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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
Larger sizes, which are made with two, or even three, espresso shots (16 oz), likewise contain 150 or 225 mg of caffeine. Decaf coffee from Starbucks contains 15â30 mg of caffeine, depending on cup size. Bottom Line: An 8-oz, brewed coffee from Starbucks contains 180 mg of caffeine. A single espresso and espresso-based drinks contain 75 mg, while an 8-oz cup of decaf coffee contains about 15 mg of caffeine. McDonaldâs