Free-radical halogenation distribution". For propane and higher alkanes, the hydrogen atoms which form part of CH (or CH) groups are preferentially replaced. The reactivity of the different halogens varies considerably. The relative rates are: fluorine (108) > chlorine (1) > bromine (7 × 10) > iodine (2 × 10). Hence, the reaction of alkanes with fluorine is difficult to control, that with chlorine is moderate to fast, that with bromine is slow and requires high levels of UV irradiation while the reaction with iodine is practically nonexistent and thermodynamically unfavorable. A common method in organic synthesis employing is the Wohl–Ziegler reaction, which
Chlorine pentafluoride with water to produce chloryl fluoride and hydrogen fluoride: It is also a strong fluorinating agent. At room temperature it reacts readily with all elements (including otherwise "inert" elements like platinum and gold) except noble gases, nitrogen, oxygen and fluorine. Chlorine pentafluoride Chlorine pentafluoride is an interhalogen compound with formula ClF. This colourless gas is a strong oxidant that was once a candidate oxidizer for rockets. The molecule adopts a square pyramidal structure with C symmetry, as confirmed by its high-resolution F NMR spectrum. Some of the earliest research on the preparation was classified. It was first prepared by fluorination