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Magically speaking, Saltpeter has a long, long, long history in hoodoo as an agent of magical protection in spritual baths and floor washes and as a shoe-sprinkle. Also, because it is an ingredient in Gunpowder, it is used in formulae which are hoped to produce quick (explosive) action, such as Block-Buster.
Originally spelled saltpetre, this term could have referred to potassium nitrate, sodium nitrate, or even calcium nitrate, but it's main use was for potassium nitrate. Saltpetre comes from sal petre, which means salt of the rock..