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Flaky dry skin due to face eczema. If your face looks dry and inflamed and moisturizers do not work at all then the problem can be face eczema. Dry flaky skin on face due to face eczema should be treated by products that contain hydrocortisone. Start with mild ones if it does not work, see a dermatologist.
1 Dry skin. Flakes from dry skin are generally smaller and less oily than those from other causes of dandruff. And, redness or inflammation is unlikely. You'll probably have dry skin on other parts of the body, such as your legs and arms, too.  Sensitivity to hair care products (contact dermatitis).