Ozone depletion an ozone layer in the Earth's stratosphere were discovered by Sydney Chapman in 1930. Short-wavelength UV radiation splits an oxygen () molecule into two oxygen (O) atoms, which then combine with other oxygen molecules to form ozone. Ozone is removed when an oxygen atom and an ozone molecule "recombine" to form two oxygen molecules, i.e. O + → 2. In the 1950s, David Bates and Marcel Nicolet presented evidence that various free radicals, in particular hydroxyl (OH) and nitric oxide (NO), could catalyze this recombination reaction, reducing the overall amount of ozone. These free radicals were known to be present
Radiation by ozone (O) in particular. Ionizing UV therefore does not penetrate Earth's atmosphere to a significant degree, and is sometimes referred to as vacuum ultraviolet. Although present in space, this part of the UV spectrum is not of biological importance, because it does not reach living organisms on Earth. There is a zone of the atmosphere in which ozone absorbs some 98% of non-ionizing but dangerous UV-C and UV-B. This so-called ozone layer starts at about and extends upward. Some of the ultraviolet spectrum that does reach the ground (the part that begins above energies of 3.1 eV, a wavelength