Polonium the Curies while they were investigating the cause of pitchblende radioactivity. Pitchblende, after removal of the radioactive elements uranium and thorium, was more radioactive than the uranium and thorium combined. This spurred the Curies to search for additional radioactive elements. They first separated out polonium from pitchblende in July 1898, and five months later, also isolated radium. German scientist Willy Marckwald successfully isolated 3 milligrams of polonium in 1902, though at the time he believed it was a new element, which he dubbed "radio-tellurium", and it was not until 1905 that it was demonstrated to be the same as polonium.
Polonium hydride and hydrogen selenide, and decomposes into its constituent elements, releasing heat in the process. The amount of heat given off in the decomposition of polonium hydride is over 100 kJ/mol, the largest of all the hydrogen chalcogenides. Polonium hydride is a liquid due to van der Waals forces, and not due to the same reason as why water (hydrogen oxide) is liquid (hydrogen bonding). It is predicted that, like the other hydrogen chalcogenides, polonium may form two types of salts: polonide (containing the Po anion) and one from polonium hydride (containing –PoH, which would be the polonium analogue of thiol,