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Spinach and other leafy greens high in vitamin C are imperative for the building and maintenance of collagen, which provides structure to skin and hair. Iron-deficiency is a common cause of hair loss, which can be prevented by an adequate intake of iron-rich foods, like spinach.
Plants have always been a main source of minerals for humans. When you eat raw spinach, for example, it contains tiny amounts of iron, calcium, magnesium, zinc, copper, and selenium (source). But... the zinc found in spinach is drastically different than zinc mined from the earth or found in sea water. When the spinach plant absorbs the zinc from the soil, it changes the molecular structure of this rock. By adding a few molecules, the zinc goes from a ionic compound to a covalent compound.