Tropospheric ozone concentration at the tropopause. About 90% of total ozone in the atmosphere is in the stratosphere, and 10% is in the troposphere. Although tropospheric ozone is less concentrated than stratospheric ozone, it is of concern because of its health effects. Ozone in the troposphere is considered a greenhouse gas, and may contribute to global warming. Photo-chemical and chemical reactions involving ozone drive many of the chemical processes that occur in the troposphere by day and by night. At abnormally high concentrations (the largest source being emissions from combustion of fossil fuels), it is a pollutant, and a constituent of smog.
Atmosphere of Mars Express has shown the presence of two distinct ozone layers at low-to-mid latitudes. These comprise a persistent, near-surface layer below an altitude of 30 km, a separate layer that is only present in northern spring and summer with an altitude varying from 30 to 60 km, and another separate layer that exists 40–60 km above the southern pole in winter, with no counterpart above the Mars's north pole. This third ozone layer shows an abrupt decrease in elevation between 75 and 50 degrees south. SPICAM detected a gradual increase in ozone concentration at 50 km until midwinter, after which it