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Stomach upset - Aspirin can upset a dog's stomach, which can interfere with the ultimate goal of relieving your dog's pain if he throws up the medication. Buffered aspirin is usually easier on a dog's stomach than non-buffered aspirin, especially if your vet advises you to give repeated doses.
Aspirin Uses, Administration and Dosage for Dogs: Dogs Health care Articles; Usage: Dogs are most commonly given aspirin for treatment of arthritis and associated joint pain. There may be other situations where your dog is in pain, where aspirin may give relief.