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Vitamin D Deficiency & Jaw Pain. Jaw pain may be related to a vitamin D deficiency. Photo Credit Digital Vision/Digital Vision/Getty Images. Many people suffer from jaw pain caused by problems with the temporomandibular joint, also known as TMJ, a joint located near your ear that allows your lower jaw to function.hile vitamin D supplementation may help symptoms of jaw pain, there's not enough clinical research to fully support its benefits. If you suffer from chronic jaw pain, see a dentist. A number of treatments can help your symptoms.
Vitamin B. Vitamin B deficiencies can cause toothaches, receding gums and overall sensitivity of the mucous membranes in the mouth. Vitamin B complex supplements are best taken in the sublingual form--under the tongue--for optimal absorption. Food sources of the B vitamins include mushrooms, meat and fish.