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Caffeine in a Frappucino varies. The cream-based varieties have no caffeine in their original recipes (you can always add shots). For the coffee-based Frapps you're talking 65/90/125mg for your standard Frappucino with flavoring. 70/95/130mg (a touch higher) for the Coffee Frapp. And 130/165/180mg for an Espresso.
Frappuccino ingredients: makes 2.5 cups (590 mL) 1  1 cup double-strength Starbucks coffee OR 3/4 cup fresh espresso (cold) 2  3/4 cup milk (low fat, 2%, whole or whatever) 3  3 tablespoons granulated sugar (or to taste)  2 cups 1  ice. Secret ingredient: Pinch of xanthan gum OR 1 teaspoon dry pectin (keeps Frapp from separating)