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The remarkable triple state of matter where solid, liquid and vapor are in equilibrium may be characterized by a temperature called the triple point. The triple state is represented by a line parallel to the Pv plane with a characteristic pressure for the substance but variable volume. The triple point temperature of water is assigned the value 273.16 K and the triple state of water is used as the reference for establishing the Kelvin temperature scale.
Thus when water molecules are close together, their positive and negative regions are attracted to the oppositely-charged regions of nearby molecules. The force of attraction, shown here as a dotted line, is called a hydrogen bond. The energy required to break multiple hydrogen bonds causes water to have a high heat of vaporization; that is, a large amount of energy is needed to convert liquid water, where the molecules are attracted through their hydrogen bonds, to water vapor, where they are not.