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The painful, burning sensation is caused by rising stomach acid. It moves from your stomach, where the lining is resistant to its corrosive effects, up into your esophagus, the lining of which is not similarly protected. It can climb all the way from the bottom of the esophagus all the way up into the throat.
This can lead to heartburn, which is the burning sensation caused by the acid inflaming the esophagus. The esophagus is a tubular pipe connecting the mouth to the stomach. As its located behind the rib cage, this can often cause pain in the chest area.