Marie Curie doubt, the Curies sought to isolate polonium and radium in pure form. Pitchblende is a complex mineral; the chemical separation of its constituents was an arduous task. The discovery of polonium had been relatively easy; chemically it resembles the element bismuth, and polonium was the only bismuth-like substance in the ore. Radium, however, was more elusive; it is closely related chemically to barium, and pitchblende contains both elements. By 1898 the Curies had obtained traces of radium, but appreciable quantities, uncontaminated with barium, were still beyond reach. The Curies undertook the arduous task of separating out radium salt by differential
Polonium hydride and hydrogen selenide, and decomposes into its constituent elements, releasing heat in the process. The amount of heat given off in the decomposition of polonium hydride is over 100 kJ/mol, the largest of all the hydrogen chalcogenides. Polonium hydride is a liquid due to van der Waals forces, and not due to the same reason as why water (hydrogen oxide) is liquid (hydrogen bonding). It is predicted that, like the other hydrogen chalcogenides, polonium may form two types of salts: polonide (containing the Po anion) and one from polonium hydride (containing –PoH, which would be the polonium analogue of thiol,