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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
CAVEAT EMPTOR: âdecaffeinatedâ does not mean 100% caffeine free. In fact a decaf coffee only needs to be 97% caffeine free according to the USDA. That means that an average 12 oz. cup of decaffeinated coffee, which originally might have been packed with 180 mg of caffeine, now only would contain 5.4 mg of caffeine.