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The Default path for All Microsoft Office Outlook .pst file location is the User data(Your account name)/Local Settings/Application Data/Microsoft/Outlook/ this is where the .pst files are stored by default!!! this goes for All Windows OS! Tuesday, June 05, 2012 12:18 PM.
The fastest way to open the folder where your Outlook Data File (.pst and .ost) is saved is to do the following: In Outlook 2010, click the File tab. Click Account Settings, and then click Account Settings.On the Data Files tab, click an entry, and then click Open Folder Location.Outlook Data Files (.pst) created by using Outlook 2010 are saved on your computer in the Documents\Outlook Files folder.lick Account Settings, and then click Account Settings. On the Data Files tab, click an entry, and then click Open Folder Location. Outlook Data Files (.pst) created by using Outlook 2010 are saved on your computer in the Documents\Outlook Files folder.