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Carbon is least electronegative so its attraction for electrons will be least so it will have a greater positive charge and alternatively fluorine will have a greater negative charge, so F-C bond is most polar. In F-N ,nitrogen will have lesser positive charge than carbon and fluorine will have a lesser negative charge as compared to in F-C and so on.
We have discussed how bonds can be both polar and nonpolar. These bonds also make the entire molecule polar or nonpolar. Again, it is the polarity that accounts for many of the properties that we see in molecules-most especially, melting and boiling points, as well as solubility.e can think of ionic bonds as being the most polar a bond can be. There is nothing more polar than the ends being different by a whole, complete electrical charge. If a molecule is made of polar bonds, it may be polar or nonpolar.