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Flaky dry skin due to face eczema. If your face looks dry and inflamed and moisturizers do not work at all then the problem can be face eczema. Dry flaky skin on face due to face eczema should be treated by products that contain hydrocortisone. Start with mild ones if it does not work, see a dermatologist.
Dandruff can have several causes, including dry skin, seborrhoeic dermatitis, not cleaning/scrubbing often enough, shampooing too often, psoriasis, eczema, sensitivity to hair care products, or a yeast-like fungus. Dry skin is the most common cause of flaking dandruff.