Work (thermodynamics) of the energy went out as heat, and how much as work. This can be summarized by saying that heat and work are not state functions of the system. This is in contrast to classical mechanics, where net work exerted by a particle is a state function. Pressure–volume work (or "PV" work) occurs when the volume of a system changes. "PV" work is often measured in units of litre-atmospheres where = . However, the litre-atmosphere is not a recognised unit in the SI system of units, which measures P in Pascal (Pa), V in m, and PV in Joule (J),
Work function of the emitter. Excess photon energy results in a liberated electron with non-zero kinetic energy. It is expected that the minimum photon energy formula_7 required to liberate an electron (and generate a current) is where "W" is the work function of the emitter. Photoelectric measurements require a great deal of care, as an incorrectly designed experimental geometry can result in an erroneous measurement of work function. This may be responsible for the large variation in work function values in scientific literature. Moreover, the minimum energy can be misleading in materials where there are no actual electron states at the Fermi