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A divergent boundary, or constructive boundary, is where two sections of the eggshell - two tectonic plates - are moving away from each other. When this happens, they leave a gap in-between, and this gap can be filled by the magma from below. This creates a series of volcanoes all the way along the boundary.
It is more a matter of whether the boundary itself lies over an ocean or land than whether the plates are continental or oceanic. Examples of Divergent Boundaries. The mid-Atlantic ridge is an example of a divergent boundary, where the Eurasian Plate that covers all of Europe separates from the North American Plate.