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Sweet Bell type peppers are can be harvested when firm and full size (at least 3 1/2 to 4 inches) but still green. If left to ripen, they may also turn red, yellow, orange, purple or even chocolate-colored depending on the cultivar. The less green you see, the sweeter the taste in both sweet and hot peppers.
1 Hot peppers may be harvested at any stage. Anaheim is usually picked green and cayenne types red. 2  Bell peppers may be chopped and quick frozen for use in many recipes; sweet cherry and banana peppers and hot cherry peppers are perfect for pickling.  A popular and trouble-free way to store hot peppers is to dry them. String mature red peppers by piercing the stem with a needle and heavy thread. Hang the string in a warm, dry, airy place (not in the sun!) to dry. They can make a colorful kitchen accent.