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Brake dust is rotor material that is caused by an excessively abrasive disc pad wearing the rotor material away. The appearance of heavy black dust on shiny aluminum rims can cause a lot of frustration. Usually the front wheels get it the worst because the front end handles about 70% of the stopping.
Brake pads overheating smell nasty, like burned popcorn. While this smell could be caused by part of your brake system dragging because of a malfunction, it could be as simple as accidentally not releasing your parking brake all of the way.