Marie Curie was present in such minute quantities that they would eventually have to process tons of the ore. In July 1898, Curie and her husband published a joint paper announcing the existence of an element which they named "polonium", in honour of her native Poland, which would for another twenty years remain partitioned among three empires (Russian, Austrian, and Prussian). On 26 December 1898, the Curies announced the existence of a second element, which they named "radium", from the Latin word for "ray". In the course of their research, they also coined the word "radioactivity". To prove their discoveries beyond any
Polonium dichloride by dehalogenation of polonium tetrachloride, PoCl. Methods for dehalogenating PoCl include thermal decomposition at 300 °C, reduction of cold, slightly moist PoCl by sulfur dioxide; and heating PoCl in a stream of carbon monoxide or hydrogen sulfide at 150 °C. PoCl dissolves in dilute hydrochloric acid to give a pink solution, which autoxidises to Po(IV). PoCl is rapidly oxidised by hydrogen peroxide or chlorine water. Addition of potassium hydroxide to the pink solution results in a dark brown precipitate – possibly hydrated PoO or Po(OH) – which is rapidly oxidised to Po(IV). With dilute nitric acid, PoCl forms a dark