Quadruple bond electrons (σπδδ*) has an Os–Os triple bond and a staggered geometry. Many other compounds with quadruple bonds between transition metal atoms have been described, often by Cotton and his coworkers. Isoelectronic with the dirhenium compound is the salt K[MoCl] (potassium octachlorodimolybdate). An example of a ditungsten compound with a quadruple bond is ditungsten tetra(hpp). Quadruple bonds between atoms of main group elements are unknown. Molecular orbital theory shows that there are two sets of paired electrons in the sigma system (one bonding, one antibonding), and two sets of paired electrons in a degenerate π-bonding set of orbitals. This adds up
Owned-and-operated television stations in the United States Westinghouse to trade its NBC-affiliated Philadelphia cluster of KYW-AM (1060) and WPTZ-TV (channel 3) to NBC in exchange for WTAM-AM-FM and WNBK-TV in Cleveland. Westinghouse only agreed to the trade after NBC threatened not only to yank its programming from WPTZ, but also Westinghouse-owned WBZ-TV (channel 4) in Boston. NBC changed the callsigns of the Philadelphia stations to WRCV-AM-TV, while Westinghouse changed the Cleveland stations' callsigns to KYW-AM-FM-TV. NBC's then-ownership of Philadelphia's channel 3 was cited by CBS when it purchased its then-affiliate WCAU-TV in 1958, despite FCC rules at the time barring companies from owning stations with overlapping signals,