Polonium the Curies while they were investigating the cause of pitchblende radioactivity. Pitchblende, after removal of the radioactive elements uranium and thorium, was more radioactive than the uranium and thorium combined. This spurred the Curies to search for additional radioactive elements. They first separated out polonium from pitchblende in July 1898, and five months later, also isolated radium. German scientist Willy Marckwald successfully isolated 3 milligrams of polonium in 1902, though at the time he believed it was a new element, which he dubbed "radio-tellurium", and it was not until 1905 that it was demonstrated to be the same as polonium.
Polonium dichloride by dehalogenation of polonium tetrachloride, PoCl. Methods for dehalogenating PoCl include thermal decomposition at 300 °C, reduction of cold, slightly moist PoCl by sulfur dioxide; and heating PoCl in a stream of carbon monoxide or hydrogen sulfide at 150 °C. PoCl dissolves in dilute hydrochloric acid to give a pink solution, which autoxidises to Po(IV). PoCl is rapidly oxidised by hydrogen peroxide or chlorine water. Addition of potassium hydroxide to the pink solution results in a dark brown precipitate – possibly hydrated PoO or Po(OH) – which is rapidly oxidised to Po(IV). With dilute nitric acid, PoCl forms a dark