Atmosphere of Earth years ago. About 3.4 billion years ago, nitrogen formed the major part of the then stable "second atmosphere". The influence of life has to be taken into account rather soon in the history of the atmosphere, because hints of early life-forms appear as early as 3.5 billion years ago. How Earth at that time maintained a climate warm enough for liquid water and life, if the early Sun put out 30% lower solar radiance than today, is a puzzle known as the "faint young Sun paradox". The geological record however shows a continuous relatively warm surface during the complete early
Atmosphere of Earth record of Earth's dynamic oxygenation evolution. These fluctuations in oxygenation were likely driven by the Lomagundi carbon isotope excursion. The constant re-arrangement of continents by plate tectonics influences the long-term evolution of the atmosphere by transferring carbon dioxide to and from large continental carbonate stores. Free oxygen did not exist in the atmosphere until about 2.4 billion years ago during the Great Oxygenation Event and its appearance is indicated by the end of the banded iron formations. Before this time, any oxygen produced by photosynthesis was consumed by oxidation of reduced materials, notably iron. Molecules of free oxygen did not