Chemical ionization source, the reagent gas is present in large excess compared to the analyte. Electrons entering the source with energy around 200-500 eV will preferentially ionize the reagent gas. Then, the ion/molecule reactions produces more stable reagent ions and the resultant collisions with other reagent gas molecules will create an ionization plasma. Positive and negative ions of the analyte are formed by reactions with this plasma. The following reactions are possible with methane as the reagent gas. If ammonia is the reagent gas, For isobutane as the reagent gas, Self chemical ionization is possible if the reagent ion is an ionized
Negative base Negative base A negative base (or negative radix) may be used to construct a non-standard positional numeral system. Like other place-value systems, each position holds multiples of the appropriate power of the system's base; but that base is negative—that is to say, the base is equal to for some natural number (). Negative-base systems can accommodate all the same numbers as standard place-value systems, but both positive and negative numbers are represented without the use of a minus sign (or, in computer representation, a sign bit); this advantage is countered by an increased complexity of arithmetic operations. The need to