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Sweet Bell type peppers are can be harvested when firm and full size (at least 3 1/2 to 4 inches) but still green. If left to ripen, they may also turn red, yellow, orange, purple or even chocolate-colored depending on the cultivar. The less green you see, the sweeter the taste in both sweet and hot peppers.
This will depend on the variety of pepper you are growing and the weather, but most begin producing within 65 to 75 days from transplant. Harvest sweet peppers when they reach the preferred size or color. If you like green peppers, go ahead and pick them at any time. The more you pick, the more the plant will set.