Charge density many of them in a macroscopic volume (there are about 10 conduction electrons in a cubic centimeter of copper) the continuous approximation is very accurate when applied to macroscopic volumes, and even microscopic volumes above the nanometer level. At atomic scales, due to the uncertainty principle of quantum mechanics, a charged particle does not "have" a precise position but is represented by a probability distribution, so the charge of an individual particle is not concentrated at a point but is 'smeared out' in space and acts like a true continuous charge distribution. This is the meaning of 'charge distribution' and
Point of zero charge Point of zero charge The point of zero charge (pzc), in physical chemistry, is a concept relating to the phenomenon of adsorption, and it describes the condition when the electrical charge density on a surface is zero. It is usually determined in relation to an electrolyte's pH, and the pzc value is assigned to a given substrate or colloidal particle. For example, the pzc of solid FeOOH is 9. In other words, pzc is (usually) the pH value at which a solid submerged in an electrolyte exhibits zero net electrical charge on the surface. A related concept in electrochemistry is