Work (thermodynamics) of the energy went out as heat, and how much as work. This can be summarized by saying that heat and work are not state functions of the system. This is in contrast to classical mechanics, where net work exerted by a particle is a state function. Pressure–volume work (or "PV" work) occurs when the volume of a system changes. "PV" work is often measured in units of litre-atmospheres where = . However, the litre-atmosphere is not a recognised unit in the SI system of units, which measures P in Pascal (Pa), V in m, and PV in Joule (J),
Conservation of energy the heat energy may be written where formula_21 is the temperature and formula_22 is a small change in the entropy of the system. Temperature and entropy are variables of state of a system. If an open system (in which mass may be exchanged with the environment) has several walls such that the mass transfer is through rigid walls separate from the heat and work transfers, then the first law may be written: where formula_24 is the added mass and formula_25 is the internal energy per unit mass of the added mass, measured in the surroundings before the process. The conservation