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Vitamin D Deficiency & Jaw Pain. Jaw pain may be related to a vitamin D deficiency. Photo Credit Digital Vision/Digital Vision/Getty Images. Many people suffer from jaw pain caused by problems with the temporomandibular joint, also known as TMJ, a joint located near your ear that allows your lower jaw to function.hile vitamin D supplementation may help symptoms of jaw pain, there's not enough clinical research to fully support its benefits. If you suffer from chronic jaw pain, see a dentist. A number of treatments can help your symptoms.
If you chew too much or subconsciously clench your jaws during stressful times, your jaw muscles can spasm and cause pain. Stress-induced clenching or grinding can cause slight misalignment of the jaw, leading to jaw, neck, or eye pain, as well as jackhammer-like headaches.