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The remarkable triple state of matter where solid, liquid and vapor are in equilibrium may be characterized by a temperature called the triple point. The triple state is represented by a line parallel to the Pv plane with a characteristic pressure for the substance but variable volume. The triple point temperature of water is assigned the value 273.16 K and the triple state of water is used as the reference for establishing the Kelvin temperature scale.
A temperature scale that is based on the triple point of water (defined to be 273.16Â°K) and assigned the value of 0.01Â°C; has replaced the centigrade scale because the triple point of water can be more accurately measured than the ice point; for most practical purposes, however, the two scales are equivalent.