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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
Think again. One Journal of Analytical Toxicology report looked at nine different types of decaffeinated coffee and determined that all but one contained caffeine. The dose ranged from 8.6 mg to 13.9 mg. (A generic brewed cup of regular coffee typically contains between 95 and 200 mg, as a point of comparison. A 12-ounce can of Coke contains between 30 and 35 mg, according to the Mayo Clinic.).