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Peachskin is a blouseweight fabric with a soft hand. It has almost a suede-like face, but still soft and does not have a nap like suede. It drapes nicely on the body and is perfect for tops, dresses and skirts.
Polyester is a man-made fibre. The material is warm and has no absorbancy. Hence is no good for a garment of regular use. A regular garment should be stretchable and sweat absorbent. It should not be heat resistant or water resistant. Polyester does not stretch, does not absorb sweat, does not breathe.