Polonium the Curies while they were investigating the cause of pitchblende radioactivity. Pitchblende, after removal of the radioactive elements uranium and thorium, was more radioactive than the uranium and thorium combined. This spurred the Curies to search for additional radioactive elements. They first separated out polonium from pitchblende in July 1898, and five months later, also isolated radium. German scientist Willy Marckwald successfully isolated 3 milligrams of polonium in 1902, though at the time he believed it was a new element, which he dubbed "radio-tellurium", and it was not until 1905 that it was demonstrated to be the same as polonium.
Polonium tetrachloride Polonium tetrachloride forms a complex with two moles of tributyl phosphate. Like selenium tetrachloride and tellurium tetrachloride, polonium tetrachloride forms and halogen complexes. Polonium tetrachloride Polonium tetrachloride (also known as polonium(IV) chloride) is a chemical compound with the formula PoCl. It is a hygroscopic bright yellow crystalline solid at room temperature. Above 200 °C, it tends to decompose into polonium dichloride and excess chlorine, similar to selenium tetrachloride and tellurium tetrachloride. Polonium tetrachloride is either monoclinic or triclinic. Polonium tetrachloride is bright yellow at room temperature. At its melting point (300 °C), it becomes straw yellow, and at its boiling