Ozone depletion an ozone layer in the Earth's stratosphere were discovered by Sydney Chapman in 1930. Short-wavelength UV radiation splits an oxygen () molecule into two oxygen (O) atoms, which then combine with other oxygen molecules to form ozone. Ozone is removed when an oxygen atom and an ozone molecule "recombine" to form two oxygen molecules, i.e. O + → 2. In the 1950s, David Bates and Marcel Nicolet presented evidence that various free radicals, in particular hydroxyl (OH) and nitric oxide (NO), could catalyze this recombination reaction, reducing the overall amount of ozone. These free radicals were known to be present
Ozone cracking were commonly seen in automobile tire sidewalls, but are now seen rarely thanks to the use of these additives. A common and low cost antiozonant is a wax which bleeds to the surface and forms a protective layer, but other specialist chemicals are also widely used. On the other hand, the problem does recur in unprotected products such as rubber tubing and seals, where ozone attack is thought to be impossible. Unfortunately, traces of ozone can turn up in the most unexpected situations. Using ozone-resistant rubbers is another way of inhibiting cracking. EPDM rubber and butyl rubber are ozone resistant,