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1 The skin condition known as rosacea can also cause hot face and ears. Other symptoms include broken veins and redness.  The condition can also be a sign of carcinoid syndrome. Hormone releasing tumors in the appendix, bronchial tubes, colon or small intestine cause this syndrome.
Anxiety also creates a great deal of stress, and stress can trigger skin disorders that were already present, such as eczema, herpes, and psoriasis. These skin disorders may cause a burning feeling. In these causes, anxiety would not have caused these skin disorders, but may contribute to them.