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activation energy. activation energy, in chemistry, minimum energy needed to cause a chemical reaction. A chemical reaction between two substances occurs only when an atom, ion, or molecule of one collides with an atom, ion, or molecule of the other.
The activation energy of complex reactions is a combination of the activation energies of the elementary stages. Sometimes the concept of âapparentâ activation energy is used in addition to the true activation energy, determined from the Arrhenius equation.