Fluorine in annual revenue. Due to the danger from direct hydrocarbon–fluorine reactions above −150 °C (−240 °F), industrial fluorocarbon production is indirect, mostly through halogen exchange reactions such as Swarts fluorination, in which chlorocarbon chlorines are substituted for fluorines by hydrogen fluoride under catalysts. Electrochemical fluorination subjects hydrocarbons to electrolysis in hydrogen fluoride, and the Fowler process treats them with solid fluorine carriers like cobalt trifluoride. Halogenated refrigerants, termed Freons in informal contexts, are identified by R-numbers that denote the amount of fluorine, chlorine, carbon, and hydrogen present. Chlorofluorocarbons (CFCs) like R-11, R-12, and R-114 once dominated organofluorines, peaking in production
Compounds of fluorine a diverse set of organic compounds. For many elements (but not all) the highest known oxidation state can be achieved in a fluoride. For some elements this is achieved exclusively in a fluoride, for others exclusively in an oxide; and for still others (elements in certain groups) the highest oxidation states of oxides and fluorides are always equal. While an individual fluorine atom has one unpaired electron, molecular fluorine (F) has all the electrons paired. This makes it diamagnetic (slightly repelled by magnets) with the magnetic susceptibility of −1.2×10 (SI), which is close to theoretical predictions. In contrast, the diatomic