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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
In the study, published in the Journal of Analytical Toxicology, researchers set out to find out how much caffeine is likely to be found in popular decaffeinated coffees. Researchers purchased 10 16-ounce decaffeinated cups of drip coffee from coffee shops and restaurants and analyzed them for caffeine content.