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Moonshine is essentially an un-aged whisky, traditionally clear with a hint of corn. It is perfect for sipping or using as a substitute in cocktails. There are different varieties of moonshine depending on the distillation process and number of times the spirit runs through the still..
In reality, the main difference surrounds the question of what they're made of: whiskeys are made from a fermented mash of grain (usually corn, rye, barley or wheat) whereas bourbon has to be comprised of at least 51% corn as part of its grain mash.