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Stomach upset - Aspirin can upset a dog's stomach, which can interfere with the ultimate goal of relieving your dog's pain if he throws up the medication. Buffered aspirin is usually easier on a dog's stomach than non-buffered aspirin, especially if your vet advises you to give repeated doses.
More websites say yes, you can give aspirin to mature dogs. But it cannot be given it to puppies or dogs that are 5 pounds or less. Dose it at 5-10mg per pound to be conservative and no more than 200mg, twice daily.