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The study of molecules by molecular physics and theoretical chemistry is largely based on quantum mechanics and is essential for the understanding of the chemical bond. The simplest of molecules is the hydrogen molecule-ion, H 2 + , and the simplest of all the chemical bonds is the one-electron bond.
In chemistry, a valence electron is an electron that is associated with an atom, and that can participate in the formation of a chemical bond; in a single covalent bond, both atoms in the bond contribute one valence electron in order to form a shared pair.ecause the number of valence electrons which actually participate in chemical reactions is difficult to predict, the concept of the valence electron is less useful for a transition metal than for a main group element; the d electron count is an alternative tool for understanding the chemistry of a transition metal.