Carbon–fluorine bond the molecule represented by CHX has a BDE of 115 kcal/mol for carbon–fluorine while values of 104.9, 83.7, 72.1, and 57.6 kcal/mol represent carbon–X bonds to hydrogen, chlorine, bromine, and iodine, respectively. The carbon–fluorine bond length is typically about 1.35 ångström (1.39 Å in fluoromethane). It is shorter than any other carbon–halogen bond, and shorter than single carbon–nitrogen and carbon–oxygen bonds, despite fluorine having a larger atomic mass. The short length of the bond can also be attributed to the ionic character/electrostatic attractions between the partial charges on carbon and fluorine. The carbon–fluorine bond length varies by several hundredths of
Bromine trifluoride BrF molecule is T-shaped and planar. In the VSEPR formalism, the bromine center is assigned two electron pairs. The distance from the bromine each axial fluorine is 1.81 Å and to the equatorial fluorine is 1.72 Å. The angle between an axial fluorine and the equatorial fluorine is slightly smaller than 90° — the 86.2° angle observed is due to the repulsion generated by the electron pairs being greater than that of the Br-F bonds. BrF is a fluorinating agent, but less reactive than ClF. The liquid is conducting, owing to autoionisation: Many ionic fluorides dissolve readily in BrF forming