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The oxidation number of K is +1. The oxidation number of Cl is -1. You assign oxidation numbers to the elements in a compound by using the Rules for Oxidation Numbers. The oxidation number of a monatomic ion equals the charge of the ion. The oxidation number of a Group 1 element in a compound is +1.
The algebraic sum of the oxidation number of all atoms in a neutral compound is zero. 6. The oxidation number of elements in its free state is zero. 7. The oxidation number of the halogens is -1 when they combine with hydrogen or with a metal in. a binary compound. We will discuss the ion-electron method first.