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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
Fourteen to twenty cups of such decaffeinated coffee would contain as much caffeine as one cup of regular coffee. The 16-ounce (473-ml) cups of coffee samples contained caffeine in the range of 8.6 mg to 13.9 mg. In another study of popular brands of decaf coffees, the caffeine content varied from 3 mg to 32 mg.ecaffeination processes for coffee [edit]. In the case of coffee, various methods can be used. The process is performed on unroasted (green) beans and starts with steaming of the beans.