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Na (Sodium) has a +1 charge. Kazyan: See above, but some exotic chemistry has produced sodium ions that are negative: -1.
When an electron is ejected from a sodium atom we have a Na+ ion. We can write an equation for this process: Na(g) Na+(g) + e-. This is the equation for the ionization of sodium and the energy required is the first ionization energy for sodium. The wavelength of a photon of light with this energy can be calculated.