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1 The skin condition known as rosacea can also cause hot face and ears. Other symptoms include broken veins and redness.  The condition can also be a sign of carcinoid syndrome. Hormone releasing tumors in the appendix, bronchial tubes, colon or small intestine cause this syndrome.
This condition causes pain as a result of inflammation of a facial nerve. The pain is described as intense and lightning like, and it can occur in the lips, scalp, forehead, eye, nose, gums, cheek, and chin on one side of the face. The pain can be set off by touching a trigger area or by slight motion.