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Sweet Bell type peppers are can be harvested when firm and full size (at least 3 1/2 to 4 inches) but still green. If left to ripen, they may also turn red, yellow, orange, purple or even chocolate-colored depending on the cultivar. The less green you see, the sweeter the taste in both sweet and hot peppers.
Freezing produce is a useful technique for preserving food when it is in season and at peak ripeness. While it is common to blanch peppers prior to freezing them, it is not necessary to preserve the green peppers' texture or flavor. You can freeze green peppers without blanching them, and this method can be a huge time-saver. Keep cleaned, sliced green peppers in your freezer to incorporate into stir-fries, soups and other dishes.