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The Default path for All Microsoft Office Outlook .pst file location is the User data(Your account name)/Local Settings/Application Data/Microsoft/Outlook/ this is where the .pst files are stored by default!!! this goes for All Windows OS! Tuesday, June 05, 2012 12:18 PM.
You installed Outlook on a new computer or a new hard disk and are ready to start using your old data. Although you can keep your data files in any folder, this is the default location that Outlook uses when creating .pst files.