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Na (Sodium) has a +1 charge. Kazyan: See above, but some exotic chemistry has produced sodium ions that are negative: -1.
Lithium is a Group IA metal, so its ion will have a +1 charge. Phosphate is a polyatomic ion with a -3 charge. The compound needs three lithium ions to balance the -3 charge of the phosphate, so the formula is Li 3 PO 4. Notice that we didn't do anything with the 4 subscript on the phosphate.