Free-radical halogenation distribution". For propane and higher alkanes, the hydrogen atoms which form part of CH (or CH) groups are preferentially replaced. The reactivity of the different halogens varies considerably. The relative rates are: fluorine (108) > chlorine (1) > bromine (7 × 10) > iodine (2 × 10). Hence, the reaction of alkanes with fluorine is difficult to control, that with chlorine is moderate to fast, that with bromine is slow and requires high levels of UV irradiation while the reaction with iodine is practically nonexistent and thermodynamically unfavorable. A common method in organic synthesis employing is the Wohl–Ziegler reaction, which
Bromine production in the United States rail access, and difficult highway access, and was shut down in 1945. Dow found a better permanent location at Freeport, Texas, where a seawater extraction plant started in 1940, and a second in 1943. The Freeport plants recovered magnesium, sodium compounds, and chlorine, in addition to the bromine. The Freeport chemical operations are still active, but they stopped extracting bromine in 1969. Brine mining Bromine production in the United States Bromine production in the United States of 225,000 tonnes in 2013 made that country the second-largest producer of bromine, after Israel. The US supplied 29 percent of world production. Since