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The sign of the heat of formation matters. Using hess's law: 2(-238kJ) + 4(242kJ) + 2(393)= -1279=Heat of reaction Heat of combustion of methanol is just the heat of reaction divided by the molar coefficient for methanol in the chemical equation so about -639.5kJ/mol. In acuality it is somewhere near -727kJ/mol.
With some redesigning, more methanol (up to 85%) can be used. The advantage for China is that the methanol can be produced from both coal and biomass via synthesis gas. This emphasis of using methanol as a fuel is reflected in the global production figures for methanol.anufacture of methanol. Methanol is manufactured from synthesis gas which is a mixture of carbon monoxide and hydrogen. The feedstock, over the last 40 or more years, has been oil or natural gas.