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Opioid analgesics, in general, are the strongest pain-relieving medications. The benchmark drug in this class is morphine -- with other opioids falling above or below it in terms of pain-relieving potential.
The Fioricet with Codeine should probably work better then the regular Fioricet, since Codeine is an opiate and opiates tend to be very strong pain killers. I hope that it works better for you than the regular Fioricet. Neurotin is a very powerful pain preventative medication.