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There are two ways to age whiskey at home. The most traditional method of DIY whiskey aging is to purchase or build a charred white oak barrel. To prep a barrel to be used for aging, make sure to first fill it with warm water and leave it sit until the wood swells enough to prevent leaking between the staves.
Water is whiskey's best friend...in small amounts. If you've got cask strength whiskey in a glass, it's going to burn you. Splash a little water in there and you'll be amazed at how much flavor opens up. If you're just starting out, try mixing 3/4 whiskey to 1/4 water in your glass. This will take the edge off the alcohol burn and allow you to taste the other flavors. Don't overdo it to start. You can always add more water if the drink's too strong.