Portageville, Missouri. Portageville is a city in New Madrid and Pemiscot counties in the U.S. state of Missouri. The population was 3,228 according to the 2010 Census.
the motional energy with which we are concerned in discussing entropy consists of the combined energy of translation rotation and vibration phase change energy is motional energy of the surroundings that has been supplied to or released by the system due to its potential energy of intermolecular bonding
As discussed in the overview, if the temperature and pressure are held constant, the Gibbs free energy is a (negative) proxy for the change in total entropy of the universe. It is negative because S appears with a negative coefficient in the expression for G, so the Gibbs free energy moves in the opposite direction from the total entropy. Thus, a reaction with a positive Gibbs free energy will not proceed spontaneously.