Budd–Michelin rubber-tired rail cars remained obscure in comparison with other competitors for the title, such as the "Pioneer Zephyr" and Union Pacific's M-10000. Rubber-tired rail cars achieved greater success in France, and similar rubber-tired subway cars have been adopted in Canada and Mexico as well as on numerous systems in Europe. During the 1920s, the American Budd Company, at the time a relatively obscure auto-frame supplier, developed an extensive working relationship with the French firm Michelin, which was best known for its tires. In 1929, Michelin built its first rail car, and by 1932 nine of its cars were in operating service, all of
Natural rubber melt the crystals. Vulcanization of rubber creates di- and polysulfide bonds between chains, which limits the degrees of freedom and results in chains that tighten more quickly for a given strain, thereby increasing the elastic force constant and making the rubber harder and less extensible. Raw rubber storage depots and rubber processing can produce malodour that is serious enough to become a source of complaints and protest to those living in the vicinity. Microbial impurities originate during the processing of block rubber. These impurities break down during storage or thermal degradation and produce volatile organic compounds. Examination of these compounds