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As in the arteries, the walls of veins have three layers, or coats: an inner layer, or tunica intima; a middle layer, or tunica media; and an outer layer, or tunica adventitia. Each coat has a number of sublayers.
The walls of arteries and veins are composed of endothelial cells, smooth muscle cells and extracellular matrix (including collagen and elastin).These are arranged into three concentric layers: intima, media and adventitia. The intima is the inner layer abutting the vessel lumen.he walls of arteries and veins are composed of endothelial cells, smooth muscle cells and extracellular matrix (including collagen and elastin).