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Actually potatoes that are left out overnight are perfectly fine to eat. as long as they do not have much milk or butter on them. even if they have butter they will be fine to eat. plain cooked potatoes, such as baked can stay out for up to 3 days.
You can store peeled potatoes in water in the refrigerator for about 24 hours. Peeled potatoes left out by themselves at room temperature, on a refrigerator shelf or wrapped in foil or plastic wrap will still get dark overnight, so submerge them in a bowl of water, cover and refrigerate. Cubed peeled potatoes can sit in water overnight, but they need to be refrigerated. Cut the potatoes into equal size chunks so that when you decide to boil them they will cook at the same time, usually 1 1/2 to 2 inch chunks.