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You can apply lemon juice to get rid of darkness around mouth due to melasma. Lemon juice is a natural bleaching agent. Massaging the dark around mouth with the lemon juice is the best home remedy for lightening the dark skin around mouth.
Use a cotton ball in the juice and apply it over your closed eyes. You should make sure that the juice covers the dark circles under your eyes as well as the eyelids. Let the juice sit for 10 to 15 minutes. After that rinse your eyelids with cool water. Repeat it once or twice daily for a few weeks.