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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
According to FDA guidelines, decaffeinated coffee must have 97% of the caffeine removed. In actuality, the caffeine content of coffee beans varies widely; therefore the caffeine content of decaffeinated coffee. also fluctuates, and can be 10mg or more per 12 ounce cup.5 Other measurements found caffeine levels.