Dimer (chemistry) dimerise to give the dimer "A-A". An example is a diaminocarbene, which dimerise to give a tetraaminoethylene: Carbenes are highly reactive and readily form bonds. Dicyclopentadiene is an asymmetrical dimer of two cyclopentadiene molecules that have reacted in a Diels-Alder reaction to give the product. Upon heating, it "cracks" (undergoes a retro-Diels-Alder reaction) to give identical monomers: Many nonmetallic elements occur as dimers: hydrogen, nitrogen, oxygen, the halogens, i.e. fluorine, chlorine, bromine and iodine. Noble gases can form dimers linked by van der Waals bonds, for example dihelium or diargon. Mercury occurs as a mercury(I) cation (Hg), formally a dimeric
Graphite intercalation compound A stage n magnetic GIC has n graphite layers separating successive magnetic layers. As the stage number increases the interaction between spins in successive magnetic layers becomes weaker and 2D magnetic behaviour may arise. Chlorine and bromine reversibly intercalate into graphite. Iodine does not. Fluorine reacts irreversibly. In the case of bromine, the following stoichiometries are known: CBr for n = 8, 12, 14, 16, 20, and 28. Because it forms irreversibly, carbon monofluoride is often not classified as an intercalation compound. It has the formula (CF). It is prepared by reaction of gaseous fluorine with graphitic carbon at 215–230