scattered photon may be larger
Werner Heisenberg 1927, Heisenberg was a Privatdozent at Göttingen, meaning he was qualified to teach and examine independently, without having a chair. From 17 September 1924 to 1 May 1925, under an International Education Board Rockefeller Foundation fellowship, Heisenberg went to do research with Niels Bohr, director of the Institute of Theoretical Physics at the University of Copenhagen. His seminal paper, "Über quantentheoretische Umdeutung kinematischer und mechanischer Beziehungen" ("Quantum theoretical re-interpretation of kinematic and mechanical relations"), was published in September 1925. He returned to Göttingen and, with Max Born and Pascual Jordan over a period of about six months, developed the matrix