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Sweet Bell type peppers are can be harvested when firm and full size (at least 3 1/2 to 4 inches) but still green. If left to ripen, they may also turn red, yellow, orange, purple or even chocolate-colored depending on the cultivar. The less green you see, the sweeter the taste in both sweet and hot peppers.
If left on the vine to ripen further, green peppers may turn red, then orange to yellow. Purple varieties will turn from green to dark purple or nearly black. Bell peppers can be eaten at any stage during this ripening process, and they will become sweeter in taste the longer they are left on the vine. Cut peppers from the vine, leaving the stem attached to the fruit. Ripe peppers may detach easily from the plant stem with a gentle twist.