Marie Curie doubt, the Curies sought to isolate polonium and radium in pure form. Pitchblende is a complex mineral; the chemical separation of its constituents was an arduous task. The discovery of polonium had been relatively easy; chemically it resembles the element bismuth, and polonium was the only bismuth-like substance in the ore. Radium, however, was more elusive; it is closely related chemically to barium, and pitchblende contains both elements. By 1898 the Curies had obtained traces of radium, but appreciable quantities, uncontaminated with barium, were still beyond reach. The Curies undertook the arduous task of separating out radium salt by differential
Polonium dioxide the scarcity of polonium in nature and the high temperatures (250 °C) required to form the dioxide. Polonium dioxide is prepared by reacting elemental polonium with oxygen at 250 °C or by thermal decomposition of polonium(IV) hydroxide (PoO(OH)), polonium disulfate (Po(SO)), polonium selenate (Po(SeO)), or polonium tetranitrate (Po(NO)). When placed in hydrogen, polonium dioxide is slowly reduced to metallic polonium at 200 °C; the same reduction occurs at 250 °C in ammonia or hydrogen sulfide. When heated in sulfur dioxide at 250 °C, a white compound is formed, possibly a polonium sulfite. When polonium dioxide is hydrated, polonous acid (HPoO),