Polonium the Curies while they were investigating the cause of pitchblende radioactivity. Pitchblende, after removal of the radioactive elements uranium and thorium, was more radioactive than the uranium and thorium combined. This spurred the Curies to search for additional radioactive elements. They first separated out polonium from pitchblende in July 1898, and five months later, also isolated radium. German scientist Willy Marckwald successfully isolated 3 milligrams of polonium in 1902, though at the time he believed it was a new element, which he dubbed "radio-tellurium", and it was not until 1905 that it was demonstrated to be the same as polonium.
Modulated neutron initiator particle bombardment, the beryllium atoms emit neutrons at a rate of about 1 neutron each 5–10 nanoseconds (See Beryllium#Nuclear properties). These neutrons trigger the chain reaction in the compressed supercritical plutonium. Placing the polonium layer between two large masses of beryllium ensures contact of the metals even if the shock wave turbulence performs poorly. The 50 curies of polonium generated about 0.1 watts of decay heat, noticeably warming the small sphere. The grooves in the inner surface of the shell shaped the shock wave into jets by the Munroe effect, similar to a shaped charge, for fast and thorough mixing