Quadruple bond electrons (σπδδ*) has an Os–Os triple bond and a staggered geometry. Many other compounds with quadruple bonds between transition metal atoms have been described, often by Cotton and his coworkers. Isoelectronic with the dirhenium compound is the salt K[MoCl] (potassium octachlorodimolybdate). An example of a ditungsten compound with a quadruple bond is ditungsten tetra(hpp). Quadruple bonds between atoms of main group elements are unknown. Molecular orbital theory shows that there are two sets of paired electrons in the sigma system (one bonding, one antibonding), and two sets of paired electrons in a degenerate π-bonding set of orbitals. This adds up
Quadruple-precision floating-point format Quadruple-precision floating-point format In computing, quadruple precision (or quad precision) is a binary floating-point-based computer number format that occupies 16 bytes (128 bits) in with precision more than twice the 53-bit double precision. This 128-bit quadruple precision is designed not only for applications requiring results in higher than double precision, but also, as a primary function, to allow the computation of double precision results more reliably and accurately by minimising overflow and round-off errors in intermediate calculations and scratch variables. William Kahan, primary architect of the original IEEE-754 floating point standard noted, "For now the 10-byte Extended format is a