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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
One cup of decaf can have close to 10 milligrams of caffeine. While everyone is different and you may be able to handle more caffeine than some others, you should never have more than 600 milligrams in a day, the U.S. Food and Drug Administration reports.