Halomethane the interaction of chlorine sources with various carbon compounds. The biosyntheses of these halomethanes are catalyzed by the chloroperoxidase and bromoperoxidase enzymes, respectively. An idealized equation is: Halons are usually defined as hydrocarbons where the hydrogen atoms have been replaced by bromine, along with other halogens. They are referred to by a system of code numbers similar to (but simpler than) the system used for freons. The first digit specifies the number of carbon atoms in the molecule, the second is the number of fluorine atoms, the third is the chlorine atoms, and the fourth is the number of bromine
Chlorine made on a large scale by direct fluorination of chlorine with excess fluorine gas at 350 °C and 250 atm, and on a small scale by reacting metal chlorides with fluorine gas at 100–300 °C. It melts at −103 °C and boils at −13.1 °C. It is a very strong fluorinating agent, although it is still not as effective as chlorine trifluoride. Only a few specific stoichiometric reactions have been characterised. Arsenic pentafluoride and antimony pentafluoride form ionic adducts of the form [ClF][MF] (M = As, Sb) and water reacts vigorously as follows: The product, chloryl fluoride, is one of