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Adjunct means something added on, but not part of the whole. An adjunct professor is someone who is hired by a college to teach but isn't a full member of the faculty. This is a word you can figure out by taking it apart. From ad- to and -junct join (think junction), you can see that this is about joining something to another. During lunch, Tim always sat the girls' lacrosse-team lunch table, and they joked that he was an adjunct member of the team.. Definitions of adjunct.
Enhancer or Enhancement. From the word enhance: to make greater, as in value, beauty, or effectiveness; augment; to provide with improved, advanced, or sophisticated features. This would satisfy the request for a word that applies to something that adds value to something else. But I don't think I've heard it used to apply to a person who adds to the value of something. I believe that the words adjunct and adjunctive could be used to express the concept of someone or something that adds value to someone or something else.