Ozone layer an altitude of 100 kilometers from the planet's surface. The photochemical mechanisms that give rise to the ozone layer were discovered by the British physicist Sydney Chapman in 1930. Ozone in the Earth's stratosphere is created by ultraviolet light striking ordinary oxygen molecules containing two oxygen atoms (O), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines with unbroken O to create ozone, O. The ozone molecule is unstable (although, in the stratosphere, long-lived) and when ultraviolet light hits ozone it splits into a molecule of O and an individual atom of oxygen, a continuing process
Ozone ozone. In the clear atmosphere, with only nitrogen and oxygen, ozone can react with the atomic oxygen to form two molecules of O An estimate of the rate of this termination step to the cycling of atomic oxygen back to ozone can be found simply by taking the ratios of the concentration of O to O. The termination reaction is catalysed by the presence of certain free radicals, of which the most important are hydroxyl (OH), nitric oxide (NO) and atomic chlorine (Cl) and bromine (Br). In the second half of the 20th Century the amount of ozone in the