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Caffeine in a Frappucino varies. The cream-based varieties have no caffeine in their original recipes (you can always add shots). For the coffee-based Frapps you're talking 65/90/125mg for your standard Frappucino with flavoring. 70/95/130mg (a touch higher) for the Coffee Frapp. And 130/165/180mg for an Espresso.
Directions. 1  In medium saucepan over medium high heat, bring water and sugar to a boil. 2  Cook until mixture thickens slightly, about three minutes. 3  Remove from heat, stir in vanilla and let cool to room temperature.4  Refrigerate in an airtight container for up to two weeks. needed a vanilla syrup for Starbucks Frappuccino, vanilla flavor. My husband is nuts for the stuff but it's expensive to buy by the bottle-this worked perfectly!