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Na (Sodium) has a +1 charge. Kazyan: See above, but some exotic chemistry has produced sodium ions that are negative: -1.
Sodium Phosphate is an ionic compound formed by two ions, Sodium Na^+ and Phosphate PO_4^-3. In order for these two polyatomic ions to bond the charges must be equal and opposite. Therefore, it will take three +1 sodium ions to balance the one -3 phosphate ion. This will make the formula for Sodium Phosphate Na_3PO_4. I hope this was helpful.