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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
The average 12-ounce cup of decaf coffee â a Starbucks tall â usually contains between 3 and 18 milligrams of caffeine.(By comparison, an 8.4-ounce can of Red Bull contains 80 milligrams of caffeine) The average of amount of caffeine in regular coffee can vary significantly, usually between 140 and 300 mg.he average 12-ounce cup of decaf coffee â a Starbucks tall â usually contains between 3 and 18 milligrams of caffeine.