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Thermal cracking. In thermal cracking, high temperatures (typically in the range of 450Â°C to 750Â°C) and pressures (up to about 70 atmospheres) are used to break the large hydrocarbons into smaller ones. Thermal cracking gives mixtures of products containing high proportions of hydrocarbons with double bonds - alkenes.
Although ethylene is produced by various methods as follows, only a few are commercially proven: thermal cracking of hydrocarbons /the principal route for the industrial production of ethylene/, catalytic pyrolysis, membrane dehydrogenation of ethane, oxydehydrogenation of ethane, oxidative coupling of methane, methanol to ethylene, dehydration of ethanol, ethylene from coal, disproportionation of propylene, and ethylene as a by-product.