Vibration modal coordinates or modal participation factors. It may be clearer to understand if formula_72 is written as: Written in this form it can be seen that the vibration at each of the degrees of freedom is just a linear sum of the mode shapes. Furthermore, how much each mode "participates" in the final vibration is defined by q, its modal participation factor. An unrestrained multi-degree of freedom system experiences both rigid-body translation and/or rotation and vibration. The existence of a rigid-body mode results in a zero natural frequency. The corresponding mode shape is called the rigid-body mode. Vibration Vibration is
Molecular vibration each of the four C-H bonds. Illustrations of symmetry-adapted coordinates for most small molecules can be found in Nakamoto. The normal coordinates, denoted as "Q", refer to the positions of atoms away from their equilibrium positions, with respect to a normal mode of vibration. Each normal mode is assigned a single normal coordinate, and so the normal coordinate refers to the "progress" along that normal mode at any given time. Formally, normal modes are determined by solving a secular determinant, and then the normal coordinates (over the normal modes) can be expressed as a summation over the cartesian coordinates (over