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Depending on how cooked you like your hard boiled eggs, the eggs should be done perfectly in 10-12 minutes. That said, depending on your altitude, the shape of the pan, the size of the eggs, the ratio of water to eggs, it can take a few minutes more.
You heat the vinegar with the pickling spices to get the flavours marrying, then pour over top the hard-boiled, peeled onions in the jar. It is best to start with eggs that are at least two to three weeks old, so they will peel more easily -- the shell tends to stick to very fresh eggs when they are hard-boiled.