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Vitamin D Deficiency & Jaw Pain. Jaw pain may be related to a vitamin D deficiency. Photo Credit Digital Vision/Digital Vision/Getty Images. Many people suffer from jaw pain caused by problems with the temporomandibular joint, also known as TMJ, a joint located near your ear that allows your lower jaw to function.hile vitamin D supplementation may help symptoms of jaw pain, there's not enough clinical research to fully support its benefits. If you suffer from chronic jaw pain, see a dentist. A number of treatments can help your symptoms.
This tends to be especially true of jaw pain and most jaw and tooth discomfort. The association between anxiety and jaw pain isn't always obvious, but there are generally two causes: 1  Facial Tension All forms of facial tension may lead to jaw pain. 2  You may not realize you're tense either. 3  Hormones in the body can tense your muscles and joints even without any action from you.