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Sweet Bell type peppers are can be harvested when firm and full size (at least 3 1/2 to 4 inches) but still green. If left to ripen, they may also turn red, yellow, orange, purple or even chocolate-colored depending on the cultivar. The less green you see, the sweeter the taste in both sweet and hot peppers.
Usually the first peppers are ready to harvest 75 to 90 days from transplanting, but that will vary with differing growing conditions. Harvest can last into fall until frost. Size and color give you the best clues about when to harvest hot peppers and sweet peppers.