Chlorine of fusion and vaporisation of chlorine are again intermediate between those of bromine and fluorine, although all their heats of vaporisation are fairly low (leading to high volatility) thanks to their diatomic molecular structure. The halogens darken in colour as the group is descended: thus, while fluorine is a pale yellow gas, chlorine is distinctly yellow-green. This trend occurs because the wavelengths of visible light absorbed by the halogens increase down the group. Specifically, the colour of a halogen, such as chlorine, results from the electron transition between the highest occupied antibonding "π" molecular orbital and the lowest vacant antibonding
Chemistry: A Volatile History all the elements in their order: Notice carbon and silicon are in Group IV and the volatile gases fluorine, chlorine and bromine are in Group VII. Mendeleev was sufficiently confident in the layout of his table that he was willing to leave gaps for unknown elements to make the pattern fit – believing other elements would later be discovered that filled the gaps. So, for Mendeleev to be vindicated, the gaps needed to be filled, and luckily, in 1859, new instrumentation had been developed for discovering elements. Robert Bunsen knew that when certain elements burned in the flames of his