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Sweet Bell type peppers are can be harvested when firm and full size (at least 3 1/2 to 4 inches) but still green. If left to ripen, they may also turn red, yellow, orange, purple or even chocolate-colored depending on the cultivar. The less green you see, the sweeter the taste in both sweet and hot peppers.
So if you purchase green 'chili' pepper seed, and grow the plants, you will harvest 'chile' peppers for 'Chile rellenos'! Peppers are part of the Solanaceae or Nightshade family which contains over 2000 species of ornamental, medicinal and poisonous plants.eppers may be harvested and enjoyed when immature or mature. There is not a best time ti harvest, let personal taste preference be the guide. Remember that sweet peppers become sweeter as they mature and hot peppers come hotter. To harvest, do not pull or tear a pepper from a plant.