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You can apply lemon juice to get rid of darkness around mouth due to melasma. Lemon juice is a natural bleaching agent. Massaging the dark around mouth with the lemon juice is the best home remedy for lightening the dark skin around mouth.
If you aren't sure what's causing the dark area around your mouth, a dermatologist may be able to diagnose the problem and suggest a treatment. Changes in the skin can be early warning signs of skin cancer and other serious disorders, so it might be wise to have a doctor check out your symptoms just in case.