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activation energy. activation energy, in chemistry, minimum energy needed to cause a chemical reaction. A chemical reaction between two substances occurs only when an atom, ion, or molecule of one collides with an atom, ion, or molecule of the other.
The activation energy diagram is drawn as a hill because there is a large amount of energy needed to form the unstable transition state (viewed as the upward slope on the diagram). The difference between this peak energy and the rectants' energy is the activation energy.