Marie Curie doubt, the Curies sought to isolate polonium and radium in pure form. Pitchblende is a complex mineral; the chemical separation of its constituents was an arduous task. The discovery of polonium had been relatively easy; chemically it resembles the element bismuth, and polonium was the only bismuth-like substance in the ore. Radium, however, was more elusive; it is closely related chemically to barium, and pitchblende contains both elements. By 1898 the Curies had obtained traces of radium, but appreciable quantities, uncontaminated with barium, were still beyond reach. The Curies undertook the arduous task of separating out radium salt by differential
Polonium a volatile liquid at room temperature prone to dissociation; it is thermally unstable. Water is the only other known hydrogen chalcogenide which is a liquid at room temperature; however, this is due to hydrogen bonding. The two oxides PoO and PoO are the products of oxidation of polonium. Halides of the structure PoX, PoX and PoF are known. They are soluble in the corresponding hydrogen halides, i.e., PoCl in HCl, PoBr in HBr and PoI in HI. Polonium dihalides are formed by direct reaction of the elements or by reduction of PoCl with SO and with PoBr with HS at