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The choice of the second buffer depends on your application: if you measure values below pH 7, use pH 4 as a second buffer. If you measure values above pH 7, use pH 10 as your second buffer. Some of our pH meter use 3 points calibration, keep in mind to always start with pH 7 first and others after.
Step 3. Use the equation of the calibration curve to adjust measurements taken on samples with unknown values. Substitute the measured value as x into the equation and solve for y (the true value). In the example from step 2, y = 1.05x + 0.2. Thus, a measured value of 75.0, for example, would adjust to y = 1.05(75) + 0.2 = 78.9.