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The sign of the heat of formation matters. Using hess's law: 2(-238kJ) + 4(242kJ) + 2(393)= -1279=Heat of reaction Heat of combustion of methanol is just the heat of reaction divided by the molar coefficient for methanol in the chemical equation so about -639.5kJ/mol. In acuality it is somewhere near -727kJ/mol.
= 1211 kJ mol-1. Therefore the molar heat of combustion of ethanol is 1211 kJ mol-1 (The molar enthalpy of combustion of ethanol is 1211 kJ mol-1). (Note that the enthalpy change for the reaction is negative because the reaction is exothermic, so the enthalpy change for the reaction is -1211 kJ mol-1, ÎH = - 1211 kJ mol-1)