It's an expression that originated in the works of Shakespeare. If someone is a piece of work, it means that he or she is a very unpleasant person or a bad person lacking morals, etc. Examples: He's a nasty piece of work, Carl. I'd avoid him if I were you.
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No, there isn't a Leovegas software to download for desktop computers. The website is an instant play casino, and only offers game that can be played with the Flash technology. The casino offers games of multiple developers, such as Netent, Microgaming, Play'n Go, NextGen Gaming, Yggdrasil, Betsoft and many more.