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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
The caffeine in coffee and other caffeinated beverages has a variety of negative effects, including sleep disturbances, Restless Legs Syndrome (RLS), tiredness, anxiety, nightmares, irritability and aggression. Decaf coffee typically contains 4 to 6% of the caffeine of regular coffee (references below).