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Binary files are usually thought of as being a sequence of bytes, which means the binary digits (bits) are grouped in eights. Binary files typically contain bytes that are intended to be interpreted as something other than text characters.
Part of the Programming glossary: A binary file is a file whose content must be interpreted by a program or a hardware processor that understands in advance exactly how it is formatted. That is, the file is not in any externally identifiable format so that any program that wanted to could look for certain data at a certain place within the file.