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As a general rule, the IRS allows you to deduct contributions to charitable organizations up to 50 percent of your AGI. Any excess donations you make can be carried forward to the next tax year. For example, say your AGI is $50,000 and you made $27,000 in donations.
The IRS rules state the the Corporation is entitled to deduct upto a maximum of 10% of a Corporations net taxable income without consideration of NOL and Charitable contribution. In other words, calculate the taxable income w/o deduction of charitable contribution, and a maximum limit is 10% of this taxable income. Therefore, if there is no taxable income, the corporations would not be able to deduct charitable contributions for that calendar year. I guess the next question would be, what if your client, the C corporation made a contribution in excess of the 10% limit.