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Caffeine in a Frappucino varies. The cream-based varieties have no caffeine in their original recipes (you can always add shots). For the coffee-based Frapps you're talking 65/90/125mg for your standard Frappucino with flavoring. 70/95/130mg (a touch higher) for the Coffee Frapp. And 130/165/180mg for an Espresso.
A Starbucks frappuccino back in the day was made with the frappuccino base (which was a mixture of powdered coffee - think an early version of Via - and a base - which was sort of like a creamer, including sweetener, a dairy, some mocha, and various other random ingredients - this arrived at stores premixed and in a box, like soy milk) and then ...