Heisenberg picture formulation of matrix mechanics in an arbitrary basis, in which the Hamiltonian is not necessarily diagonal. It further serves to define a third, hybrid, picture, the interaction picture. In the Heisenberg picture of quantum mechanics the state vectors, |"ψ("t")"〉, do not change with time, while observables satisfy where is the Hamiltonian and <nowiki>[•,•]</nowiki> denotes the commutator of two operators (in this case and ). Taking expectation values automatically yields the Ehrenfest theorem, featured in the correspondence principle. By the Stone–von Neumann theorem, the Heisenberg picture and the Schrödinger picture are unitarily equivalent, just a basis change in Hilbert space. In
Werner Heisenberg explain the outstanding problem of the anomalous Zeeman effect, led Heisenberg to use the virtual oscillator model to try to calculate spectral frequencies. The method proved too difficult to immediately apply to realistic problems, so Heisenberg turned to a simpler example, the anharmonic oscillator. The dipole oscillator consists of a simple harmonic oscillator, which is thought of as a charged particle on a spring, perturbed by an external force, like an external charge. The motion of the oscillating charge can be expressed as a Fourier series in the frequency of the oscillator. Heisenberg solved for the quantum behavior by two