Compounds of fluorine heavier halogens (chlorine, bromine, and iodine) all form mono-, tri-, and pentafluorides: XF, XF, and XF. Of the neutral +7 species, only iodine heptafluoride is known. While chlorine and bromine heptafluorides are not known, the corresponding cations and , extremely strong oxidizers, are. Astatine is not well-studied, and although there is a report of a non-volatile astatine monofluoride, its existence is debated. Many of the halogen fluorides are powerful fluorinators. Chlorine trifluoride is particularly noteworthy—readily fluorinating asbestos and refractory oxides—and may be even more reactive than chlorine pentafluoride. Used industrially, ClF requires special precautions similar to those for fluorine gas
Fluorine perchlorate Fluorine perchlorate Perchloryl Hypofluorite is the rarely encountered chemical compound of fluorine, chlorine, and oxygen with the chemical formula or . It is an extremely unstable gas that explodes spontaneously and has a penetrating odor. One synthesis uses fluorine and perchloric acid, though the action of ClF on water is another method. Another method of synthesis involves the thermal decomposition of tetrafluoroammonium perchlorate, , which yields very pure that may be manipulated and frozen without explosions. Fluorine perchlorate is not analogous to perchloric acid because the fluorine atom does not exist as a positive ion. It contains an oxygen atom