Marie Curie doubt, the Curies sought to isolate polonium and radium in pure form. Pitchblende is a complex mineral; the chemical separation of its constituents was an arduous task. The discovery of polonium had been relatively easy; chemically it resembles the element bismuth, and polonium was the only bismuth-like substance in the ore. Radium, however, was more elusive; it is closely related chemically to barium, and pitchblende contains both elements. By 1898 the Curies had obtained traces of radium, but appreciable quantities, uncontaminated with barium, were still beyond reach. The Curies undertook the arduous task of separating out radium salt by differential
Chalcogen and Pierre Curie discovered that a sample of pitchblende was emitting four times as much radioactivity as could be explained by the presence of uranium alone. The Curies gathered several tons of pitchblende and refined it for several months until they had a pure sample of polonium. The discovery officially took place in 1898. Prior to the invention of particle accelerators, the only way to create polonium was to extract it over several months from uranium ore. The first attempt at creating livermorium was from 1976 to 1977 at the LBNL, who bombarded curium-248 with calcium-48, but were not successful.