Natural gas gas is often described as the cleanest fossil fuel. It produces 25–30% and 40–45% less carbon dioxide per joule delivered than oil and coal respectively, and potentially fewer pollutants than other hydrocarbon fuels. However, in absolute terms, it comprises a substantial percentage of human carbon emissions, and this contribution is projected to grow. According to the IPCC Fourth Assessment Report, in 2004, natural gas produced about 5.3 billion tons a year of emissions, while coal and oil produced 10.6 and 10.2 billion tons respectively. According to an updated version of the Special Report on Emissions Scenario by 2030, natural gas
Carbon dioxide and microbial fermentation. In 1772, English chemist Joseph Priestley published a paper entitled "Impregnating Water with Fixed Air" in which he described a process of dripping sulfuric acid (or "oil of vitriol" as Priestley knew it) on chalk in order to produce carbon dioxide, and forcing the gas to dissolve by agitating a bowl of water in contact with the gas. Carbon dioxide was first liquefied (at elevated pressures) in 1823 by Humphry Davy and Michael Faraday. The earliest description of solid carbon dioxide was given by Adrien-Jean-Pierre Thilorier, who in 1835 opened a pressurized container of liquid carbon dioxide,