Bohemian style. In modern usage, the term Bohemian is applied to people who live unconventional, usually artistic, lives. The adherents of the Bloomsbury Group, which formed around the Stephen sisters, Vanessa Bell and Virginia Woolf in the early 20th century, are among the best-known examples.
up vote 31 down vote. The phosphate group in NADPH doesn't affect the redox abilities of the molecule, it is too far away from the part of the molecule involved in the electron transfer. What the phosphate group does is to allow enzymes to discriminate between NADH and NADPH, which allows the cell to regulate both independently.
NADPH and that electrons are removed from water and passed through a pathway that does not return them; they end up as part of NADPH (which is reduced), thus the pathway is noncyclic electron flow. ATP formation during the light reactions.