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The remarkable triple state of matter where solid, liquid and vapor are in equilibrium may be characterized by a temperature called the triple point. The triple state is represented by a line parallel to the Pv plane with a characteristic pressure for the substance but variable volume. The triple point temperature of water is assigned the value 273.16 K and the triple state of water is used as the reference for establishing the Kelvin temperature scale.
Simply subtracting out bulk water overcorrects because some waters are associated with the proton. By properly scaling the bulk water peak, they identify n as six. Deconvolution of the spectrum of H(H 2 O) 6 + gives peaks at 3134 Â±12, 2816 Â± 40, 1746 Â± 11, 1202 Â± 4 and 654 Â± 12 cm -1.