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Sweet Bell type peppers are can be harvested when firm and full size (at least 3 1/2 to 4 inches) but still green. If left to ripen, they may also turn red, yellow, orange, purple or even chocolate-colored depending on the cultivar. The less green you see, the sweeter the taste in both sweet and hot peppers.
steph New Seed. I have several bell pepper plants that have fruit already on them, but are getting brown before they mature. These are actually sweet red bell peppers and at first I just thought they were beginning to turn red, but it looks more like the color of bread crust. One pepper has one whole side that looks that way and others have spots toward the bottom of them.