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The integrated rate law for the zero-order reaction A âB is [A] t = [A] 0 â kt. (a) Sketch the following plots: (i) rate versus [A] t and. (ii) [A] t versus t. (b) Derive an expression for the half-life of the reacÂ­tion. (c) Calculate the time in half-lives when the inÂ­tegrated rate law is no longer valid, that is, when [A] t = 0. STEP-BY-STEP SOLUTION. JavaScript Not Detected. JavaScript is required to view textbook solutions.
If the reaction is truly zero order, the rate constant will be the slope of the line, and be in terms of moles reacted per unit time. Thus, you can determine the time frame of the reaction if you want to carry it out to be compatible with your timing equipment. cattbarf Â· 8 years ago.Thumbs up. 1. would like to know how do you calculate the rate constant from a graph that yields a zero order. The graph is linear of course to have a zero order. I need to calculate the rate constant from a graph Concentration vs. Time data. I do not know which number to choose to place in the first order equation.