Chlorine electron affinity, enthalpy of dissociation of the X molecule (X = Cl, Br, I), ionic radius, and X–X bond length. (Fluorine is anomalous due to its small size.) All four stable halogens experience intermolecular van der Waals forces of attraction, and their strength increases together with the number of electrons among all homonuclear diatomic halogen molecules. Thus, the melting and boiling points of chlorine are intermediate between those of fluorine and bromine: chlorine melts at −101.0 °C and boils at −34.0 °C. As a result of the increasing molecular weight of the halogens down the group, the density and heats
Origin and use of the term metalloid their ability to form oxyanions. A common oxyanion of sulfur, for example, is the sulfate ion SO. Many metals can do the same. Chromium, for instance, can form the chromate ion CrO. Berzelius' terminology was widely adopted although it was subsequently regarded by some commentators as counterintuitive, misapplied, incorrect or invalid. In 1825, in a revised German edition of his "Textbook of Chemistry," Berzelius subdivided the metalloids into three classes. These were: constantly gaseous 'gazolyta' (hydrogen, nitrogen, oxygen); real metalloids (sulfur, phosphorus, carbon, boron, silicon); and salt-forming 'halogenia' (fluorine, chlorine, bromine, iodine). In 1844, Jackson gave the meaning of 'metalloid'