White wine as the heat accelerates its degradation. There are many other acids in small quantities: citric acid, ascorbic acid, α-ketoglutaric, fumaric acid, galacturonic acid, coumaric acid, etc. Their variable quantity varies the pH of the wort. The must of white wine is generally more acidic than red grape must simply because the grape maturity is less advanced. Vitamin C (or ascorbic acid) is present in the grape and the must up to 50 milligrams per litre. It is a protection in the wort against the oxidation phenomenon. In the presence of oxygen it produces hydrogen peroxide; by this reaction it deprives
Chemistry of ascorbic acid the presence of free metal ions can not only promote but also initiate free radical reactions, thus making it a potentially dangerous pro-oxidative compound in certain metabolic contexts. Ascorbic acid and its sodium, potassium, and calcium salts are commonly used as antioxidant food additives. These compounds are water-soluble and, thus, cannot protect fats from oxidation: For this purpose, the fat-soluble esters of ascorbic acid with long-chain fatty acids (ascorbyl palmitate or ascorbyl stearate) can be used as food antioxidants. It creates volatile compounds when mixed with glucose and amino acids in 90 °C. It is a cofactor in tyrosine oxidation.