Asphyxiant gas can smell the odorants, and assigning a different smell to each gas may be impractical. Another difficulty is that most odorants (e.g., the thiols) are chemically reactive. This is not a problem with natural gas intended to be burned as fuel, which is routinely odorized, but a major use of asphyxiants such as nitrogen, helium, argon and krypton is to protect reactive materials from the atmosphere. The dangers of excess concentrations of nontoxic gases has been recognized for centuries within the mining industry. The concept of black damp (or "stythe") reflects an understanding that certain gaseous mixtures could lead to
Inert gas oxygen content of the tank atmosphere below 5% (on crude carriers, less for product carriers and gas tankers), thus making any air/hydrocarbon gas mixture in the tank too rich (too high a fuel to oxygen ratio) to ignite. IG is most important during discharging and during the ballast voyage when more hydrocarbon vapour is likely to be present in the tank atmosphere. Inert gas can also be used to purge the tank of the volatile atmosphere in preparation for gas freeing - replacing the atmosphere with breathable air - or vice versa. The flue gas system uses the boiler exhaust