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Caffeine in a Frappucino varies. The cream-based varieties have no caffeine in their original recipes (you can always add shots). For the coffee-based Frapps you're talking 65/90/125mg for your standard Frappucino with flavoring. 70/95/130mg (a touch higher) for the Coffee Frapp. And 130/165/180mg for an Espresso.
The Vanilla Frappuccino, for instance, has just under 300 calories and 45 grams of sugar, but you can opt for an alternative, which can help reduce your overall calorie intake by more than 50% (the Mocha Frappuccino Light Blended coffee is a great choice).