Quadruple bond Quadruple bond A quadruple bond is a type of chemical bond between two atoms involving eight electrons. This bond is an extension of the more familiar types double bonds and triple bonds. Stable quadruple bonds are most common among the transition metals in the middle of the d-block, such as rhenium, tungsten, molybdenum and chromium. Typically the ligands that support quadruple bonds are π-donors, not π-acceptors. Chromium(II) acetate, Cr("μ"-OCCH)(HO), was the first chemical compound containing a quadruple bond to be synthesized. It was described in 1844 by E. Peligot, although its distinctive bonding was not recognized for more than a
Quadruple-precision floating-point format the double-double technique above, although that technique does not implement IEEE quadruple precision), since direct hardware support for quadruple precision is, as of 2016, less common (see "Hardware support" below). One can use general arbitrary-precision arithmetic libraries to obtain quadruple (or higher) precision, but specialized quadruple-precision implementations may achieve higher performance. A separate question is the extent to which quadruple-precision types are directly incorporated into computer programming languages. Quadruple precision is specified in Fortran by the codice_2 (module codice_3 from Fortran 2008 must be used, the constant codice_4 is equal to 16 on most processors), or as codice_5, or in