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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
Not only did Dunkinâ Donuts increase the caffeine of their standard brewed coffee to be more inline with coffee establishments such as Starbucks, but they also reformulated their decaf. In 2015, a medium Dunkinâ Decaf had 74 milligrams of caffeine, which is very high for a decaf coffee with about as much caffeine as an espresso shot. This was not received well by the consumer and I imagine this was part of the reason they went back to more standard caffeine amounts in 2016.