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Since a shot is typically a spirit with 40 percent alcohol, this makes the shot 1.5 imp fl oz or 42.6 ml (though many establishments serve a standard drink of 1 oz). A double shot in North America may be either 2.5 or 3 fluid ounces.
In some states you aren't allowed to serve a drink with more than an ounce of alcohol in it, so in those states a shot would be one ounce. In my state, no such law exists, but a standard shot is 1 ounce. And I'm surprised you people pick a 5th as a standard bottle.