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activation energy. activation energy, in chemistry, minimum energy needed to cause a chemical reaction. A chemical reaction between two substances occurs only when an atom, ion, or molecule of one collides with an atom, ion, or molecule of the other.
In this diagram, the activation energy is signified by the hump in the reaction pathway and is labeled. At the peak of the activation energy hump, the reactants are in the transition state, halfway between being reactants and forming products. This state is also known as an activated complex.