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The Default path for All Microsoft Office Outlook .pst file location is the User data(Your account name)/Local Settings/Application Data/Microsoft/Outlook/ this is where the .pst files are stored by default!!! this goes for All Windows OS! Tuesday, June 05, 2012 12:18 PM.
In Outlook 2013, you can no longer set a pst file as the delivery location for Exchange mailboxes. You will need to use rules to move all of your mail to a pst file.Alternately, you can use POP3, IMAP, or EAS.ith Outlook 2010, you can't set a pst as the delivery location when you first add the Exchange account to your profile. After the account is added and set up, you can switch the default to a pst file.