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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
In 2007, Consumer Reports studied cups of decaffeinated coffee from popular chains. While most cups had fewer than 5 milligrams of caffeine, one cup from Dunkin Donuts contained a whopping 32 milligrams, and another from Seattleâs Best came in at 29 milligrams â certainly not a caffeine-free choice.he average 12-ounce cup of decaf coffee â a Starbucks tall â usually contains between 3 and 18 milligrams of caffeine.