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The integrated rate law for the zero-order reaction A âB is [A] t = [A] 0 â kt. (a) Sketch the following plots: (i) rate versus [A] t and. (ii) [A] t versus t. (b) Derive an expression for the half-life of the reacÂ­tion. (c) Calculate the time in half-lives when the inÂ­tegrated rate law is no longer valid, that is, when [A] t = 0. STEP-BY-STEP SOLUTION. JavaScript Not Detected. JavaScript is required to view textbook solutions.
B Write the rate law for the reaction. Using the appropriate data from the table and the linear graph corresponding to the rate law for the reaction, calculate the slope of the plotted line to obtain the rate constant for the reaction.xperimental data for this reaction at 330Â°C are listed in Table 14.5 Concentration of NO ; they are provided as [NO 2 ], ln[NO 2 ], and 1/[NO 2 ] versus time to correspond to the integrated rate laws for zeroth-, first-, and second-order reactions, respectively.