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A network solid or covalent network solid is a chemical compound (or element) in which the atoms are bonded by covalent bonds in a continuous network extending throughout the material.
The best answer I can come up with is that covalent molecular are held together by covalent bonds AND intermolecular bonds whereas covalent networks are only held together by â¦ covalent bonds. This means that the intermolecular bonds in covalent molecular are easy to break which is why it has a low boiling point. Covalent networks are all covalently bonded which means they are stronger and have a higher boiling point. I hope that's right because i have a test on this tomorrow. Sorry if it is wrong.