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1 There is 24 percent more CO2 embedded in a barrel of tar sands bitumen than in a barrel of light oil. 2  15 to 30 percent of a barrel of tar sands bitumen can end up as petcoke, depending on the upgrading and refining process used. 3  Of 134 operating U.S. refineries in 2012, 59 are equipped to produce petcoke.ut as bad as these impacts already are, existing analyses of the impacts of tar sands fail to account for a byproduct of the process that is a major source of climate change causing carbon emissions: petroleum coke â known as petcoke.