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Caffeine in a Frappucino varies. The cream-based varieties have no caffeine in their original recipes (you can always add shots). For the coffee-based Frapps you're talking 65/90/125mg for your standard Frappucino with flavoring. 70/95/130mg (a touch higher) for the Coffee Frapp. And 130/165/180mg for an Espresso.
Thanks to social media, the Starbucks Secret Menu has recently achieved some recognition, so drinks like the Captain Crunch Frappuccino or the Nutella Frappuccino are emerging. Other favorites include the Vanilla Bean Frap and the Double Chocolate Chip Frappuccino.