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Santorini is complex of overlapping shield volcanoes. Basalt and andesite lava flows that make the shield are exposed in the cliff below the town of Phira. Some of t he cliff is thought to be a caldera wall associated with an eruption 21,000 year ago.antorini is complex of overlapping shield volcanoes. Basalt and andesite lava flows that make the shield are exposed in the cliff below the town of Phira. Some of t he cliff is thought to be a caldera wall associated with an eruption 21,000 year ago.
Santorini was named by the Latin Empire in the thirteenth century, and is a reference to Saint Irene, from the name of the old cathedral in the village of Perissa-the name Santorini is a contraction of the name Santa Irini.antorini is essentially what remains after an enormous volcanic eruption that destroyed the earliest settlements on a formerly single island, and created the current geological caldera.