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The answer is 20. Duplicated chromosome has two sister chromatids, identical copies of the chromosome. These two chromatids are joined at the region called centromere. Therefore, one duplicated chromosome has one centromere and two sister chromatids. If there are 20 duplicated chromosomes in a cell, there will be 20 centromeres.
During prophase and metaphase of mitosis, each chromosome exists in the above state. For humans, this means that during prophase and metaphase of mitosis, a human will have 46 chromosomes, but 92 chromatids (again, remember that there are 92 chromatids because the original 46 chromosomes were duplicated during S phase of interphase).