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Sweet Bell type peppers are can be harvested when firm and full size (at least 3 1/2 to 4 inches) but still green. If left to ripen, they may also turn red, yellow, orange, purple or even chocolate-colored depending on the cultivar. The less green you see, the sweeter the taste in both sweet and hot peppers.
When to Harvest Peppers. Peppers should be ready to harvest in approximately 70-80 days of ideal growing conditions. Sweet peppers are picked green, not fully ripe. They will feel firm and crisp when ready, and should not be pulled from the plant but cut with a sharp knife or pruning shears.