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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
Instant coffee may be lower in caffeine averaging between 40-108 mg per cup. Decaffeinated coffee, despite its name, does contain some caffeine, although only about 2-5 mg per five ounce cup. Source(s): http://pol.spurious.biz/dev_zero/caffein...