Quadruple bond electrons (σπδδ*) has an Os–Os triple bond and a staggered geometry. Many other compounds with quadruple bonds between transition metal atoms have been described, often by Cotton and his coworkers. Isoelectronic with the dirhenium compound is the salt K[MoCl] (potassium octachlorodimolybdate). An example of a ditungsten compound with a quadruple bond is ditungsten tetra(hpp). Quadruple bonds between atoms of main group elements are unknown. Molecular orbital theory shows that there are two sets of paired electrons in the sigma system (one bonding, one antibonding), and two sets of paired electrons in a degenerate π-bonding set of orbitals. This adds up
Owned-and-operated television stations in the United States (channel 2) to Fox. CBS then unsuccessfully sought to affiliate with other stations in the market before it eventually purchased low-rated ethnic independent WGPR-TV (channel 62) and changed the station's callsign to WWJ-TV (a callsign once used by one of the stations that CBS approached for an affiliation, WDIV-TV) in 1995. The station continues to receive low ratings, and after a brief attempt at running an 11:00 p.m. newscast from 2001 to 2002 that was produced by sister station WKBD-TV (which voluntarily shut down its news department shortly afterward to enter into a short-lived news share agreement with WXYZ-TV), was