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About Rum & Cane Spirits. Rum, and its fraternal twin, cane spirit, are made by distilling fermented sugar and water. This sugar comes from the sugar cane and is fermented from cane juice, concentrated cane juice, or molasses. Molasses is the sweet, sticky residue that remains after sugar cane juice is boiled and the crystallized sugar is extracted.
To know more detail in brief of making vodka please use the link Prashant G. Arabhavi's answer to What is vodka made of? Whisky, the main ingredients used are Barley (in Scotch whisky), Rye (in Ireland whiskey) and Corn (in American whiskey) Rum is made from molasses (by product of sugar manufacture).