Compounds of fluorine heavier halogens (chlorine, bromine, and iodine) all form mono-, tri-, and pentafluorides: XF, XF, and XF. Of the neutral +7 species, only iodine heptafluoride is known. While chlorine and bromine heptafluorides are not known, the corresponding cations and , extremely strong oxidizers, are. Astatine is not well-studied, and although there is a report of a non-volatile astatine monofluoride, its existence is debated. Many of the halogen fluorides are powerful fluorinators. Chlorine trifluoride is particularly noteworthy—readily fluorinating asbestos and refractory oxides—and may be even more reactive than chlorine pentafluoride. Used industrially, ClF requires special precautions similar to those for fluorine gas
Chlorine nuclide in a ratio of about (7–10) × 10 to 1 with stable chlorine isotopes: it is produced in the atmosphere by spallation of Ar by interactions with cosmic ray protons. In the top meter of the lithosphere, Cl is generated primarily by thermal neutron activation of Cl and spallation of K and Ca. In the subsurface environment, muon capture by Ca becomes more important as a way to generate Cl. Chlorine is intermediate in reactivity between fluorine and bromine, and is one of the most reactive elements. Chlorine is a weaker oxidising agent than fluorine but a stronger one