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The most recent and debatably best-known, the CretaceousâPaleogene extinction event, which occurred approximately 66 million years ago (Ma), was a large-scale mass extinction of animal and plant species in a geologically short period of time.
The worst mass extinction of all time came about 250 million years ago [the Permian-Triassic extinction event]. There's a pretty good consensus there that this was caused by a huge volcanic event that went on for a long time and released a lot of carbon-dioxide into the atmosphere.