Asphyxiant gas can smell the odorants, and assigning a different smell to each gas may be impractical. Another difficulty is that most odorants (e.g., the thiols) are chemically reactive. This is not a problem with natural gas intended to be burned as fuel, which is routinely odorized, but a major use of asphyxiants such as nitrogen, helium, argon and krypton is to protect reactive materials from the atmosphere. The dangers of excess concentrations of nontoxic gases has been recognized for centuries within the mining industry. The concept of black damp (or "stythe") reflects an understanding that certain gaseous mixtures could lead to
Trace gas the major greenhouse gases are water, carbon dioxide, methane, nitrous oxide, ozone, and CFCs. These gases can absorb infrared radiation from the Earth's surface as it passes through the atmosphere. The most important greenhouse gas is water vapor because it can trap about 80 percent of outgoing IR radiation. The second most important greenhouse gas, and the most important one affected by man-made sources into the atmosphere, is carbon dioxide. The reason for why greenhouse gases can absorb infrared radiation is their molecular structure. For example, carbon dioxide has two basic modes of vibration that create a strong dipole-moment, which