Quadruple bond electrons (σπδδ*) has an Os–Os triple bond and a staggered geometry. Many other compounds with quadruple bonds between transition metal atoms have been described, often by Cotton and his coworkers. Isoelectronic with the dirhenium compound is the salt K[MoCl] (potassium octachlorodimolybdate). An example of a ditungsten compound with a quadruple bond is ditungsten tetra(hpp). Quadruple bonds between atoms of main group elements are unknown. Molecular orbital theory shows that there are two sets of paired electrons in the sigma system (one bonding, one antibonding), and two sets of paired electrons in a degenerate π-bonding set of orbitals. This adds up
Owned-and-operated television stations in the United States order to stay under the ownership cap. In addition, networks may choose to sell off O&Os in smaller markets in order to concentrate on their stations in larger markets, or to give themselves leeway to purchase stations in other growing markets. The following are examples of transactions involving owned-and-operated stations in the United States: The DuMont network found itself in financial trouble in 1954, and decided to sell off its Pittsburgh owned-and-operated station, WDTV (channel 2), which was the only commercial VHF station in what was then a top ten television market in the United States. Westinghouse Electric Corporation bought