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Report Abuse. Iodine is a purple solid at room temperature. Some of these people are confusing iodine with iodine (or potassium iodide) solution which is a browny/orangey/yellowy colour.When this solution is added to starch...it turns black.Why the thumbs-down???it's true!!!ome of these people are confusing iodine with iodine (or potassium iodide) solution which is a browny/orangey/yellowy colour.When this solution is added to starch...it turns black. Why the thumbs-down???it's true!!!
Complexed iodine, soluble in water as triiodide, forms a brown solution in the denser aqueous layer while free iodine forms a faint pink color in the organic solution. Upon addition of an oxidizing agent, such as bleach, to the bottom of the vial, the triiodide complex is oxidized to free iodine.omplexed iodine, soluble in water as triiodide, forms a brown solution in the denser aqueous layer while free iodine forms a faint pink color in the organic solution. Upon addition of an oxidizing agent, such as bleach, to the bottom of the vial, the triiodide complex is oxidized to free iodine.