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Caffeine in a Frappucino varies. The cream-based varieties have no caffeine in their original recipes (you can always add shots). For the coffee-based Frapps you're talking 65/90/125mg for your standard Frappucino with flavoring. 70/95/130mg (a touch higher) for the Coffee Frapp. And 130/165/180mg for an Espresso.
All the way from brewed coffees, to ice-cold Frappuccinos, this list provides all major drinks. Please use this site as a reference to all drinks. But remember that every drink is custom made and can be prepared differently at your local Starbucks. Try any beverage with whipped cream, soy milk, or non-fat milk.