Photosynthesis that a complex of reactions consisting of an intermediate to cytochrome b (now a plastoquinone), another is from cytochrome f to a step in the carbohydrate-generating mechanisms. These are linked by plastoquinone, which does require energy to reduce cytochrome f for it is a sufficient reductant. Further experiments to prove that the oxygen developed during the photosynthesis of green plants came from water, were performed by Hill in 1937 and 1939. He showed that isolated chloroplasts give off oxygen in the presence of unnatural reducing agents like iron oxalate, ferricyanide or benzoquinone after exposure to light. The Hill reaction is
Artificial photosynthesis is usually a consequence in many of the tested systems after a period of exposure to light, bio-inspired photoprotectants have been tested, such as carotenoids (which are used in photosynthesis as natural protectants). Photoelectrochemical cells are a heterogeneous system that use light to produce either electricity or hydrogen. The vast majority of photoelectrochemical cells use semiconductors as catalysts. There have been attempts to use synthetic manganese complex-impregnated Nafion as a working electrode, but it has been since shown that the catalytically active species is actually the broken-down complex. A promising, emerging type of solar cell is the dye-sensitized solar cell.