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The notes of the G-sharp major scale are: G#, A#, B#, C#, D#, E#, Fx, G#. The x you see is called a double sharp. (Double sharps raise a note higher by 1 whole step. Fx is actually G.) However, because of the simpler enharmonic equivalent of Ab major, which has 4 flats, Ab major is used a lot more than G# major ever is.
A major/natural minor scale can never have both flats and sharps - it's either one or the other. The order of flats is the same as the order of sharps, but reversed. Every major scale that has a natural note as the tonic has sharps, except for C which has all natural notes and F, which has one flat. When a major scale has sharps, the last sharp (in the order of sharps) is the seventh note in the scale. Example: E major - the seventh note is D#. D# is the fourth sharp.