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Caffeine in a Frappucino varies. The cream-based varieties have no caffeine in their original recipes (you can always add shots). For the coffee-based Frapps you're talking 65/90/125mg for your standard Frappucino with flavoring. 70/95/130mg (a touch higher) for the Coffee Frapp. And 130/165/180mg for an Espresso.
1 Frappuccino: Frappuccino is a blended coffee beverages developed and sold by Starbucks who have trademarked the name. 2  It is an iced or chilled cappuccino that may be topped with whipped cream. 3  It generally consists of espresso coffee, milk, sugar, ice, whipped cream and other sweeteners.rappuccino is actually a registered trademark of Starbucks, so think of it as the difference between a burger and Big Mac, whereas the frappe was an accidental invention originating in Greece, and outside of the USA, is usually served as a flavoured, iced, milk-based drink without all the toppings.