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Stomach upset - Aspirin can upset a dog's stomach, which can interfere with the ultimate goal of relieving your dog's pain if he throws up the medication. Buffered aspirin is usually easier on a dog's stomach than non-buffered aspirin, especially if your vet advises you to give repeated doses.
Giving your dog the correct dose of aspirin is critically important because an overdose, even a small one, could have disastrous consequences. The recommend aspirin dosage for dogs is. 5 - 10mg per pound of body weight (10 is the maximum!) This can be given twice a day, that's one dose per 12 hours.