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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
A 16 oz StarbucksÂ® Grande contains 12-23 milligrams and a 20 oz Venti contains upwards of 28 milligrams! If you order a cup of decaf coffee at a coffee bar or restaurant, independent studies have shown a great variance in the amount of caffeine in the cup even on the same day from the very same place.