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Gas chromatographyâmass spectrometry (GCâMS) was used to identify volatile and semivolatile organic compounds generated by the thermal degradation reactions. The main aim of this paper has been to propose two models to describe the pyrolysis and combustion degradation of flexible polyurethane foam (FPUF) wastes. In order to obtain a single set of kinetic parameters for pyrolysis and combustion, a wide range of runs were performed in each condition.