Atomic theory formula for the water molecule (HO), or 16 if one assumes the modern water formula (HO). The flaw in Dalton's theory was corrected in principle in 1811 by Amedeo Avogadro. Avogadro had proposed that equal volumes of any two gases, at equal temperature and pressure, contain equal numbers of molecules (in other words, the mass of a gas's particles does not affect the volume that it occupies). Avogadro's law allowed him to deduce the diatomic nature of numerous gases by studying the volumes at which they reacted. For instance: since two liters of hydrogen will react with just one liter
Amagat's law pressure, the sum of which is the total pressure. Amagat's law assumes that the volumes of the component gases (again at the same temperature and pressure) are additive; the interactions of the different gases are the same as the average interactions of the components. The interactions can be interpreted in terms of a second virial coefficient, B(T), for the mixture. For two components, the second virial coefficient for the mixture can be expressed as: where the subscripts refer to components 1 and 2, the X's are the mole fractions, and the B's are the second virial coefficients. The cross term,