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You can also try home remedies for toothache relief too: 1  Avoidance - Do not chew on the side where the pain is located. 2  Saltwater - Mix a few teaspoons of table salt in a glass of warm water and swish it around in your mouth as long as you can stand it (but don't swallow it).
Naproxen is a very good anti-inflammatory and usually with a toothache there is pain and inflammation associated with it. You may still want to contact your dentist, because if there is an infection, the Naproxen won't help with this, but it should help subside the pain.