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In this case they are n-hexane, 2-methylpentane, 3-methylpentane, 2,2-dimethylbutane, and 2,3-dimethylbutane. Any formula that goes by CnH2n+2 is an alkane. There isn't a formula you can use to find out how many isomers there are for any given class of molecules with a specified number of carbons. You just have to think very systematically when you try to find them all.
n-Heptane is the straight-chain alkane with the chemical formula H3C(CH2)5CH3 or C7H16. When used as a test fuel component in anti-knock test engines, a 100% heptane fuel is the zero point of the octane rating scale (the 100 point is a 100% iso-octane).