Atomic orbital , the letters associated with those numbers are K, L, M, N, O, ... respectively. The simplest atomic orbitals are those that are calculated for systems with a single electron, such as the hydrogen atom. An atom of any other element ionized down to a single electron is very similar to hydrogen, and the orbitals take the same form. In the Schrödinger equation for this system of one negative and one positive particle, the atomic orbitals are the eigenstates of the Hamiltonian operator for the energy. They can be obtained analytically, meaning that the resulting orbitals are products of a
Particle in a box not strictly hold for the measured momentum ; the energy eigenstate formula_38 is not a momentum eigenstate, and, in fact, not even a superposition of two momentum eigenstates, as one might be tempted to imagine from equation () above: peculiarly, it has no well-defined momentum before measurement! In classical physics, the particle can be detected anywhere in the box with equal probability. In quantum mechanics, however, the probability density for finding a particle at a given position is derived from the wavefunction as formula_39 For the particle in a box, the probability density for finding the particle at a given