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XLS files are Excel workbook files created in Excel 97 or Excel 2003. The 2007, 2010 and 2013 versions of the program use the XLSX format by default to save workbooks, but can also use the XLS format. You can edit XLS spreadsheets you received from your customers or employees in Excel 2013 and save them as XLSX or XLS files.
The .xlsx and .xlsm formats store almost all components of the workbook in XML format, i.e. specially formatted text. This makes it easy for other programs to read and even manipulate the contents of the workbook without having to start Excel. The .xlsb format stores the core components of the workbook in binary format. You need Excel to read and edit it. So the .xlsx and .xlsm formats are more open. For small and medium-sized workbooks, the difference in size and in reading/writing speed between .xlsx/.xlsm on the one hand, and .xlsb on the other hand, are not significant.