Tennessine 17 in the periodic table, below the five halogens; fluorine, chlorine, bromine, iodine, and astatine, each of which has seven valence electrons with a configuration of . For tennessine, being in the seventh period (row) of the periodic table, continuing the trend would predict a valence electron configuration of , and it would therefore be expected to behave similarly to the halogens in many respects that relate to this electronic state. However, going down group 17, the metallicity of the elements increases; for example, iodine already exhibits a metallic luster in the solid state, and astatine is often classified as
Bromine thought that they could not exist at all. Dibromine monoxide is a dark-brown solid which, while reasonably stable at −60 °C, decomposes at its melting point of −17.5 °C; it is useful in bromination reactions and may be made from the low-temperature decomposition of bromine dioxide in a vacuum. It oxidises iodine to iodine pentoxide and benzene to 1,4-benzoquinone; in alkaline solutions, it gives the hypobromite anion. So-called "bromine dioxide", a pale yellow crystalline solid, may be better formulated as bromine perbromate, BrOBrO. It is thermally unstable above −40 °C, violently decomposing to its elements at 0 °C. Dibromine trioxide,