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Sweet Bell type peppers are can be harvested when firm and full size (at least 3 1/2 to 4 inches) but still green. If left to ripen, they may also turn red, yellow, orange, purple or even chocolate-colored depending on the cultivar. The less green you see, the sweeter the taste in both sweet and hot peppers.
1 Harvest as soon as peppers reach desired size. 2  The longer bell peppers stay on the plant, the more sweet they become and the greater their Vitamin C content.  Use a sharp knife or scissors to cut peppers clean off the plant for the least damage.