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The Default path for All Microsoft Office Outlook .pst file location is the User data(Your account name)/Local Settings/Application Data/Microsoft/Outlook/ this is where the .pst files are stored by default!!! this goes for All Windows OS! Tuesday, June 05, 2012 12:18 PM.
By default, Outlook 2010 automatically adds a new Outlook Data File (.pst) when you add a new POP3 account. However, earlier versions of Outlook let you select an existing Personal Folders file as the default delivery location.f the account is already configured to use the default settings, the default delivery location can be changed. To do this, access Account Settings, and then use the Change Folder option for the POP account. To change the Outlook Data File (.pst) that an existing account uses, follow these steps: