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Potassium salt is often used as a substitute for regular sodium chloride salt (the salt you find on your kitchen table), and for good reason. Most people in the United States take in too much salt on a daily basis, which may put them at risk for hypertension, heart attacks and strokes.
That they are different elements that combine with the same anions to make similar salts was suspected in 1702, and was proven in 1807 using electrolysis. Most industrial applications of potassium exploit the high solubility in water of potassium compounds, such as potassium soaps.