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An animation demonstrating the relationship between volume and temperature. Charles's law (also known as the law of volumes) is an experimental gas law which describes how gases tend to expand when heated. A modern statement of Charles's law is.
Charlesâs Law states that at constant pressure, the volume of a given sample of a gas is? directly proportional to the absolute (or Kelvin) temperature. Suppose a sample of oxygen has a volume of 135. mL at a temperature of 50.0ÂºC.